新型蓝绿发光材料ZnSe／BeTe超晶格的能带剪裁

由于器件的快速退化，101.5小时似乎成了Znse基蓝绿色半导体激光器难于逾越的寿命极限。分析退化机制，发现在强电流注入的半导体激光器中，热退化具有重要影响。研究表明，用作载流子限制层的宽带Ⅱ-Ⅵ族四元合金（如ZnMgSSe）只能对ZnSe中的电子有效地限制，无法对空穴很好地限制;而对BeTe，却只能对空穴进行有效的限制，无法对电子很好地限制。这导致ZnSe（或BeTe）活性层空穴（或电子）漏电发热，引起退化。本文提出以ZnSe／BeTe超晶格为蓝绿发光层，并用包络函数理论具体计算了阱宽、垒宽对载流子能级的不同影响，考察了ZnSe、BeTe厚度比和超晶格周期对带隙、载流子限制能力的调节。为研制新型长寿命蓝绿色半导体激光器提供了一条新的途径。     

Graphitic nanofillers in PMMA nanocomposites—An investigation of particle size and dispersion and their influence on nanocomposite properties

Mechanical, thermal, and electrical properties of graphite/PMMA composites have been evaluated as functions of particle size and dispersion of the graphitic nanofiller components via the use of three different graphitic nanofillers: “as received graphite” (ARG), “expanded graphite,” (EG) and “graphite nanoplatelets” (GNPs) EG, a graphitic materials with much lower density than ARG, was prepared from ARG flakes via an acid intercalation and thermal expansion. Subsequent sonication of EG in a liquid yielded GNPs as thin stacks of graphitic platelets with thicknesses of ～10 nm. Solution‐based processing was used to prepare PMMA composites with these three fillers. Dynamic mechanical analysis, thermal analysis, and electrical impedance measurements were carried out on the resulting composites, demonstrating that reduced particle size, high surface area, and increased surface roughness can significantly alter the graphite/polymer interface and enhance the mechanical, thermal, and electrical properties of the polymer matrix. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2097–2112, 2007     

Investigation on crosslinking behaviors of NBR/PVC filled with anhydrous copper sulfate particles by dynamic mechanical analysis

Crosslinking behaviors of acrylonitrile butadiene rubber (NBR)/poly (vinyl chloride) (PVC) alloy, filled with anhydrous copper sulfate (CuSO₄) particles, were investigated for the first time by dynamic mechanical analysis (DMA) under hetero and isothermal modes, respectively. In the heterothermal testing, (NBR/PVC)/CuSO₄ compound showed two marked increases in the storage modulus (E′), corresponding to coordination crosslinking of NBR-CuSO₄ and self-crosslinking of NBR and PVC respectively. During the isothermal testing, a dramatic increase in E′ was found at the initial stage while that of original NBR/PVC alloy was not detected. The marked increase in E′ of (NBR/PVC)/CuSO₄ compound was mainly due to the crosslinking induced by coordination between  CN and Cu²⁺. The increasing extent of E′ increased with the rise of CuSO₄ content, suggesting the formation of a greater number of crosslinks. Moreover, the activation energy (E_a) of crosslinking process was about 139 kJ/mol. In this work, fourier transform infrared spectrum (FT-IR) and equilibrium swelling method were also performed for the characterization of the compound. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 41–51, 2007     

CARS光谱测温及仪器狭缝函数对测量的影响

设计了一种利用光参量振荡器(OPO)来代替染料激光器的宽带相干反斯托克斯喇曼散射(CARS)光谱测温实验装置。为了提高CARS测量温度的精度,测量和分析了检测系统中狭缝函数对测量结果的影响,确定了狭缝函数的具体形式。将测量结果与热电偶读数比较,发现在温度范围300K～1200K内,温度测量的不确定度小于2%。     

AnUV-algorithm for semi-infinite multiobjective programming

In this paper, we give an application ofUV-decomposition method of convex programming to multiobjective programming, and offer a new algorithm for solving semi-infinite multiobjective programming. Finally, the superlinear convergence of the algorithm is proved.     

简并光学参量振荡器混沌反控制

提出一种实现简并光学参量振荡器混沌反控制的方法，用正弦信号调制简并光学参量振荡器的基模衰减率，使简并光学参量振荡器从定态输出转化为混沌态.数值模拟结果表明，选择不同的调制幅度和调制角频率，只要满足系统的最大李雅谱诺夫指数大于零，即可实现不同的混沌轨道重构.通过比较最大李雅谱诺夫指数λ_max随调制幅度和调制角频率变化曲线， 指出系统从周期态调制到混沌态比从无亚谐波输出的定态调制到混沌态更容易，有更宽的调制幅度和调制角频率选择范围. 关键词： 简并光学参量振荡器 混沌反控制 调制     

双面金属包覆介质波导模序数的判别方法

在双面金属包覆介质波导中 ,随着介质层厚度的变化 ,会出现TM0 模与TM1 模的分离和简并两种状态 ,从而影响衰减全反射 (ATR)谱中模序数的确认。通过对金属波导的理论分析和实验研究 ,提出了三种模序数确认方法 :本征角计算法、吸收峰全峰半宽比较法和吸收峰峰间距比较法 ,实现了两种状态下对模序数的准确判断     

对流扩散方程的离散技术及数值实验

本文研究了对流扩散方程的离散技术,并进行了大量数值实验。研究表明,scharfetter—Gummel的广义形式可以良好地消除内部的非物理振荡,且对边界层生成振荡的传播有抑制作用,但不能有效地消除边界层振荡。     

非掺杂InP的低温光致发光研究

研究了2K低温下非有意掺杂InP单晶的光致发光谱,对近带边的辐射跃迁进行了仔细分析,报道了InP单晶在大功率光激发时束缚于中性施主的激子跃迁发光相对减弱、而束缚于中性受主的激子跃迁发光相对增强的现象,并探讨了其机制,确认了材料中存在Mg、Zn等残余受主杂质,并计算得到Mg受主的离化能为41.5meV.