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71.
Chunya Du Hui Liu Zhuang Cheng Shaoqin Zhang Zexing Qu Dezhi Yang Xianfeng Qiao Zujin Zhao Ping Lu 《Advanced functional materials》2023,33(45):2304854
The pursuit for efficient deep blue material is an ever-increasing issue in organic optoelectronics field. It is a long-standing challenge to achieve high external quantum efficiency (EQE) exceed 10% at brightness of 1000 cd m−2 with a Commission International de L'Eclairage (CIEy) <0.08 in non-doped organic light-emitting diodes (OLEDs). Herein, this study reports a deep blue luminogen, PPITPh, by bonding phenanthro[9,10-d]imidazole moiety with m-terphenyl group via benzene bridge. The non-doped OLED based on PPITPh exhibits an exceptionally high EQE of 11.83% with a CIE coordinate of (0.15, 0.07). The EQE still maintains 10.17% at the brightness of 1000 cd m−2, and even at a brightness as high as 10000 cd m−2, an EQE of 7.5% is still remained, representing the record-high result among non-doped deep-blue OLEDs at 1000 cd m−2. The unprecedented device performance is attributed to the reversed intersystem crossing process through hot exciton mechanism. Besides, the maximum EQE of orange phosphorescent OLED with PPITPh as host is 32.02%, and remains 31.17% at the brightness of 1000 cd m−2. Such minimal efficiency roll-off demonstrates that PPITPh is also an excellent phosphorescent host material. The result offers a new design strategy for the enrichment of high-efficiency deep blue luminogen. 相似文献
72.
Tao Cheng Xuan-Li Yang Sheng Yang Lang Li Zhong-Ting Liu Jie Qu Chao-Fu Meng Xiang-Chun Li Yi-Zhou Zhang Wen-Yong Lai 《Advanced functional materials》2023,33(5):2210997
Flexible transparent supercapacitors (FTSs) have aroused considerable attention. Nonetheless, balancing energy storage capability and transparency remains challenging. Herein, a new type of FTSs with both excellent energy storage and superior transparency is developed based on PEDOT:PSS/MXene/Ag grid ternary hybrid electrodes. The hybrid electrodes can synergistically utilize the high optoelectronic properties of Ag grids, the excellent capacitive performance of MXenes, and the superior chemical stability of PEDOT:PSS, thus, simultaneously demonstrating excellent optoelectronic properties (T: ≈89%, Rs: ≈39 Ω sq−1), high areal specific capacitance, superior mechanical softness, and excellent anti-oxidation capability. Due to the excellent comprehensive performances of the hybrid electrodes, the resulting FTSs exhibit both high optical transparency (≈71% and ≈60%) and large areal specific capacitance (≈3.7 and ≈12 mF cm−2) besides superior energy storage capacity (P: 200.93, E: 0.24 µWh cm−2). Notably, the FTSs show not only excellent energy storage but also exceptional sensing capability, viable for human activity recognition. This is the first time to achieve FTSs that combine high transparency, excellent energy storage and good sensing all-in-one, which make them stand out from conventional flexible supercapacitors and promising for next-generation smart flexible energy storage devices. 相似文献
73.
Qijun Li Yukun Qin Dengke Cheng Ming Cheng Hongjia Zhao Lvzhou Li Songnan Qu Jing Tan Jianning Ding 《Advanced functional materials》2023,33(15):2211013
Moisture-enabled electricity generation (MEG) is highly promising in next-generation energy conversion. However, the practical applications of existing MEG devices are limited due to their low current and voltage outputs, strong dependence on high moisture, and inflexible nature. Herein, an efficient MEG integrated with flexible, all-weather, and scalable fabrication characteristics based on the rational combination of carbonized polymer dots (CPDs) and liquid metal (LM) active electrodes is developed for the first time. Remarkably, the fabricated MEG device can produce a stable voltage output of 800 mV and a record high current density of 1640 µA cm−2. Even at a low air humidity of 15%, the MEG device can provide a high voltage output of 0.65 V and a considerable current density of 12 µA cm−2. The prompted diffusion of hydrogen ions in CPDs and the additional metal ions ionized from the LM electrode contribute synergistically to the high electricity generation. Additionally, the device can be easily integrated on various flexible substrates and generate an ultrahigh voltage of 210 V to power commercial electronics, showing great potential in large-scale fabrication and application. 相似文献
74.
