Single-molecule single crystals

Various approaches to the preparation and verification of single-molecule single crystals are discussed for polyethylene and poly (oxyethylene). Analytic tools are electron microscopy, electron diffraction, and differential scanning calorimetry. The main difficulty in producing a single-molecule single crystal is to keep crystals from joining during growth.     

Design aspects of planar and conventional SMPS transformer: a cost benefit analysis

The intent of this paper is to design a high-frequency transformer that is to be incorporated into the DC/DC pulsewidth-modulated switch-mode power supplies by two different technical approaches: a conventional wound-coil magnetic using copper wires, and a planar magnetic with layered copper tracks on laminated printed circuit board. Comparisons will be made between the two approaches in terms of profile: mounting height and surface area, and performance: power losses and efficiency. Other indicators like temperature rise and leakage inductance that causes electromagnetic interference, and cost, materials, and process fluency are also to be looked into. A sandwiched configuration for primary and secondary windings is proposed for the planar type. Issues arising and typical phenomena encountered will be discussed in detail. Primarily, the dominating factor in performance, cost effectiveness, or circuit compactness that restrains the choice of a particular type is to be evaluated.     

2‐Cyanoprop‐2‐yl dithiobenzoate mediated reversible addition–fragmentation chain transfer polymerization of acrylonitrile targeting a polymer with a higher molecular weight

The reversible addition–fragmentation chain transfer (RAFT) polymerization of acrylonitrile (AN) mediated by 2‐cyanoprop‐2‐yl dithiobenzoate was first applied to synthesize polyacrylonitrile (PAN) with a high molecular weight up to 32,800 and a polydispersity index as low as 1.29. The key to success was ascribed to the optimization of the experimental conditions to increase the fragmentation reaction efficiency of the intermediate radical. In accordance with the atom transfer radical polymerization of AN, ethylene carbonate was also a better solvent candidate for providing higher controlled/living RAFT polymerization behaviors than dimethylformamide and dimethyl sulfoxide. The various experimental parameters, including the temperature, the molar ratio of dithiobenzoate to the initiator, the molar ratio of the monomer to dithiobenzoate, the monomer concentration, and the addition of the comonomer, were varied to improve the control of the molecular weight and polydispersity index. The molecular weights of PANs were validated by gel permeation chromatography along with a universal calibration procedure and intrinsic viscosity measurements. ¹H NMR analysis confirmed the high chain‐end functionality of the resultant polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1272–1281, 2007     

Kinetic behaviour of aluminum naphthenate/benzene system in process of gelation and degradation

The kinetic behaviour of aluminum naphthenate/benzene system in the process of gelation and degradation was systematically studied. The results obtained from the kinetic experiments indicated that the gelation stage was in accordance with a kinetic model of an auto-catalytic first-order reaction, and the degradation stage was a simple first-order reaction. The rate constants in these two stages at various temperaturs were measured. And the determined apparent activation energies for the gelation stage and for the degradation stage are 27.5±2.0 and 37.7±2.3 kJ/mol, respectively.     

X射线聚束透镜原理及其应用

本文阐述了一种新型的Ｘ射线聚束装置─—Ｘ射线透镜的聚束原理。给出了透镜的基本设计方法，并对它应用于Ｘ射线光刻研究领域的前景作了展望。     

微波BJT超宽带低噪声放大器的设计

本文给出了一种频带覆盖达１０－１６００ＭＨｚ的微波ＢＪＴ超宽带低噪声放大器的设计方法，从微波ＢＪＴ的噪声模型出发，通过拟合５０Ω源阻抗下微波ＢＪＴ的噪声系数ＮＦ５０和Ｓ参数来提取其噪声参数，然后根据增益，噪声及驻波比要求优化设计放大器，使放大器在超宽带范围内获得平坦增益和低噪声，本文所给出的微波ＢＪＴ惨数提取及放大器优化设计方法已由实验结果所验证。     

介质加载圆柱腔的场分析

本文应用严格场匹配法解决了介质加载圆柱腔的本征问题，计算了圆柱腔在纵向部分填充介质后ＴＥ０１ｎ模和ＴＭ０１ｎ模的本征频率和本征场型的变化。特别分析了本征模式在空气段为截止模的情况。本文的分析方法亦可应用到纵向部分填充介质的传输线和其它形状的谐振腔。     

用稳态反饱和吸收法测量C_（60）的激发态吸收截面

用准连续激光实现了Ｃ６０的稳态反饱和吸收，通过实验和理论计算的拟合，确定了Ｃ６０的三重第一激发态吸收截面。     

A spectrally efficient constant envelope modulation technique forPCS and mobile communications

A newly developed constant envelope FQPSK modem/radio architecture, which employs a modified double-jump (DJ) filter in the cross-correlated FQPSK system, is proposed for personal communications systems (PCS) and mobile radio applications. Power efficiency, spectrum efficiency, BER, and system capacity of this system are investigated in a non-linear amplified (NLA) Rayleigh fading environment. We demonstrate that with the simplest threshold detectors (binary robust eye diagrams in I and Q channels), this system is 4-7 dB more power efficient than the US digital cellular and Japanese Handyphone standard π/4-QPSK, 50%-100% more spectrally efficient than the European standard GMSK, and it almost double the capacity of GMSK     

YAG脉冲激光器快速连通保护系统

本文阐述了ＹＡＧ脉冲激光器的一种快速连通保护系统，利用大功率二极管作为连通故障信号检出的关键元件，采用了可控硅与继电器双重保护，使得整个保护系统既快速可靠，又简便适用。