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81.
In the reaction of paraoxon with alkali metal ethoxides, ion-paired EtO-M+ species are more reactive than the dissociated EtO- with the reactivity order EtO-Li+ EtO-Na+ > EtO-K+ > EtO-, while in the reaction of parathion, the reactivity follows the order EtO-K+ > EtO- > EtO-Na+ > EtO-Li+. 相似文献
82.
83.
Seung-Chul Lee Young-Deuk Jeon Jong-Kee Kwon Jongdae Kim 《Solid-State Circuits, IEEE Journal of》2007,42(12):2688-2695
This paper describes a 10-bit 205-MS/s pipeline analog-to-digital converter (ADC) for flat panel display applications with the techniques to alleviate the design limitations in the deep-submicron CMOS process. The switched source follower combined with a resistor-switch ladder eliminates the sampling switches and achieves high linearity for a large single-ended input signal. Multistage amplifiers adopting the complementary common-source topology increase the output swing range with lower transconductance variation and reduce the power consumption. The supply voltage for the analog blocks is provided by the low drop-out regulator for a high power-supply rejection ratio (PSRR) under the noisy operation environment. The pipeline stages of the ADC are optimized in the aspect of power consumption through the iterated calculation of the sampling capacitance and transconductance. The ADC occupies an active area of 1.0 mm2 in a 90-nm CMOS process and achieves a 53-dB PSRR for a 100-MHz noise tone with the regulator and a 55.2-dB signal-to-noise-and-distortion ratio for a 30-MHz 1.0-VPP single-ended input at 205 MS/s. The ADC core dissipates 40 mW from a 1.0-V nonregulated supply voltage. 相似文献
84.
Kyung Ah Jeon Hyo Jeong Son Chang Eun Kim Jong Hoon Kim Sang Yeol Lee 《Physica E: Low-dimensional Systems and Nanostructures》2007,37(1-2):222
ZnO nanowires were fabricated on c-plane (0 0 0 1), a-plane (1 1 2¯ 0) sapphire, and boron doped p-type (1 0 0) Si substrates in vacuum furnace by simple physical vapor deposition. Room temperature photoluminescence spectra of the nanowires show the near band-edge emission and the deep-level green light emission. The ZnO nanowires formed on sapphire (1 1 2¯ 0) substrates exhibited enhancement on optical properties and better crystalline structures than those of nanowires grown on other substrates. The formation mechanism and the effect of substrate direction on structural and optical properties of the nanowires are discussed. 相似文献
85.
A 9‐bit 80‐MS/s CMOS pipelined folding analog‐to‐digital converter employing offset‐canceled preamplifiers and a subranging scheme is proposed to extend the resolution of a folding architecture. A fully differential dc‐decoupled structure achieves high linearity in circuit design. The measured differential nonlinearity and integral nonlinearity of the prototype are ×0.6 LSB and ×1.6 LSB, respectively. 相似文献
86.
Soyoung Yun Eunok Lee Young-Kwon Park Soon-Yong Jeong Jeongsik Han Byunghun Jeong Jong-Ki Jeon 《Research on Chemical Intermediates》2011,37(9):1215-1223
In this study, in order to develop catalysts for the selective isomerization of higher paraffin, the hydroisomerization reaction of n-dodecane was performed as a model reaction. Pt/ZSM-48, Pt/HZSM-5, Pt/HY, and Pt/SAPO-11 were examined for the selective hydroisomerization of n-dodecane. The catalysts were characterized via X-ray powder diffraction, N2 adsorption, and the temperature-programmed desorption of ammonia. Among the catalysts studied, the Pt/HZSM-48 catalyst exhibited the best isomerization selectivity in the hydroisomerization reaction of n-dodecane, which is attributed to the moderate acid sites and medium-sized pores present in the HZSM-48. The highest iso-dodecane yield was obtained at a reaction temperature of 280 °C in the Pt/HZSM-48 catalyst. The optimal selectivity of the n-dodecane hydroisomerization over the Pt/SAPO-11 catalyst was obtained at approximately 300 °C, which was slightly higher than that of the Pt/HZSM-48 catalyst. 相似文献
87.
Hongkyu Eoh Youngdoo Jung Chanho Park Chang Eun Lee Tae Hyun Park Han Sol Kang Seungbae Jeon Du Yeol Ryu June Huh Cheolmin Park 《Advanced functional materials》2022,32(1):2103697
Structural color (SC) arising from a periodically ordered self-assembled block copolymer (BCP) photonic crystal (PC) is useful for reflective-mode sensing displays owing to its capability of stimuli-responsive structure alteration. However, a set of PC inks, each providing a precisely addressable SC in the full visible range, has rarely been demonstrated. Here, a strategy for developing BCP PC inks with tunable structures is presented. This involves solution-blending of two lamellar-forming BCPs with different molecular weights. By controlling the mixing ratio of the two BCPs, a thin 1D BCP PC film is developed with alternating in-plane lamellae whose periodicity varies linearly from ≈46 to ≈91 nm. Subsequent preferential swelling of one-type lamellae with either solvent or non-volatile ionic liquid causes the photonic band gap of the films to red-shift, giving rise to full-visible-range SC correlated with the pristine nanostructures of the blended films in both liquid and solid states. The BCP PC palette of solution-blended binary solutions is conveniently employed in various coating processes, allowing facile development of BCP SC on the targeted surface. Furthermore, full-color SC paintings are realized with their transparent PC inks, facilitating low-power pattern encryption. 相似文献
88.
The large deviation principle (LDP) which has been effectively used in queueing analysis is the sample path LDP, the LDP in a function space endowed with the uniform topology. Chang [5] has shown that in the discrete-time G/D/1 queueing system under the FIFO discipline, the departure process satisfies the sample path LDP if so does the arrival process. In this paper, we consider arrival processes satisfying the LDP in a space of measures endowed with the weak* topology (Lynch and Sethuraman [12]) which holds under a weaker condition. It is shown that in the queueing system mentioned above, the departure processes still satisfies the sample path LDP. Our result thus covers arrival processes which can be ruled out in the work of Chang [5]. The result is then applied to obtain the exponential decay rate of the queue length probability in an intree network as was obtained by Chang [5], who considered the arrival process satisfying the sample path LDP. 相似文献
89.
The radical addition reactions of α-substituted β,β-difluorovinyl sulfones 1 with α-oxy and acyl radical species, such as 1,3-dioxolane, tetrahydrofuran, 1,4-dioxane, butanal and hexanal, afforded radical addition products 2--16 in good yields. 相似文献
90.
We design and fabricate ultra-high-quality (Q) photonic nanocavities in a symmetrically glass-clad silicon (Si) two-dimensional (2D) photonic crystal (PhC) structure. We theoretically investigate the dependence of the refractive index of the glass on the Q factors for asymmetric and symmetric structures. We show that the index-symmetric distribution of the glass is a critical factor to realize ultrahigh Q factors for glass-clad 2D PhC structures. We fabricate symmetrically glass-clad Si PhC nanocavities and achieve a record Q factor of 1×10(6), comparable with the highest Q factors of nanocavities in air-bridge structures. 相似文献