Cheng-Jie Li Jin Hu Ge Gao Jia-Hao Chen Cheng-Shuang Wang Hong Zhou Guangxu Chen Peng Qu Peng Lin Wei-Wei Zhao 《Advanced functional materials》2023,33(8):2211277
Incorporating biomolecules into metal-organic frameworks (MOFs) as exoskeletons to form biomolecules-MOFs biohybrids has attracted great attention as an emerging class of advanced materials. Organic devices have been shown as powerful platforms for next-generation bioelectronics, such as wearable biosensors, tissue engineering constructs, and neural interfaces. Herein, biomolecules-incorporated MOFs as innovative gating module is realized for the first time, which is exemplified by biocatalytic precipitation (BCP)-oriented horseradish peroxidase (HRP)-embedded zeolitic imidazolate framework-90 (HRP@ZIF-90)/CdIn2S4 gated organic photoelectrochemical transistor under light illumination. In connection to a sandwich immunocomplexing targeting the model analyte human IgG, the IgG-dependent generation of H2O2 and the tandem HRP-triggered BCP reaction can cause the in situ blocking of the pore network of ZIF-90, leading to variant gating effect with corresponding responses of the device. This representative biodetection achieved good analytical performance with a wide linear range and a low detection limit of 100 fg mL−1. In the view of the plentiful biomolecule-MOF complexes and their potential interactions with organic systems, this study provides a proof-of-concept study for the generic development of biomolecules-MOFs-gated electronics and beyond. 相似文献
75.
Rui Zhang Pengyu Zang Dan Yang Jiahao Li Narisu Hu Songnan Qu Piaoping Yang 《Advanced functional materials》2023,33(25):2300522
The sensitization performance of sonosensitizers plays a key role in the sonodynamic therapy (SDT) effect. Herein, ZnSnO3:Nd nanoparticles with R3c phase/amorphous heterogeneous structure are developed by phase engineering strategy and applied as an ideal sonosensitizer. In the crystalline perovskite-type ZnSnO3:Nd, the substitution of the Zn2+ with Nd3+ causes the O 2p non-bonded state to move toward the Fermi level, which optimizes the band structure for ultrasound sensitization by reducing bandgap. Meanwhile, the unequal charge substitution can also form electron traps and oxygen vacancies to shorten the electron migration distance, which accelerates the electron–hole separation and inhibits carrier recombination, thus improving the acoustic sensitivity. Moreover, the dangling bonds exposed on the surface of amorphous ZnSnO3:Nd provide more active sites, and the localized states of the amorphous phase may also promote carrier separation, resulting in synergistic SDT effect. In particular, the Zn2+ released from ZnSnO3:Nd in the acidic tumor microenvironment (TME) reduces the adenosine triphosphate production by inhibiting the electron transport chain , which promotes the tumor cell apoptosis through destroying the redox balance of TME. Combining the inherent second near infrared and computed tomography imaging capabilities, this ZnSnO3:Nd nanoplatform shows a promising perspective in clinic SDT field. 相似文献
77.
78.
n型单晶硅片的电阻率和扩散方阻对IBC太阳电池电性能的影响 总被引:1,自引:0,他引:1
叉指背接触式(IBC)太阳电池因正面没有金属栅线遮挡,具有较高的短路电流,且组件外观更加美观。但由于IBC太阳电池正负电极在背面交叉式分布,在制备过程中需要采用光刻掩模技术进行隔离,难以实现大规模生产。采用Quokka软件仿真模拟了电阻率和扩散方阻对n型IBC太阳电池效率的影响,并对不同电阻率和扩散方阻的电池片进行了实验验证,从n型单晶硅片电阻率的选择和扩散工艺优化方面为IBC太阳电池的规模化生产提供了理论基础。实验结果表明,电阻率为3~5Ω·cm、扩散方阻为70Ω/时,小批量生产的IBC太阳电池平均光电转换效率可达23.73%,开路电压为693 mV,短路电流密度为42.44 mA/cm2,填充因子为80.69%。 相似文献
79.
钼钨铌磷杂多化合物的研究(Ⅰ):杂多酸的合成和表征 总被引:4,自引:0,他引:4
提出了分步酸化一分步加料合成[PNb_2Mo_xW_(10-x)O_(40)]~(5-)(x=0,2,4,6)系列杂多酸的方法,给出了最佳配料比和生成反应的pH值,并进行了红外、紫外、极谱、电位滴定及热稳定性研究。 相似文献
80.