Ueber einige vorläufige Beobachtungen bezüglich der Ursachen natürlicher Veränderungen im Latex von Hevea Brasiliensis

Colloid and Polymer Science - Die in den voraufgehenden Zeilen gegebene Analysis der Ursachen und Bedingungen der natürlichen Koagulation von Hevea Brasiliensis-Latex läßt uns mehr...     

Substitution-permutation networks resistant to differential and linear cryptanalysis

In this paper we examine a class of product ciphers referred to as substitution-permutation networks. We investigate the resistance of these cryptographic networks to two important attacks: differential cryptanalysis and linear cryptanalysis. In particular, we develop upper bounds on the differential characteristic probability and on the probability of a linear approximation as a function of the number of rounds of substitutions. Further, it is shown that using large S-boxes with good diffusion characteristics and replacing the permutation between rounds by an appropriate linear transformation is effective in improving the cipher security in relation to these two attacks.This work was supported by the Natural Sciences and Engineering Research Council of Canada and the Telecommunications Research Institute of Ontario, and was presented at the rump session of CRYPTO '93. Howard Heys is now with Electrical Engineering, Faculty of Engineering and Applied Science, Memorial University of Newfoundland, St. John's, Newfoundland, Canada A1B 3X5.     

Far-Infrared Optics Design & Verification

Compact quasi-optics are difficult to design with any confidence using techniques developed for visible wavelengths. In this paper we investigate the performance of existing software design tools (ASAP, CODE V, GLAD) as well as a Gaussian beam mode analysis technique not yet available as commercial software. We have devised a set of test cases and used these to study the underlying methodologies and physics of these packages and we probe their suitability for the analysis of submillimetre-wave systems and components. We have used the physical optics package GRASP as our benchmark software.     

Altering the Mechanical Properties of Sn Films by Alloying with Bi: Mimicking the Effect of Pb to Suppress Whiskers

Stress is believed to be the main driving force for whisker formation in Sn coatings on Cu. This suggests that whiskering can be suppressed by enhancing stress relaxation in the Sn layer, which is believed to be the reason why Sn-Pb alloys do not form whiskers. However, Pb is no longer acceptable for use in electronics manufacturing. As an alternative, we used pulsed plating to create Sn-Bi coatings with an equiaxed microstructure similar to that of Sn-Pb alloys. An optical wafer curvature technique was used to measure stress relaxation kinetics in Sn, Sn-Pb and Sn-Bi alloy thin films during thermal cycles. The results show that Sn-Bi films have significantly enhanced stress relaxation relative to pure Sn films. Comparison between Sn-Bi samples with equiaxed and columnar microstructures shows that both microstructure and alloy composition play a role in enhancing the stress relaxation.     

Synthesis of thiol-clickable and block copolypeptide brushes via nickel-mediated surface initiated polymerization of α-amino acid N-carboxyanhydrides (NCAs)

We describe the synthesis of homo-, block, and clickable copolypeptide brushes from low surface area substrates using nickel-mediated surface-initiated polymerization of α-amino N-carboxyanhydrides.     

Interpreting protein structural dynamics from NMR chemical shifts

In this investigation, semiempirical NMR chemical shift prediction methods are used to evaluate the dynamically averaged values of backbone chemical shifts obtained from unbiased molecular dynamics (MD) simulations of proteins. MD-averaged chemical shift predictions generally improve agreement with experimental values when compared to predictions made from static X-ray structures. Improved chemical shift predictions result from population-weighted sampling of multiple conformational states and from sampling smaller fluctuations within conformational basins. Improved chemical shift predictions also result from discrete changes to conformations observed in X-ray structures, which may result from crystal contacts, and are not always reflective of conformational dynamics in solution. Chemical shifts are sensitive reporters of fluctuations in backbone and side chain torsional angles, and averaged (1)H chemical shifts are particularly sensitive reporters of fluctuations in aromatic ring positions and geometries of hydrogen bonds. In addition, poor predictions of MD-averaged chemical shifts can identify spurious conformations and motions observed in MD simulations that may result from force field deficiencies or insufficient sampling and can also suggest subsets of conformational space that are more consistent with experimental data. These results suggest that the analysis of dynamically averaged NMR chemical shifts from MD simulations can serve as a powerful approach for characterizing protein motions in atomistic detail.     

A horn-reflector antenna for high-performance submillimetre-wave imaging arrays

We have developed an antenna for high-performance submillimetrewave imaging arrays. The antenna comprises a corrugated horn with an off-axis paraboloidal reflector at its aperture. The corrugated horn is machined directly into two halves of a split aluminium block. This approach avoids electroforming and is compatible with E-plane circuit technology. The resulting antenna is light weight and is ideal for space applications. For compatibility with submillimetre-wave optics, the the behaviour has been calculated by using Gaussian-Hermite modes, and the integrity of the theory has been verified by modelling the behaviour of a 17GHz antenna. The manufacturing procedure has been investigated by machining and testing a horn-reflector antenna for 450–500GHz. Our next step is to extend the technique to 1THz.