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141.
C. W. Stark 《K-Theory》1991,5(4):333-354
We exhibit infinitely many commensurability classes of smooth closed manifolds M
m
, for all m 12, such that the universal cover of M is the product of a sphere and a Euclidean space and such that 1(M) contains finite dihedral subgroups. 相似文献
142.
Three novel methods are used to reconstruct a simulated image from a set of incomplete data spanning a 160 degrees angular range. These methods are the squashing affine transformation of J.A. Reeds and L.A. Shepp (1987), the circular interpolation method derived from the theory of J.J. Clark, M.R. Plamer, and P.D. Lawrence (1985), and the geometry-free reconstruction using the theory of convex projections. These methods are briefly explained, and their reconstructions are compared for the case of limited angular views. 相似文献
143.
Several oxidative approaches namely thiocyanation of aromatic compounds, epoxidation of alkenes, amidation of aromatic aldehydes, epoxidation of α, β-unsaturated ketones, oxidation of sulfides to sulfoxides and sulfones, bayer-villeger reaction, bromination and iodation of aniline and phenol derivatives oxidative esterification, oxidation of pyridines and oxidation of secondary, allylic and benzyllic alcohols were carried out using 1,1,2,2-Tetrahydroperoxy-1,2-Diphenylethane as the potential solid oxidant which can be stored for several months without any loss in its activity. All of the procedures were accomplished via mild reaction conditions and the products were afforded in high yields and short reaction times. 相似文献
144.
Masoud Salavati-Niasari Shirin Shafaie-Arani Mohammad Reza Ganjali Parviz Norouzi 《Transition Metal Chemistry》2006,31(7):964-969
12- and 13-Membered diaza dioxa Schiff-base nickel(II) complexes were successfully prepared in a nanoscale microreactor by
the template condensation of (1,8-diamino-3,6-dioxaoctane)nickel(II) complex with bifunctional diketones within the nanodimensional
pores of zeolite Y. The host–guest nanocatalyst (HGN); ([Ni((R2[12]1,3-dieneN2O2)]2+-NaY, [Ni(R2[13]1,4-dieneN2O2)]2+-NaY; R = H, Me and Ph) is catalytically very efficient as compared to other neat complexes for oxidation of cyclohexene with
molecular oxygen as oxidant in the absence of solvent at 70 °C, affording 2-cyclohexene-1-ol and 2-cyclohexene-1-one. 相似文献
145.
Harries C. Hofmann Fritz Ditmar R. Backer H. J. Stark J. Ruggli P. Nierenstein M. Donath E. Indra A. Eisenlohr F. Pitaval M. R. Hoffmann F. Danneel H. Meyer J. Fischer Franz Rinne F. Block W. Riemann C. Buchner G. Hinneberg P. v. Meyer E. Engler C. Wöhler L. Wallach O. Luther R. Nernst W. Blanc M. Le Kossel A. Kellner O. Immendorff H. Witt O. N. 《Analytical and bioanalytical chemistry》1913,52(10-11):664-668
Analytical and Bioanalytical Chemistry - 相似文献
146.
147.
PHOTOOXIDATION OF 2-MERCAPTOETHANOL BY VARIOUS WATER-SOLUBLE PHTHALOCYANINES IN AQUEOUS ALKALINE SOLUTION UNDER IRRADIATION WITH VISIBLE LIGHT 总被引:1,自引:0,他引:1
Gerhard Schneider Dieter Wohrle Wolfgang Spiller Johannes Stark Günter Schulz-Ekloff 《Photochemistry and photobiology》1994,60(4):333-342
Abstract A selection of charged water-soluble phthalocyanines was employed for the photocatalytic oxidation of 2-mercaptoethanol in aqueous alkaline solution in the presence of oppositely charged detergents. Most efficient are Zn(II) and Al(III) phthalocyaninetetrasulfonic acids, which oxidize the thiolate to the sulfonic acid and sulfate, whereas Co(II)phthalocyaninetetrasulfonic acid does not exhibit a photoeffect. During the photooxidation reactions, decomposition (photobleaching) of the zinc phthalocyanine derivatives occurs, whereas the analogous alumina chelates are more stable. Covalent binding of Zn(II)phthalocyanine derivatives to silica carriers results in photocatalytic activities even in the absence of detergents, since the immobilization of the complexes preserves the required monomeric state. Moreover, the photodecomposition (bleaching) of the heterogenized complexes is strongly retarded. For the photo-oxidations mainly the pathway via the sensitized formation of singlet oxygen with subsequent oxidation reactions is valid. Hydrogen peroxide as one reduction product of oxygen was found. 相似文献
148.
149.
150.
Stark CB Lopes NP Fonseca T Gates PJ 《Chemical communications (Cambridge, England)》2003,(21):2732-2733
We report the use of RuCl3 as an "alkali metal sponge". This is a general and highly efficient method for generating protonated parent ions for a variety of compounds that usually do not show this ion in electrospray mass spectrometry. This technique is demonstrated to be highly useful in "cleaning up" spectra from multiply metallated ions, thereby substantially improving the signal-to-noise ratio. 相似文献