Dynamic of the Fluorescence of the Complex Zn++/Bis-N-Carbazolyl-Distyrylbenzene

The discrimination between similar concentrations of the different metal ions is one of the important roles of fluorescent sensors. Here we present the study of the fluorescence dynamic of the chromophore bis-N-carbazolyl-distyrylbenzene (BCDSB) in acetonitrile/water (mmol/L), doped with metal ions such as K+; Ca++; Mg++; Zn++(10 micromol/L). BCDSB has the fluorescence with lambda(max) at 448 nm by excitation at lambda(exc) = 378 nm, lifetime 1.089 ns: quantum yield of the fluorescence is 0.68. With continuation of irradiation fluorescence quenching has been registered for all investigated metal ions. However, in the presence of Zn++ oscillation of the intensity was observed. The energy activation of the oscillation as much as 15 kcal/mol was estimated. We believe, that the specificity of the complex Zn++/BCDSB, is in an asymmetrical structure, formed via binding sites of Zn++ with the electron-enriched binding sites of the BCDSB, excited in n(pi)* state. This asymmetrical complex structure can cause the photoinduced structural fluctuation in the complex coordination.     

Anisotropic percolation and the d-dimensional surface roughening problem

We review recent numerical simulations of several models of interface growth in d-dimensional media with quenched disorder. These models belong to the universality class of anisotropic diode-resistor percolation networks. The values of the roughness exponent δ=0.63±0.01 (d=1+1) and δ=0.48±0.02 (d=2+1) are in good agreement with our recent experiments. The values of δ in higher dimensions (δ=0.38±0.03 in d=4 and δ=0.27±0.05 in d=5) do not support a recent theoretical conjecture.     

Activation of tertiary paraffins by elemental fluorine

Elemental fluroine was found to substitute, in a regio and stereospecific way, tertiary unactivated hydrogens in alkanes - the most unreactive family of organic compounds.     

Selective fluorination of bile acids using elemental fluorine

Specific direct mono fluorinations on various sites of the steroidal skeleton of bile acids were achieved by introduction of electronegative groups at selected points.     

Isotopic dependence of giant multipole resonances

A procedure is presented which allows the application of linear response theory and the random phase approximation to an open shell. The procedure is applied to Ca isotopes. The general features of giant multipole resonances are found to vary smoothly with the mass. The resonances exhibit more structure in the open 1f_{$\text{7}\text{2}$} shell nuclei. While the energy-weighted dipole sum is practically constant in all isotopes, the isoscalar quadrupole and octupole energy weighted sums increase continuously by ~ 30 % from ⁴⁰Ca to ⁴⁸Ca.