甲基二氯硅烷—甲苯等压汽液平衡研究

用泵式沸点仪测定了甲基二氯硅烷—甲苯二元系在常压下的汽液平衡数据,并用间接法由ＴＰＸ 推算了与之平衡的汽相组成,用最小二乘法求出了该系统的液相活度系数模型参数,由模型参数推算的泡点温度与实验值符合良好,所得数据通过了热力学一致性检验。     

Exploring the role of samarium in the modification of rhodium catalysts through surface science approach

In this paper we review the preparation and reaction properties of ordered SmRh surface alloys and SmO_x/Rh(1 0 0) model catalyst which have been systematically investigated by low energy electron diffraction (LEED), Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), high-resolution electron energy loss spectroscopy (HREELS) and temperature desorption spectroscopy (TDS). The growth of Sm on Rh(1 0 0) at room temperature follows the Stranski-Krastanov mode. Thermal treatment of the Sm films on Rh(1 0 0) leads to the formation of ordered SmRh surface alloys. An “inverse” SmO_x/Rh(1 0 0) model catalyst is produced under controlled oxidation of the SmRh surface alloy. CO adsorption on the SmRh alloy and SmO_x/Rh(1 0 0) surfaces gives rise to five TDS characteristic features originating from different adsorption sites. Both the site blocking of SmO_x and the electron transfer between SmO_x and Rh substrate significantly affect the CO adsorption. Acetate decomposition on both Rh(1 0 0) and the SmO_x/Rh(1 0 0) surfaces are found to undergo two competitive pathways that yields either (i) CO(a) and O(a) or (ii) CO₂(g) and H₂(g) at high temperature. The reactive desorption of acetic acid on SmO_x/Rh(1 0 0) is dramatically different from that on Rh(1 0 0). A rapid decomposition of acetic acid to produce CO(g) and CO₂(g) can be observed only on SmO_x/Rh(1 0 0), where CO(g) becomes the predominant product at 225 K, indicating a strong promotional effect of SmO_x in the selective decomposition of acetate. Finally, we briefly describe the future outlook of research on rare earth oxide/metal model catalysts.     

An approach for optimization of loading cycles of hydraulic mining excavators

The present paper describes an optimization multi-stage approach for computing the optimal loading cycle of a heavy weight excavator along a predefined trajectory under dynamic constraints such as maximal ensuing forces, accelerations, and maximal allowed hydraulic power. The approach involves the use of splines of 3rd and 5th order for smooth interpolation of the spatial trajectory up to the level of linear and angular accelerations, as well as an SQP optimization routine to find the optimal end-effector motion law along the trajectory, which finally leads to strokes and pressures at the hydraulic actuators as a function of time. The approach can also be extended to other multi-body systems following a predetermined trajectory. The solution scheme can be included in a more general optimization routine aiming to optimize the trajectory itself. (© 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Fabrication of CdSe composite by using the amphiphilic block copolymer as template

CdSe nanoparticles of improved stability against aggregation were synthesized by using amphiphilic block copolymer polyacrylonitrile-block-poly(ethylene glycol)-block-polyacrylonitrile (PAN-b-PEG-b-PAN, PEA). The products were characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopic (HRTEM). The optical properties were characterized by UV-vis spectrophotometer and the room temperature photoluminescence (PL). The results revealed that the CdSe nanoparticles have been uniformly distributed throughout the copolymer with diameters of 6-7 nm and the produced novel hybrid nanocomposites displayed obviously quantum size effects and interesting fluorescence features. FTIR results provided the information on the interaction between the copolymer and the nanoparticles. The TGA revealed that the thermal property of the copolymer enhanced due to the interaction of the nanoparticles and the groups of the copolymer.     

