Nonlinear dispersion in a coupled-resonator optical waveguide

The propagation of an optical pulse in a coupled-resonator optical waveguide may be calculated nonperturbatively to all orders of dispersion, in the conventional tight-binding approximation, even though the dispersion relationship is nonlinear. Working in this framework, we discuss limits of the physical parameters and approximations to the exact formulation that highlight the conditions under which pulse distortion can be minimized. The results are fundamental to the design of coupled-resonator optical waveguides and are also relevant to other applications of the tight-binding method.     

Computational study on the reaction mechanism of atmospheric oxidation of ethanol with ozone

The reaction of C₂H₅OH and O₃ on the singlet potential energy surface is carried out using the MP2 and CCSD(T)//MP2 theoretical approaches in connection with the 6-311++G(d,p) basis set. Three pre-reactive complexes C1, C2, and C3 are formed between ethanol and ozone at atmospheric pressure and 298.15 K temperature. With variety of the complexes, seven types of product are obtained which four types of them have enough thermodynamic stability. In thermodynamic approach, the most favor product begins with the formation of pre-reactive C2 complex and produces the CH₃CH(OH)₂ + O₂ as final adduct in a process that is computed to be exothermic by ?53.759 kcal/mol and spontaneous reaction by ?51.833 kcal/mol in Gibbs free energy. In kinetic viewpoint, the formation of CH₃COH + cis-H₂O₃ as a final adducts is the most favor path.     

Dispersion characteristics of coupled-resonator optical waveguides

A tight-binding optical waveguide formed by proximity coupling of nearest-neighbor resonators, e.g., a coupled-resonator optical waveguide (CROW), has distinct wave and pulse propagation characteristics compared with a conventional waveguide, and several applications in photonic devices have been proposed recently. But analysis of the dispersion, and in particular the group-velocity dispersion, in such a waveguide requires particular attention: the waveguide displays two distinct regimes of operation, depending on the position of the wave packet in the dispersion relationship.     

A delay model and optimization method of a low-power BiCMOS logiccircuit

A new delay model and optimization method is proposed for a low-power BiCMOS driver. A transient overdrive, base directly-tied complementary BiCMOS logic circuit operates faster than conventional BiCMOS and CMOS circuits for supply voltage down to 1.5 V by using a speed-power-area optimization approach. An analytical delay expression is derived for the first time for a full-swing BiCMOS circuit with short-channel effects. The circuit is simulated with a HSPICE model using 0.8-μm BiCMOS technology with a 6-GHz n-p-n and a 1-GHz p-n-p transistor. The simulation results have verified the analytical results and demonstrated that the circuit can work up to 200 MHz operating frequency for a load capacitance of 1 pF at 1.5 V of supply voltage     

Hybrid Devices by Selective and Conformal Deposition of PtSe2 at Low Temperatures

2D materials display very promising intrinsic material properties, with multiple applications in electronics, photonics, and sensing. In particular layered platinum diselenide has shown high potential due to its layer-dependent tunable bandgap, low-temperature growth, and high environmental stability. Here, the conformal and area selective (AS) low-temperature growth of layered PtSe₂ is presented defining a new paradigm for 2D material integration. The thermally-assisted conversion of platinum which is deposited by AS atomic layer deposition to PtSe₂ is demonstrated on various substrates with a distinct 3D topography. Further the viability of the approach is presented by successful on-chip integration of hybrid semiconductor devices, namely by the manufacture of a highly sensitive ammonia sensors channel with 3D topography and fully integrated infrared-photodetectors on silicon photonics waveguides. The presented methodologies of conformal and AS growth therefore lay the foundation for new design routes for the synthesis of more complex hybrid structures with 2D materials.     

Diradical Organic One-Dimensional Polymers Synthesized on a Metallic Surface

We report on the synthesis and characterization of atomically precise one-dimensional diradical peripentacene polymers on a Au(111) surface. By means of high-resolution scanning probe microscopy complemented by theoretical simulations, we provide evidence of their magnetic properties, which arise from the presence of two unpaired spins at their termini. Additionally, we probe a transition of their magnetic properties related to the length of the polymer. Peripentacene dimers exhibit an antiferromagnetic (S=0) singlet ground state. They are characterized by singlet–triplet spin-flip inelastic excitations with an effective exchange coupling (J_eff) of 2.5 meV, whereas trimers and longer peripentacene polymers reveal a paramagnetic nature and feature Kondo fingerprints at each terminus due to the unpaired spin. Our work provides access to the precise fabrication of polymers featuring diradical character which are potentially useful in carbon-based optoelectronics and spintronics.     

Technological and economical analysis of flare recovery methods,and comparison of different steam and power generation systems

Journal of Thermal Analysis and Calorimetry - One of the most important environmental issues in the oil, gas, and petrochemical industries is the appropriate disposal of waste hydrocarbon gases in...     

Modification of the Peng–Robinson equation of state for helium in low temperature regions

Helium shows the nearest behaviour to ideal gas in the room conditions. In contrast, thermodynamic behaviour of helium in the critical region, in which its liquefaction is possible, is extremely complicated. The equation of state (EOS), which is in common use for helium, is the modified Benedict–Webb–Rubin (MBWR) EOS developed by McCarty and Arp which is a 13th-order equation with 32 substance-dependent parameters. MBWR is a complicated EOS and its use is time consuming. In this work, the modified Peng–Robinson EOS introduced by Feyzi et al. is customised with 10 adjustable parameters for helium in the temperature range of 2.20–15.20 K and pressures up to 16 bar. The proposed EOS is able to predict the properties of helium in the vapour–liquid equilibrium (VLE) conditions and in the single gas-phase region. In addition, a temperature-dependent correlation for constant pressure heat capacity of helium from very low up to normal temperatures is proposed. The liquefaction process of helium, which is being done by cooling it to very low temperatures by passing through a Joule–Thomson valve, is predicted by the proposed EOS. Very accurate results are observed.