全文获取类型
收费全文 | 1505篇 |
免费 | 45篇 |
国内免费 | 5篇 |
专业分类
化学 | 890篇 |
力学 | 39篇 |
数学 | 328篇 |
物理学 | 182篇 |
无线电 | 116篇 |
出版年
2022年 | 11篇 |
2021年 | 17篇 |
2020年 | 11篇 |
2019年 | 24篇 |
2018年 | 17篇 |
2017年 | 16篇 |
2016年 | 33篇 |
2015年 | 41篇 |
2014年 | 42篇 |
2013年 | 103篇 |
2012年 | 96篇 |
2011年 | 130篇 |
2010年 | 69篇 |
2009年 | 65篇 |
2008年 | 113篇 |
2007年 | 88篇 |
2006年 | 84篇 |
2005年 | 77篇 |
2004年 | 89篇 |
2003年 | 45篇 |
2002年 | 52篇 |
2001年 | 16篇 |
2000年 | 22篇 |
1999年 | 19篇 |
1998年 | 20篇 |
1997年 | 12篇 |
1996年 | 17篇 |
1995年 | 13篇 |
1994年 | 17篇 |
1993年 | 13篇 |
1992年 | 6篇 |
1991年 | 9篇 |
1990年 | 9篇 |
1989年 | 8篇 |
1988年 | 5篇 |
1986年 | 4篇 |
1985年 | 10篇 |
1984年 | 12篇 |
1983年 | 4篇 |
1982年 | 7篇 |
1981年 | 8篇 |
1980年 | 8篇 |
1979年 | 9篇 |
1978年 | 18篇 |
1977年 | 4篇 |
1976年 | 6篇 |
1975年 | 7篇 |
1974年 | 6篇 |
1973年 | 6篇 |
1971年 | 4篇 |
排序方式: 共有1555条查询结果,搜索用时 15 毫秒
151.
152.
Serge Galam 《Journal of statistical physics》1990,61(3-4):943-951
Real-space renormalization group ideas are used to study a voting problem in political science. A model to construct self-directed pyramidal structures from bottom up to the top is presented. Using majority rules, it is shown that a minority and even a majority can be systematically self-eliminated from top leadership, provided the hierarchy has a minimal number of levels. In some cases, 70% of the population is found to have zero representation after six hierarchical levels. Results are discussed with respect to the internal operation of political organizations. 相似文献
153.
Salima Saïdi Frdric Guittard Claude Guimon Serge Gribaldi 《Journal of polymer science. Part A, Polymer chemistry》2005,43(17):3737-3747
A series of polyacrylate monomers with F‐alkylalkyl [F(CF2)n(CH2)n′] side groups were prepared by free‐radical polymerization. The effect of the chemical structure on the surface properties of poly(ethylene terephthalate)s was evaluated by variations in the relative length of the fluorocarbon and hydrocarbon units in the side group. The resulting polymers were quite surface‐active in the solid state. The surface and bulk organization was investigated by X‐ray photoelectron spectroscopy analysis. A strong correlation between the bulk organization and surface properties of the polymers was established. The outmost layer, formed from trifluoromethyl groups and some ester functions, suggests that the side chain is arranged irregularly in the polymer–air interface. The length of the lateral chain governs this organization: long fluorinated chains and short hydrocarbon spacers are essential elements of the molecular design for such low‐surface‐energy materials. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 3737–3747, 2005 相似文献
154.
Serge Bouc 《Algebras and Representation Theory》2003,6(5):515-543
Let p be a prime number. This paper describes the primitive idempotents and prime spectrum of the crossed Burnside algebra of a finite group over a p-local ring. The main application is a formula for the block idempotents of the p-local Mackey algebra of the group, in terms of the corresponding bloks of the group algebra. 相似文献
155.
Yu Shen Jean-Yves Potvin Jean-Marc Rousseau Serge Roy 《Annals of Operations Research》1995,61(1):189-211
In this paper, we describe an expert consulting system for a dispatcher working in a courier service company. The system integrates interactive-graphic features and a learning module to support the dispatcher in his(her) task, and to suggest appropriate decisions when new requests come in. An experiment with a professional dispatcher is also reported. 相似文献
156.
Summary For the testing problem concerning the coefficients of the multivariate linear functional relationship model, the distribution
of a statistic previously proposed by A. P. Basu depends on the unknown covariance matrixV of errors, so limiting its applicability. This article proposes new test statistics with sampling distributions which are
independent of the unknown parameters for the cases whereV is either unknown or known only up to a proportionality factor. The exact distributions of the test statistics are also discussed. 相似文献
157.
