全文获取类型
收费全文 | 1429篇 |
免费 | 76篇 |
国内免费 | 10篇 |
专业分类
化学 | 743篇 |
晶体学 | 17篇 |
力学 | 20篇 |
数学 | 49篇 |
物理学 | 233篇 |
无线电 | 453篇 |
出版年
2024年 | 5篇 |
2023年 | 28篇 |
2022年 | 32篇 |
2021年 | 51篇 |
2020年 | 26篇 |
2019年 | 39篇 |
2018年 | 23篇 |
2017年 | 25篇 |
2016年 | 48篇 |
2015年 | 49篇 |
2014年 | 54篇 |
2013年 | 102篇 |
2012年 | 112篇 |
2011年 | 105篇 |
2010年 | 79篇 |
2009年 | 70篇 |
2008年 | 94篇 |
2007年 | 74篇 |
2006年 | 72篇 |
2005年 | 81篇 |
2004年 | 67篇 |
2003年 | 63篇 |
2002年 | 53篇 |
2001年 | 26篇 |
2000年 | 37篇 |
1999年 | 20篇 |
1998年 | 20篇 |
1997年 | 8篇 |
1996年 | 7篇 |
1995年 | 13篇 |
1994年 | 3篇 |
1993年 | 5篇 |
1992年 | 10篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 6篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有1515条查询结果,搜索用时 10 毫秒
61.
Drop retraction methods are popular means of measuring the interfacial tension between immiscible polymers. Experiments show that two different drop retraction methods, imbedded fiber retraction (IFR) and deformed drop retraction (DDR), give inconsistent results when a surfactant is present on the surface of the drop. These inconsistencies are deemed to be due to dilution of the surfactant and due to gradients in interfacial concentration of surfactant along the drop surface. This physical picture is quantified for the simple case of a Newtonian drop in a Newtonian matrix, with an insoluble, nondiffusive surfactant at the interface. The drop is deformed in computational fluid dynamics simulations by shearing the matrix, and then allowed to retract. Dilution and interfacial tension gradients effects are found to be especially large at the early stages of retraction, making IFR unsuitable for measuring the interfacial tension of surfactant-laden interfaces. The effects of surfactant dilution and gradients are found to persist even at late stages of retraction, causing the DDR method to underestimate the equilibrium interfacial tension significantly. The largest underestimates occur when the drop viscosity is lower than the matrix viscosity. 相似文献
62.
63.
64.
Hyun Ju Kang Md. Abdul Aziz Boyoun Jeon Kyungmin Jo Haesik Yang 《Electroanalysis》2009,21(24):2647-2652
This article describes an electrochemical strategy to achieve low background‐current levels in horse‐radish peroxidase (HRP)‐based electrochemical immunosensors. The strategy consists of (i) the use of an HRP substrate/product redox couple whose formal potential is high and (ii) the use of an electrode that shows moderate electrocatalytic activity for the redox couple. The strategy is proved by a model biosensor using a catechol/o‐benzoquinone redox couple and an indium tin oxide (ITO) electrode. The combined effect of high formal potential and moderate electrocatalytic activity allows o‐benzoquinone electroreduction with minimal catechol electrooxidation and H2O2 electroreduction. The detection limit for mouse‐IgG is 100 pg/mL. 相似文献
65.
Junwon Han Byung Ho Jeon Chang Y. Ryu James J. Semler Young K. Jhon Jan Genzer 《Macromolecular rapid communications》2009,30(18):1543-1548
Interaction chromatography has been employed to validate that adsorption of poly[styrene‐co‐(4‐bromostyrene)] (PBrxS) random copolymers, where x denotes the mole fraction of 4‐bromostyrene (4–BrS) in PBrxS in solution depends on the average number of adsorptive segments, the type of adsorbing substrate, and on the co‐monomer sequence distribution in PBrxS.
66.
Lee JM Min YJ Lee KB Jeon SG Na JG Ryu HJ 《Langmuir : the ACS journal of surfaces and colloids》2010,26(24):18788-18797
The awareness of symptoms of global warming and its seriousness urges the development of technologies to reduce greenhouse gas emissions. Carbon dioxide (CO(2)) is a representative greenhouse gas, and numerous methods to capture and storage CO(2) have been considered. Recently, the technology to remove high-temperature CO(2) by sorption has received lots of attention. In this study, hydrotalcite, which has been known to have CO(2) sorption capability at high temperature, was impregnated with K(2)CO(3) to enhance CO(2) sorption uptake, and the mechanism of CO(2) sorption enhancement on K(2)CO(3)-promoted hydrotalcite was investigated. Thermogravimetric analysis was used to measure equilibrium CO(2) sorption uptake and to estimate CO(2) sorption kinetics. The analyses based on N(2) gas physisorption, X-ray diffractometry, Fourier transform infrared spectrometry, Raman spectrometry, transmission electron microscopy, scanning electron microscopy, and energy dispersive X-ray spectroscopy were carried out to elucidate the characteristics of sorbents and the mechanism of enhanced CO(2) sorption. The equilibrium CO(2) sorption uptake on hydrotalcite could be increased up to 10 times by impregnation with K(2)CO(3), and there was an optimal amount of K(2)CO(3) for a maximum equilibrium CO(2) sorption uptake. In the K(2)CO(3)-promoted hydrotalcite, K(2)CO(3) was incorporated without changing the structure of hydrotalcite and it was thermally stabilized, resulting in the enhanced equilibrium CO(2) sorption uptake and fast CO(2) sorption kinetics. 相似文献
67.
