Physical aging of a polyetherimide: Creep and DSC measurements

Creep and differential scanning calorimetry (DSC) measurements have been used to study the physical aging behavior of a polyetherimide. Isothermal aging temperatures ranged from 160°C to T_g with aging times ranging from 10 min to 8 days. The only measurable effect of physical aging on the short-time creep curves is a shift of the creep compliance to longer times. Andrade plots of the compliance versus the cube root of time are linear at short times with the slope β decreasing with increasing aging time to a constant value once equilibrium is reached. Log β³ is related directly to the degree to which the creep curves shift to longer times with physical aging, and is used in this work as a measure of physical aging. A reduced curve of log β³ versus log aging time is obtained for the aging temperatures investigated by appropriate vertical and horizontal shifts. The enthalpy change during aging increases linearly with the logarithm of the aging time, t_a, leveling off at equilibrium at values which increase with decreasing aging temperature. Hence, both nonequilibrium and equilibrium temperature shift factors can be calculated from the DSC data. Good agreement is observed between the equilibrium temperature shift factors obtained from the creep and DSC data. The temperature dependence of the nonequilibrium temperature shift factors is found to be an order of magnitude smaller than that of the equilibrium shift factors. The time scales to reach equilibrium for enthalpy and for mechanical measurements are found to be the same within experimental error. © 1995 John Wiley & Sons, Inc.     

The effect of crystallinity on chain mobility and free volume in the amorphous regions of a miscible polycarbonate/polyester blend

Homopolymers and blends of polycarbonate/ThermX have been investigated by differential scanning calorimetry, dynamic mechanical analysis, density measurements, and positron annihilation lifetime spectroscopy. The study focuses on the chain mobility and free volume in the amorphous miscible regions of the blends and how this mobility and free volume are affected by increasing crystallinity. It is proposed that judicious annealing, which results in increasing crystallinity (while avoiding ageing or transesterification), induces a constraint on the amorphous region leading to an increase in T_g and coalescence of free volume sites. © 1994 John Wiley & Sons, Inc.     

On the optimum design of unitary cyclic group space-time codes

In this letter, based on the exact pairwise-error probability, we derive the union bound on the symbol-error probability (SEP) of the differential unitary space-time (DUST) modulation employing group codes. Instead of using the rank-and-determinant or Euclidean distance criteria, we optimize the cyclic group codes such that the union bound on the SEP is minimized for a predetermined scenario, taking into account the number of transmit and receive antennas and the operating signal-to-noise ratio (SNR). Our simulation results show that for a wide range of SNRs, the codes with the minimum union bound for a particular SNR outperform the codes designed based on rank-and-determinant or Euclidean distance criteria.     

当道路难行时,尽快转向无带方向——Sony XDCAM HD高清系统全程支持2006陆虎G4越野挑战赛

陆虎（Land Rover）G4越野挑战赛．是各大汽车公司彼此互相交流的重大活动。经过三年多的精心准备．2006年G4挑战赛正式拉开了帷幕——一个月时间，18组挑战者．4000公里行程．跨越泰国、老挝、巴西和波利维亚。本届赛事是2003年G4挑战赛的延续．它的前身就是2000年结束的“骆驼杯”越野挑战赛。     

Approximate neutrality of large-Z ions

LetN(Z) denote the number of electrons which a nucleus of chargeZ can bind in non-relativistic quantum mechanics (assuming that electrons are fermions). We prove thatN(Z)/Z1 asZ.Research partially supported by the NSERC under Grant NA7901 and by the USNSF under Grants DMS-8416049 and PHY 85-15288-A01     

Lifshitz tails for periodic plus random potentials

We prove that the integrated density of states () for a potentialW =V _per +V has Lifshitz tails where V_per is a periodic potential with reflection symmetry andV is a random potential, e.g., of the formV =q _i ()f(x–i).research partially supported by DFG.research partially supported by USNSF under grant No. MCS-81-20833.