Ultrafast Electron Transfer Kinetics of Graphene Grown by Chemical Vapor Deposition

High electrochemical reactivity is required for various energy and sensing applications of graphene grown by chemical vapor deposition (CVD). Herein, we report that heterogeneous electron transfer can be remarkably fast at CVD‐grown graphene electrodes that are fabricated without using the conventional poly(methyl methacrylate) (PMMA) for graphene transfer from a growth substrate. We use nanogap voltammetry based on scanning electrochemical microscopy to obtain very high standard rate constants k⁰≥25 cm s^?1 for ferrocenemethanol oxidation at polystyrene‐supported graphene. The rate constants are at least 2–3 orders of magnitude higher than those at PMMA‐transferred graphene, which demonstrates an anomalously weak dependence of electron‐transfer rates on the potential. Slow kinetics at PMMA‐transferred graphene is attributed to the presence of residual PMMA. This unprecedentedly high reactivity of PMMA‐free CVD‐grown graphene electrodes is fundamentally and practically important.     

Implications of proxy caching for provisioning networks and servers

In this paper, we examine the potential benefits of Web proxy caches in improving the effective capacity of servers and networks. Since networks and servers are typically provisioned based on a high percentile of the load, we focus on the effects of proxy caching on the tail of the load distribution. We find that, unlike their substantial impact on the average load, proxies have a diminished impact on the tail of the load distribution. The exact reduction in the tail and the corresponding capacity savings depend on the nature of the workload and the percentile of the load distribution chosen for provisioning networks and servers-the higher the percentile, the smaller the savings. For workloads considered in this study, compared with over a 50% reduction in the average load, the savings in network and server capacity was only 20%-35% for the 99th percentile of the load distribution. We also find that while proxies can be somewhat useful in smoothing out some of the burstiness in Web workloads; the resulting workload continues, however, to exhibit substantial burstiness and a heavy-tailed nature. We identify one-time requests for large objects to be the limiting factor that diminishes the impact of proxies on the tail of load distribution. We conclude that, while proxies are immensely useful to users due to the reduction in the average response time, they are less effective in improving the capacities of networks and servers.     

57Fe and 166Er Mössbauer and magnetic studies of RFe4B (R = Er,Tm, Lu) compounds

Magnetic and Mössbauer studies have been carried out on a series of ternary borides RFe₄B (R = Er, Tm, Lu) which have the hexagonal CeCo₄B type structure. These compounds are found to be magnetically ordered at room temperature. Magnetization studies in the temperature range from 5 to 300 K reveal the presence of compensation temperatures in Er and Tm compounds and indicate antiferromagnetic coupling between the rare earth and Fe moments. Room temperature ⁵⁷Fe Mössbauer studies yield values of hyperfine fields at the two Fe sites as 246 and 185 kOe in ErFe₄B and TmFe₄B, and 204 and 145 kOe in LuFe₄B. The ¹⁶⁶Er Mössbauer studies give nearly free-ion hyperfine field at the Er sites which indicates that the exchange interaction in ErFe₄B is much stronger than crystal field interaction.     

A review on drag reduction with special reference to micellar systems

A state-of-the-art review on drag reduction has been presented in order to bring out some important aspects of the drag reduction phenomenon and its potential for practical use. The review is biased towards micellar systems and discusses in detail the morphological differences between drag reducing polymeric and micellar systems. Work relating to polymeric systems has not been dealt in detail as it has been the subject of earlier reviews. Studies relating to biological additives as well as suspensions have been briefly mentioned without detailed discussion as their potential for practical use presently appears] to be limited.NCL-Communication No. 3384     

A dynamic solution concept for abstract games

Several solution concepts have been defined for abstract games. Some of these are the core, due to Gillies and Shapley, the Von Neumann-Morgenstern stable sets, and the subsolutions due to Roth. These solution concepts are rather static in nature. In this paper, we propose a new solution concept for abstract games, called the dynamic solution, that reflects the dynamic aspects of negotiation among the players. Some properties of the dynamic solution are studied. Also, the dynamic solution of abstract games arising fromn-person cooperative games in characteristic function form is investigated.This research was supported by the Office of Naval Research under Contract No. N00014-75-C-0678, by the National Science Foundation under Grants Nos. MPS-75-02024 and MCS-77-03984 at Cornell University, by the United States Army under Contract No. DAAG-29-75-C-0024, and by the National Science Foundation under Grant No. MCS-75-17385-A01 at the University of Wisconsin. The author is grateful to Professor W. F. Lucas under whose guidance the research was conducted.     

Mössbauer studies of dilute Au:Er alloys: Obervation of hyperfine structure of ground and excited CEF levels

The hyperfine structure of dilute ¹⁶⁶Er impurities in Au has been investigated between 1.8 and 60 K by Mössbauer spectroscopy. The hyperfine spectrum of the Γ₇ electronic ground state is clearly observed below 4.2 K while at higher temperatures there is an indication of the contribution from the excited CEF-states Γ⁽¹⁾₈ and Γ₆. Using Hirst's relaxation theory for the Γ₇ ground state the magnetic hyperfine coupling constant A=(247±3) MHz and the exchange coupling constant J_sf=(0.10±0.02)eV were derived. A quadruple coupling constant B of about 1 MHz was estimated from the hyperfine pattern of the Γ⁽¹⁾₈ quartet.