Hyung-Geun Moon You-Sun Kim Jun-Pyo Choi Dong-Sic Choi Chang Min Yoon Seong Gyu Jeon Yong Song Gho Yoon-Keun Kim 《Experimental & molecular medicine》2010,42(1):47-60
Theophylline is commonly used to treat severe asthma and chronic obstructive pulmonary disease (COPD) characterized by non-eosinophilic inflammation. Acetyl salicylic acid (ASA) is one of the most widely used medications worldwide, but up to 20% of patients with asthma experience aggravated respiratory symptoms after taking ASA. Here we evaluated the adverse effect of ASA on the therapeutic effect of theophylline in mice with non-eosinophilic asthma. A non-eosinophilic asthma mouse model was induced by airway sensitization with lipopolysaccharide-containing allergen and then challenged with allergen alone. Therapeutic intervention was performed during allergen challenge. Theophylline inhibited lung inflammation partly induced by Th1 immune response. ASA attenuated the beneficial effects of theophylline. However, co-administration of the ASA metabolite salicylic acid (SA) showed no attenuating effect on theophylline treatment. The therapeutic effect of theophylline was associated with increase in cAMP levels, which was blocked by co-treatment of theophylline and ASA. ASA co-treatment also attenuated the anti-inflammatory effects of a specific phosphodiesterase 4 inhibitor. These results demonstrate that ASA reverses anti-inflammatory effects of theophylline, and that ASA exerts its adverse effects through the inhibition of cAMP production. Our data suggest that ASA reverses lung inflammation in patients taking theophylline, although clinical evidence will be needed. 相似文献
68.
69.
Sunhee Lee Eunyoung Jeon Yeontae Jung Jinwon Lee 《Applied biochemistry and biotechnology》2012,167(1):24-38
The goal of the present study was to increase the content of intracellular long-chain fatty acids in two bacterial strains, Pseudomonas aeruginosa PA14 and Escherichia coli K-12 MG1655, by co-overexpressing essential enzymes that are involved in the fatty acid synthesis metabolic pathway. Recently, microbial fatty acids and their derivatives have been receiving increasing attention as an alternative source of fuel. By introducing two genes (accA and fabD) of P. aeruginosa into the two bacterial strains and by co-expressing with them the fatty acyl?Cacyl carrier protein thioesterase gene of Streptococcus pyogenes (strain MGAS10270), we have engineered recombinant strains that are efficient producers of long-chain fatty acids (C16 and C18). The recombinant strains exhibit a 1.3?C1.7-fold increase in the production of long-chain fatty acids over the wild-type strains. To enhance the production of total long-chain fatty acids, we researched the carbon sources for optimized culture conditions and results were used for post-culture incubation period. E. coli SGJS17 (containing the accA, fabD, and thioesterase genes) produced the highest content of intracellular total fatty acids; in particular, the unsaturated fatty acid content was about 20-fold higher than that in the wild-type E. coli. 相似文献
70.
D. W. Kim B. K. Jeon C. S. Kim Y. S. Jeon 《Journal of Radioanalytical and Nuclear Chemistry》2000,245(3):509-511
The elution chromatographic separation of magnesium isotopes was investigated by chemical ion exchange with the synthesized 1,7-dioxa-4,10,13-triazacyclopentadecane-4,10,13-trimerrifield peptide resin [N3O2·3M]. The capacity of novel N3O2 azacrown ion exchanger was 0.21 meq/g dry resin. The heavier isotopes of magnesium concentrated in the resin phase, while the lighter isotopes are enriched in the solution phase. The glass ion exchange column used in our experiment was 30 cm long with inner diameter of 0.2 cm, and the 2.0M NH4Cl solution was used as an eluent. The separation factors of 24Mg-25Mg, 25Mg-26Mg, and 24Mg-26Mg were 1.030, 1.009, and 1.027, respectively. 相似文献