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901.
We studied electron transport properties of a dithiol‐benzene molecule covalently bonded between two gold electrodes by combining ab initio calculations for the central molecule and a green function method to calculate electron transport. Due to the large computational demand, this type of calculations usually involves certain ways of simplification. The simplification commonly used is to fix the contact surface of the electrodes by ignoring the disturbance of the Au contact surface by contacting with the central molecule, i.e. without scattering region relaxation. In this study, we intended to resolve the difference between models with and without the above simplification. The large conductance found in our models without scattering region relaxation is due to the highly symmetric arrangement of the Au contact surface and those layers near the contact. The disturbance of the Au contact surface by the contact of the central molecule is important since the increase of the Au‐S bond and the distortion of the Au atom on the FCC site can lower the transmission coefficient between the two electrodes. In order to obtain better results, the model should include scattering region relaxation. However, when such relaxation is not applicable or demands too much calculation resource, the center molecule of the electronic transport junction should be at least optimized by the calculation level including electronic correlation, i.e. post‐HF methods. 相似文献
902.
A systematic study of various metal trifluoromethanesulfonates as efficient catalysts in the regioselective reductive ring opening of benzylidene acetals is described, including the effects of solvents, reducing agents, and temperature. These catalysts are found to be effective in cleaving the 4,6‐O‐acetal rings of hexopyranosides at either O4 or O6, respectively. When used in conjunction with a 1 M solution of BH3·THF in THF without extra addition of any solvent, it affects the ring fission at the O6 position to generate the corresponding primary alcohols, whereas O4‐opening takes place in acetonitrile in the presence of dimethylethylsilane as the reductant leading to the secondary hydroxyl derivatives in high selectivity and yields. These methodologies can be applied to a wide range of substrates containing various functional groups. 相似文献
903.
Haifeng Shang 《Journal of Differential Equations》2009,247(6):1720-740
In this paper we study the Cauchy problem for the singular evolution p-Laplacian equations with gradient term and source on the assumption of measures as initial conditions. For the supercritical case q>p−1+p/N, we obtain that for every nonnegative solution there exists a nonnegative Radon measure μ as initial trace and μ has some local regularity. 相似文献
904.
A general approach is described for array-based biochemical sensing that uses contact-free dispersal of compounds into addressable microfabricated reactors. The arrays are composed of 1 to 100 nL volume open reactors that have been microfabricated on quartz substrates using lithography. The open architecture of these reactors allows them to be addressed in parallel or individually with an ink-jet arrayer that is capable of distributing 0.004 to 1 nL volumes of reagents. A seven-step biochemical assay has been conducted on a small array of reactors to demonstrate how they can be integrated with an ink-jet arrayer and optical detector. This nanoreactor assay format appears to overcome several limitations that chip-based microarray technology currently imposes on protein assays: the arrays can be created in a manner that does not expose the biochemical reagents to osmotic stress, independent reactions can be conducted in individual reactors, and the conditions in all of the reactors (e.g., concentration and pH) can be rapidly scanned. We believe that these nanoreactor arrays will be useful for biochemical sensing that involves delicate proteins and protein assemblies. 相似文献
905.
The objective of this work was to coat aluminosilicate clays on an inert silica support, and to characterize the properties and stability of the clay-silica coating. Two polymers, polyacrylamide (PAM) and polyvinyl alcohol (PVA), were used to bind kaolinite, illite, and smectite onto silica grains. The clay-polymer composites were studied by X-ray diffraction, FTIR, and electrophoretic mobility. Clay coatings on silica grains were characterized by mass coverage, scanning electron microscopy, specific surface area, and pH stability. Silica sand was successfully coated with clays by using the two polymers, but with PVA, the clay coating had a greater mass coverage and was more stable against pH variations. Less polymer was needed for the clay coating using PVA as compared to using PAM. Clay-polymer complexes and pure clay minerals had similar cation exchange capacities and electrophoretic mobilities, indicating that overall surface charge of the clays was little affected by the polymers. Some decrease in hydrophilicity was observed for illite and smectite when clays where coated with the polymers. The methodology reported here allows the generation of a clay-based porous matrix, with hydraulic properties that can be varied by adjusting the grain size of the inert silica support. 相似文献
906.
907.
文章应用资源依赖理论对终端定制过程进行了分析,拥有资源的稀缺性和重要性决定了运营商在终端定制过程中的主导作用。基于相互依赖关系的终端定制受市场规模、市场价值、定制终端兼容性、技术规范复杂性程度和市场集中度等因素的影响,表现为品牌形象定制、业务应用定制和全面定制三种类型。最后预测了3G时代终端定制的发展趋势。 相似文献
908.
Yilun Shang 《The Journal of mathematical sociology》2018,42(2):77-82
The H index, also known as Hirsch index, quantifies and compares the citation impact of scientific researchers. In the general context of networks, we define a node as a leader if its H index is not less than the average of the H indices of its neighbors. We show that in a randomly connected network, the proportion of leaders is almost always close to a half. 相似文献
909.
910.
Zhijin Zhao Zhen Peng Shilian Zheng Junna Shang 《Wireless Communications, IEEE Transactions on》2009,8(9):4421-4425
Cognitive radio has been regarded as a promising technology to improve spectrum utilization significantly. In this letter, spectrum allocation model is presented firstly, and then spectrum allocation methods based on genetic algorithm (GA), quantum genetic algorithm (QGA), and particle swarm optimization (PSO), are proposed. To decrease the search space we propose a mapping process between the channel assignment matrix and the chromosome of GA, QGA, and the position of the particle of PSO, respectively, based on the characteristics of the channel availability matrix and the interference constraints. Results show that our proposed methods greatly outperform the commonly used color sensitive graph coloring algorithm. 相似文献