Sur les fonctions absolument monotones 总被引:2,自引:0,他引:2
Serge Bernstein 《Acta Mathematica》1929,52(1):1-66
158.
Bertrand Reuillard Solène Gentil Marie Carrière Alan Le Goff Serge Cosnier 《Chemical science》2015,6(9):5139-5143
We report the non-covalent functionalization of a multi-walled carbon nanotube (MWCNT) electrode with a biomimetic model of the horseradish peroxidase (HRP) active site. By modifying the MWCNT electrode surface with imidazole-modified polypyrrole, a new biomimetic complex of HRP was synthesized on the MWCNT sidewalls via the coordination of imidazole (Im) to the metal centre of iron protoporphyrin IX, affording (Im)(PP)FeIII. Compared to the pi-stacking of non-coordinated (PP)FeIII on a MWCNT electrode, the (Im)(PP)FeIII-modified MWCNT electrode exhibits higher electrocatalytic activity with an I max = 0.52 mA cm–2 for the reduction of H2O2, accompanied by a high onset potential of 0.43 V vs. Ag/AgCl. The performances of these novel surface-confined HRP mimics were compared to those of a MWCNT electrode modified by HRP. Although the enzyme electrode displays a higher electrocatalytic activity towards H2O2 reduction, the (Im)(PP)FeIII-modified MWCNT electrode exhibits a markedly higher operational stability, retaining 63% of its initial activity after one month. 相似文献
159.
Cristina Díez Davy Guillarme Aline Staub Spörri Emmanuelle Cognard Didier Ortelli Patrick Edder Serge Rudaz 《Analytica chimica acta》2015
In this study, fourteen highly polar aminoglycoside (AGs) antibiotics were selected. Various stationary phases were tested, including Obelisc R, ZIC-HILIC, BEH amide and aminopropyl. The nature of the stationary phase, mobile phase (water or buffer solutions and acetonitrile), pH (percentage of formic acid), gradient conditions and injection solvents were systematically studied as relevant parameters for tuning retention selectivity and detectability of AGs in liquid chromatography electrospray tandem mass spectrometry (LC–(ESI)–MS/MS). Only the two zwitterionic phases (Obelisc R and ZIC-HILIC) achieved a proper chromatographic separation considering interferences due to the crosstalk effect in low resolution mass spectrometers. The water/acetonitrile mobile phase containing 1% formic acid used with Obelisc R provided more sensitivity than the highly concentrated buffered mobile phases required for ZIC-HILIC. A solid phase extraction (SPE) clean-up procedure with polymeric weak cation exchange (WCX) cartridges was optimized for honey, milk and liver samples. Different brands of cartridges and elution solvents were tested, and the Taurus WCX offered the best recovery rate with a buffer elution at pH 3. The final optimized method was validated in these matrices according to Decision 2002/657/EC. A monitoring campaign for sixty honey, milk and liver samples was carried out at the Food Authority Control in Geneva. The concentration of dihydrostreptomycin (DSTP) found in one ovine liver exceeded the established maximum residue levels (MRLs) within the European and Swiss legislations but it was compliant taking into account the validation data. 相似文献
160.
An electrochemical biosensor capable of indirect detection of DNA damage induced by any one of the three endocrine-disrupting compounds (EDCs) – bisphenol A (BPA), 4-nonylphenol (NP) and 4-t-octylphenol (OP), has been researched and developed. The methylene blue (MB) dye was used as the redox indicator. The glassy carbon electrode (GCE) was modified by the assembled dsDNA/graphene oxide-chitosan/gold nano-particles to produce a dsDNA/GO-CS/AuNPs/GCE sensor. It was characterized with the use of electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and scanning electron microscopy (SEM) techniques. The loading/release of the MB dye by the dsDNA/GO-CS/AuNPs film was investigated, and the results showed that the process was reversible. Based on this, the sensor was used to measure the difference between the loading capabilities of intact and damaged dsDNA in the films. The sensor was then successfully applied to detect DNA damage electrochemically. The differential pulse voltammetry (DPV) peak current ratio for MB, observed before and after DNA damage, increased linearly in the presence the BPA, NP or OP compounds; the treatment range was 10–60 min, and the respective damage rates were 0.0069, 0.0044 and 0.0031 min−1, respectively. These results were confirmed by the binding constants: 2.09 × 106 M−1 (BPA-DNA), 1.28 × 106 M−1 (NP-DNA) and 9.33 × 105 M−1 (OP-DNA), all of which were obtained with the use of differential pulse stripping voltammetry (DPSV). 相似文献