A hybrid elephant herding optimization and cultural algorithm for energy‐balanced cluster head selection scheme to extend the lifetime in WSNs

Clustering‐based optimal cluster head selection in wireless sensor networks (WSNs) is considered as the efficient technique essential for improving the network lifetime. But enforcing optimal cluster head selection based on energy stabilization, reduced delay, and minimized distance between sensor nodes always remain a crucial challenge for prolonging the network lifetime in WSNs. In this paper, a hybrid elephant herding optimization and cultural algorithm for optimal cluster head selection (HEHO‐CA‐OCHS) scheme is proposed to extend the lifetime. This proposed HEHO‐CA‐OCHS scheme utilizes the merits of belief space framed by the cultural algorithm for defining a separating operator that is potent in constructing new local optimal solutions in the search space. Further, the inclusion of belief space aids in maintaining the balance between an optimal exploitation and exploration process with enhanced search capabilities under optimal cluster head selection. This proposed HEHO‐CA‐OCHS scheme improves the characteristic properties of the algorithm by incorporating separating and clan updating operators for effective selection of cluster head with the view to increase the lifetime of the network. The simulation results of the proposed HEHO‐CA‐OCHS scheme were estimated to be superior in percentage of alive nodes by 11.21%, percentage of dead nodes by 13.84%, residual energy by 16.38%, throughput by 13.94%, and network lifetime by 19.42% compared to the benchmarked cluster head selection schemes.     

Correlation in spatial intensity distribution between volumetric bubble oscillations and sonochemiluminescence in a multibubble system

The correlation in spatial intensity distribution between volumetric oscillation of multibubble and sonochemiluminescence in an ultrasonic standing-wave field is investigated through the measurements of scattered light from bubbles by changing the measuring position in the direction of sound propagation and sonochemiluminescence with luminol. When a thin light sheet, finer than half the wavelength of sound, is introduced into the cavitation bubbles at the anti-node of the sound pressure, the scattered light intensity oscillates temporally. The peak-to-peak light intensity corresponds to the number of the bubbles which contribute to the sonochemical reaction because the radius for oscillating bubbles at pressure antinode is restrictive in a certain range due to the shape instability and the action of Bjerknes force that expels from anti-node bubbles larger than the resonant size. The experimental results show that at the side near the water surface, the peak-to-peak light intensity is larger in comparison with the intensity near the sound source, and this tendency becomes apparent at higher input power. These light scattering results correspond with the spatial intensity distribution of the sonochemiluminescence with luminol. Therefore, it is interpreted that most of the cavitation bubbles contributing to the sonochemical reactions in the standing wave field exist near liquid surface. Present method of light scattering in reference with the image of the sonochemiluminescence is promising for evaluating spatial distribution of violently oscillating cavitation bubbles effective for sonochemical reactions.     

Effect of guest molecule flexibility in access to dendritic interiors

[structure: see text] Dendrimers are attractive scaffolds for catalysis, since catalytic sites can be isolated and the catalysts are recoverable and reusable. Herein, we show that conformationally constrained molecules have better access to dendritic cores compared to the more flexible counterparts. The results reported here should have implications in utilizing dendrimers as scaffolds for artificial selectivity in catalysis.     

Nitroketene acetal chemistry. 3. Facile synthesis of nitroacetic acid triarylmethyl ortho esters from 1,1-di(methylsulfanyl)-2-nitroethylene

The reaction of 1,1-di(methylsulfanyl)-2-nitroethylene, benzyl alcohols, and sodium hydride furnishes crystalline triarylmethyl ortho esters of nitroacetic acid.     

2D-3D transformation of layered perovskites through metathesis: synthesis of new quadruple perovskites A2La2CuTi3O12 (A = Sr, Ca)

We describe the synthesis of two new quadruple perovskites, Sr(2)La(2)CuTi(3)O(12) (I) and Ca(2)La(2)CuTi(3)O(12) (II), by solid-state metathesis reaction between K(2)La(2)Ti(3)O(10) and A(2)CuO(2)Cl(2) (A = Sr, Ca). I is formed at 920 degrees C/12 h, and II, at 750 degrees C/24 h. Both the oxides crystallize in a tetragonal (P4/mmm) quadruple perovskite structure (a = 3.9098(2) and c = 15.794(1) A for I; a = 3.8729(5) and c = 15.689(2) A for II). We have determined the structures of I and II by Rietveld refinement of powder XRD data. The structure consists of perovskite-like octahedral CuO(4/2)O(2/2) sheets alternating with triple octahedral Ti(3)O(18/2) sheets along the c-direction. The refinement shows La/A disorder but no Cu/Ti disorder in the structure. The new cuprates show low magnetization (0.0065 micro(B) for I and 0.0033 micro(B) for II) suggesting that the Cu(II) spins are in an antiferromagnetically ordered state. Both I and II transform at high temperatures to 3D perovskites where La/Sr and Cu/Ti are disordered, suggesting that I and II are metastable phases having been formed in the low-temperature metathesis reaction. Interestingly, the reaction between K(2)La(2)Ti(3)O(10) and Ca(2)CuO(2)Cl(2) follows a different route at 650 degrees C, K(2)La(2)Ti(3)O(10) + Ca(2)CuO(2)Cl(2) --> CaLa(2)Ti(3)O(10) + CaCuO(2) + 2KCl, revealing multiple reaction pathways for metathesis reactions.     

Applications of generalized inverses to interval linear programs in hilbert spaces

Let H₁ and H₂ be real Hilbert spaces. Suppose H₂ is partially ordered, a, b ? H₂ c ? H₁ and A :H₁ → H₂ is a continuous linear map. We consider the following interval linear program: Maximize subject to a ≤ Ax ≤ b.

Conditions under which explicit solutions to the above problem can be found are studied. The solutions are represented in terms of generalized inverses of A. Several examples are given to illustrate the main results.     

A Routing Algorithm Framework for Survivable Optical Networks Based on Resource Consumption Minimization

In this paper, we consider the problem of determining primary and backup paths for survivable optical wavelength-division multiplexed mesh networks. We propose a distributed routing mechanism, which is called Least Resource Consumption Routing, that tries to minimize the combined cost of the primary and the backup paths. The proposed cost model includes the effect of various factors such as mean load, variance of the load on the route, number of converters required by the route, and the length of the route. Further, we model the route cost in such a way that it is extensible to include any new parameters and vary their relative importance. The performance studies conducted for the 14-node National Science Foundation Network and a 30-node topology show that the proposed scheme leads to significant improvements in blocking probability at low and moderate loads. Further, the proposed cost model also reduces the number of converters required to obtain a target blocking performance as compared to some other techniques proposed in the literature.