液晶CPBOB吸附的STM研究

利用STM对吸附在导电基底上的液晶进行研究，能提供近原子分辨的液晶分子图象，这一创新不仅拓宽了STM的研究领域，也使STM成为研究液晶吸附的重要手段之一．根据液晶相变特征不同，样品的制备方法大致分四种情况：直接法，加热法，气相沉积法和溶剂法．无论采用以上哪种方法，     

多官能度噁唑烷的合成及其改性聚氨酯材料

合成了2,2-二甲基-N-羟乙基-1,3-噁唑烷(OX),并以其为结构单元合成了2种多官能度的噁唑烷化合物——丙二酸二-2,2-二甲基-N-羟乙基-1,3-噁唑烷酯(OX1)和1,1,5,5-戊烷端四甲酸四-2,2-二甲基-N-羟乙基-1,3-噁唑烷酯(OX2).采用13C核磁共振谱、质谱、元素分析和傅里叶变换红外光谱对产物结构进行表征,并探索了产物用于单组份湿固化聚氨酯(SPU)体系的潜固化剂性能.研究了固化体系的表观性能、力学性能和热性能.结果表明:纯湿固化SPU发泡且膨胀,拉伸强度为3.2 MPa,断裂伸长率为364%;而SPU-OX2固化体系的拉伸强度达27.2 MPa,是纯SPU固化体系拉伸强度(3.2 MPa)的9倍;SPU-OX2固化体系断裂伸长率达457%,是纯SPU固化体系断裂伸长率(364%)的1.26倍.聚氨酯中加入噁唑烷OX1和OX2为潜固化剂,不仅较好改善了聚氨酯的表观性能,而且增加了聚氨酯预聚体的力学性能和热稳定性.     

有机/无机异质结薄膜发光二极管

聚合物发光二极管（LED）自从Burrou吵es等于1990年首次报导PPV的电致发光［‘］以来，由于聚合物半导体具有热和化学性能的稳定，克眼了有机小分子材料容易晶化的优点，在平板显示领域必将占有一席之地，从而吸引了许多科学家投身到这一领域来．众所周知，要想实现LED的实用化     

Cross‐Linked Aptamer–Lipid Micelles for Excellent Stability and Specificity in Target‐Cell Recognition

The specific binding ability of DNA–lipid micelles (DLMs) can be increased by the introduction of an aptamer. However, supramolecular micellar structures based on self‐assemblies of amphiphilic DLMs are expected to demonstrate low stability when interacting with cell membranes under certain conditions, which could lead to a reduction in selectivity for targeting cancer cells. We herein report a straightforward cross‐linking strategy that relies on a methacrylamide branch to link aptamer and lipid segments. By an efficient photoinduced polymerization process, covalently linked aptamer–lipid units help stabilize the micelle structure and enhance aptamer probe stability, further improving the targeting ability of the resulting nanoassembly. Besides the development of a facile cross‐linking method, this study clarifies the relationship between aptamer–lipid concentration and the corresponding binding ability.     

Precursor-directed fungal generation of novel halogenated chaetoglobosins with more preferable immunosuppressive action

Precursor-fed cultivation of endophytic Chaetomium globosum 1C51 afforded nine novel "unnatural" halogenated chaetoglobosins including those with more preferable immunosuppressive activity.     

高熵合金强韧化理论建模与模拟研究进展

高熵合金因其优异的性能受到广泛关注,如高强度、高硬度、高韧性、高耐磨、高耐辐照、高耐腐蚀、高电阻、高耐热等,有望应用于核能、航天航空等重要领域和重大装备.高熵合金制备、组织结构以及性能表征等方面开展的实验研究表明其独特的性质依赖于高熵合金高熵效应、晶格畸变和扩散迟滞.在微观尺度以及宏观尺度,理论模型和数值模拟为研究高熵合金微观机理和力学特性提供了一种方法.建立从高熵合金的微观结构与变形机理到宏观独特力学性能的联系是一个多尺度的科学问题.最近,基于实验观察结果,采用多尺度的理论与模拟方法(第一性原理、分子动力学、离散位错动力学、晶体塑性有限元、微结构依赖的理论模型),研究了高熵合金层错能、弹性模量、扩散系数以及相稳定性,揭示了高熵合金变形与强韧化机制.论文综述多尺度计算在高熵合金力学性能和变形行为方面的研究进展,并对高熵合金在原位变形实验、高通量技术以及机器学习方面的研究进行简要展望.     

无光釉中LiAlSiO4-SiO2固溶体的枝晶研究

本文研究了无光釉中LiAlSiO4-SiO2固溶体的枝晶形貌、物相、成分、形成温度及其关系.六枝雪花状枝晶为六方晶系的β-石英固溶体,十字状枝晶为四方晶系的凯石英固溶体,即枝晶形貌反映了晶体结构的对称.枝晶的成分与基质玻璃的成分分异与形成温度和机制有关.枝晶形成时存在两种机制,其生长基元分别为原子(分子)生长或晶核切变生长.枝晶分枝程度和形成机制除与过冷度有关外,还与枝晶对称性有关.四方凯石英枝晶多以原子(分子)生长,其分枝少;六方β-石英枝晶多以晶核切变机制生长,其分枝多.     

基于关键路径的三模冗余表决器插入算法

在FPGA的三模冗余设计中,寄存器的反馈环路会导致错误持续出现,严重影响三模冗余的容错性能,因此需要在寄存器的反馈环路上插入表决器。该文首次提出了一种针对映射后网表进行三模冗余设计的方法,同时提出了基于关键路径的表决器插入算法,该算法在表决器的插入时避开关键路径,缓解了三模冗余设计中插入表决器时增加延时的影响。与国外同类算法相比,该文算法在不降低电路可靠性的前提下,以不到1%的面积开销,使得关键路径延时减少3%~10%,同时算法运算速度平均提高35.4%。

     

Qualitative analysis for recurrent neural networks with linear threshold transfer functions

Multistable networks have attracted much interest in recent years, since multistability is of primary importance for some applications of recurrent neural networks where monostability exhibits some restrictions. This paper focuses on the analysis of dynamical property for a class of additive recurrent neural networks with nonsaturating linear threshold transfer functions. A milder condition is derived to guarantee the boundedness and global attractivity of the networks. Dynamical properties of the equilibria of two-dimensional networks are analyzed theoretically, and the relationships between the equilibria features and network parameters (synaptic weights and external inputs) are revealed. In addition, the sufficient and necessary conditions for coexistence of multiple equilibria are obtained, which confirmed the observations in with a cortex-inspired silicon circuit. The results obtained in this paper are applicable to both symmetric and nonsymmetric networks. Simulation examples are used to illustrate the theory developed in this paper.