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151.
As a new model of chemical assay-guided natural product isolation, an effective chemodosimetric assay system was devised. Our chemical assay system features a fluorogenic chemodosimeter immobilized on a solid support, which offers advantages in identifying the desired compounds in complex natural product mixtures. To isolate only compounds with the target functional groups, the click chemistry concept was adopted. The model system presented here was developed for natural products with a terminal alkyne. Using our newly designed alkyne sensing beads with the aforementioned features, we have readily identified, quantified, and isolated compounds with a terminal alkyne group from plant extracts. 相似文献
152.
153.
Farzana Ahmad Young Jae Jeon 《International Journal of Polymer Analysis and Characterization》2017,22(8):659-668
In this study, the dye-doped polymer dispersed liquid crystals (PDLC) gratings techniques performed by the various research groups or being developed are briefly reviewed. Especially, the electrically switched diffraction and holographic gratings, have attained much attention by various research groups working in the PDLC-related display studies. The fabrication methodologies used for such grating texture, include like the conventional dye-doped PDLC grating, Azo-dye doped PDLC gratings, and lasing techniques etc., adopted for dye-doped PDLC gratings. The useful features and characteristics of their fabrication process of such gratings are discussed. Finally, some of the future perspectives on this particular research field are presented. 相似文献
154.
Axisymmetric problem of a nonhomogeneous elastic layer 总被引:3,自引:0,他引:3
Summary The paper deals with a theoretical treatment of elastic behavior for a medium with nonhomogeneous materials property, which
is defined by the relation , i.e., shear modulus of elasticity G varies with the dimensionless axial coordinate by the power product form, arbitrarily. Fundamental differential equation for such nonhomogeneous medium has been already
proposed in [5]. It is given by a second-order partial differential equation. However, it was found that the fundamental equation
is not sufficient in general to solve several kinds of boundary-value problems. On the other hand, it is shown in the present
paper making use of the fundamental equations system for a nonhomogeneous medium, which has been proposed in our previous
paper [7], it is possible to solve axisymmetric problems for a thick plate (layer) subjected to an arbitrarily distributed
load or a concentrated load on its surfaces. Numerical calculations are carried out for several cases, taking into account
the variation of the nonhomogeneous parameter m. The numerical results for displacements stress and components are shown in graphical form.
Accepted for publication 25 March 1997 相似文献
155.
20% External Quantum Efficiency in Solution‐Processed Blue Thermally Activated Delayed Fluorescent Devices
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Yong Joo Cho Byung Doo Chin Sang Kyu Jeon Jun Yeob Lee 《Advanced functional materials》2015,25(43):6786-6792
Highly efficient solution‐processed blue thermally activated delayed fluorescent (TADF) devices are developed by designing soluble blue TADF emitters. The solubility and emission color could be managed by introducing F as an electron withdrawing unit instead of CN. Two soluble blue TADF emitters are synthesized and show a high external quantum efficiency of 20.0% with a color coordinate of (0.16,0.26), and it is the best quantum efficiency reported in solution‐processed TADF devices. The device performances of the solution‐processed blue TADF devices are comparable to those of vacuum‐processed blue TADF devices. 相似文献
156.
Fluorine: Edge‐Fluorinated Graphene Nanoplatelets as High Performance Electrodes for Dye‐Sensitized Solar Cells and Lithium Ion Batteries (Adv. Funct. Mater. 8/2015)
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157.
An efficient synthetic method has been developed for the synthesis of 2-arylacrylic esters from the corresponding aryl methyl ketones via Wittig reaction and singlet oxygen ene reaction. Wittig reaction to aryl methyl ketones with (methoxymethyl)triphenylphosphonium chloride in basic condition afforded the methyl enol ethers, and then 2-arylacrylic esters were obtained by singlet oxygen ene reaction, followed by tosylation and elimination in one-pot to the methyl enol ethers in good yields. 相似文献
158.
Parent ME Yang J Jeon Y Toney MF Zhou ZL Henze D 《Langmuir : the ACS journal of surfaces and colloids》2011,27(19):11845-11851
Electrophoretic inks, which are suspensions of colorant particles that are controllably concentrated and dispersed by applied electric fields, are the leading commercial technology for high-quality reflective displays. Extending the state of the art for high-fidelity color in these displays requires improved understanding and control of the colloidal systems. In these inks, reverse micelles in nonpolar media play key roles in media and particle charging. Here we investigate the effect of surfactant structure on reverse micelle size and charging properties by synthesizing different surfactants with variations in polyamine polar head groups. Small-angle X-ray scattering (SAXS) and dynamic light scattering (DLS) were used to determine the micelle core plus shell size and micelle hydrodynamic radius, respectively. The results from SAXS agreed with DLS and showed that increasing polyamines in the surfactant head increased the micelle size. The hydrodynamic radius was also calculated on the basis of transient current measurements and agreed well with the DLS results. The transient current technique further determined that increasing polyamines increased the charge stabilization capability of the micelles and that an analogous commercial surfactant OLOA 11000 made for a lower concentration of charge-generating ions in solution. Formulating magenta inks with the various surfactants showed that the absence of amine in the surfactant head was detrimental to particle stabilization and device performance. 相似文献
159.
Soyoung Yun Eunok Lee Young-Kwon Park Soon-Yong Jeong Jeongsik Han Byunghun Jeong Jong-Ki Jeon 《Research on Chemical Intermediates》2011,37(9):1215-1223
In this study, in order to develop catalysts for the selective isomerization of higher paraffin, the hydroisomerization reaction of n-dodecane was performed as a model reaction. Pt/ZSM-48, Pt/HZSM-5, Pt/HY, and Pt/SAPO-11 were examined for the selective hydroisomerization of n-dodecane. The catalysts were characterized via X-ray powder diffraction, N2 adsorption, and the temperature-programmed desorption of ammonia. Among the catalysts studied, the Pt/HZSM-48 catalyst exhibited the best isomerization selectivity in the hydroisomerization reaction of n-dodecane, which is attributed to the moderate acid sites and medium-sized pores present in the HZSM-48. The highest iso-dodecane yield was obtained at a reaction temperature of 280 °C in the Pt/HZSM-48 catalyst. The optimal selectivity of the n-dodecane hydroisomerization over the Pt/SAPO-11 catalyst was obtained at approximately 300 °C, which was slightly higher than that of the Pt/HZSM-48 catalyst. 相似文献
160.
We synthesized five novel uridine-based cationic nucleolipids, introducing basic amino acid residues at the 5' position of uridine, through 1,3-dipolar cycloaddition, and hydrophobic alkyl moieties at the 2' and 3' positions, through carbamate linkages. Their lipoplexes delivered siRNAs efficiently to cells, in vitro, without any severe toxicity. 相似文献