Symmetrical broken and nonlinear response of Weyl semimetal TaAs influenced by the topological surface states and Weyl nodes

A Weyl semimetal (WSM) features Weyl fermions in its bulk and topological surface states on surfaces, and is novel material hosting Weyl fermions, a kind of fundamental particles. The WSM was regarded as a three‐dimensional version of “graphene” under the illusion. In order to explore its promising photoelectric properties and applications in photonics and photoelectronics, here, we study the anisotropic linear and nonlinear optical responses of a WSM TaAs, which are determined by the relationship and balance between its topological surface states and Weyl nodes. We demonstrate that topological surface states which break the bulk symmetry are responsible for the anisotropy of the mobility, and the anisotropic nonlinear response shows saturable characteristic with extremely large saturable intensity. We also find that the mobility is anisotropic with the magnitude of 10⁴ cm²V⁻¹s⁻¹ at room temperature and can be accelerated by the optical field. By analyzing the symmetry, the nonlinear response is mainly contributed by the fermions close to the Weyl nodes, and is related to the Pauli's blocking of fermions, electron‐electron interaction. This work experimentally discovers the anisotropic ultrahigh mobility of WSMs in the optical field and may start the field for the applications of WSMs in photonics and photoelectronics.

     

基于用户体验质量和系统能耗的异构网络联合接入选择和功率分配策略

为了解决无线网络能耗和用户体验质量的问题,提出了一种应用于异构无线网络环境的基于多目标优化的联合接入选择和功率分配策略。该策略以最小化系统整体能耗和最大化用户平均体验质量为目标,建立了多目标优化联合分配模型,通过差分进化算法得到联合分配模型的最优解集,并结合 TOPSIS 的方法从最优解集中得到折中的联合分配方案。仿真结果表明,本文所提的策略能够有效地降低系统能耗,并提升用户整体的服务体验。     

一种数字微镜器件的倒装封装设计

数字微镜器件是由MEMS工艺制成的数字式光反射开关阵列组成,其I/O管脚工作频率高达800 MHz。针对数字微镜器件的对光电两方面性能的严格要求,设计了一种数字微镜器件的封装结构。首先选择倒装封装技术来减小寄生参数,提高器件响应速度;其次优化了板层结构,采用玻璃基底和遮光层来满足光学要求;最后通过对信号完整性和电源完整性问题的仿真设计,满足了电学性能要求,完善了封装基板设计流程。对制作出的微镜器件封装进行测试,在800 MHz的数据频率下,眼图结果与仿真结果较为吻合,降低了封装对信号完整性的影响,达到封装设计要求的指标。     

一种适合3G移动的微支付方案

本方案提出利用改进后3G入网认证机制中密钥和随机数,结合AES算法生成安全性高的一次性签名,且计算量和存储量很少,具有不可否认性,还利用了登录第三方网站后生成的用户临时标识,具有很好的匿名性和不可跟踪性。其中商家受到第三方的监视和管理,防止用户和商家的欺诈,用户收到商品后对商家的信用进行评价,具有公平性。该方案交易灵活、效率高,适合3G用户实行微支付交易。     

High-spin states in 160Lu

High-spin states of ¹⁶⁰Lu have been studied through the ¹⁴⁴Sm( ¹⁹F, 3n) reaction. The previously known πh _11/2⊗υi _13/2 yrast band is extended from I ^π = 21^- to 25^- and a four quasiparticle band with configuration πh _11/2[523]7/2 ^-⊗υh _9/2[521]3/2 ^-⊗ (υi _13/2)² is reported. Received: 21 May 2001 / Accepted: 19 July 2001     

氮在含氧Mo(100)面上的吸附与反应

 用HREELS, AES, LEED和TDS考察了氮在含氧Mo(100)上的吸附和热脱附. 120 K下氮在含氧Mo(100)上吸附时存在着N—N伸缩振动频率2150和1600 cm-1, 分别对应于线式(γ态)和侧位(α态)两种分子吸附态. 升温引起γ态氮的脱附和α态氮的解离. 其中γ态氮的脱附峰温位于155 K, 遵循一级脱附动力学; 由α态解离生成的N原子占据Mo(100)的四重空位(即β态), 并在高于1?150 K的温度重新化合形成氮而脱附. 120 K时,氮的吸附是无序的; 吸附了氮的表面经1100 K退火后生成了有序的c(2×2)-N表面结构.