Synthesis of POSS‐Functionalized Polyisobutylene via Direct Initiation

POSS‐functionalized polyisobutylenes (PIBs) were synthesized by carbocationic polymerization using an epoxy‐POSS/TiCl₄ initiating system in hexane/methyl chloride (60:40 v/v) solvent mixture at −80 °C. ¹H NMR spectroscopy verified the incorporation of one epoxy‐POSS per polymer chain. Light scattering and TEM analysis demonstrated the formation of 50–100 nm sized aggregates and micron‐sized clusters.

     

A comparison of iterative Fourier transform algorithms for image quality estimation

A comparison was established between two iterative Fourier transform algorithms (IFTAs), such as the original Gerchberg–Saxton (GS) and the mixed-region amplitude freedom (MRAF) algorithms, for the hologram reconstruction of different target images through the full reference image quality estimation (IQE) and pixel homogeneity in the Fourier plane presented theoretically and experimentally. The comparison was applied depending upon both algorithms based on a computer-generated hologram (CGH) implemented utilizing a reflective phase-modulated liquid-crystal spatial light modulator (LC-SLM) to obtain the digital kinoform holograms of the desired intensity distributions. These digital holograms were applied to reconstruct the intensity patterns for 852 nm, which represents a laser beam source. The theoretical and experimental results of the reconstructed patterns obtained using the MRAF algorithm were found to be smoother and better than the patterns obtained using the GS algorithm. Unmodulated light beam (dc term) is removed from the reconstructed patterns attributed to digital kinoform holograms of MRAF algorithm as an alternative to the theoretical and experimental results without using any additional optic equipment at the light path. Moreover, this paper discussed the full reference objective quality estimations, such as mean square error (MSE), peak signal-to-noise ratio (PSNR), structural content (SC), normalized absolute error (NAE), normalized cross correlation (NK), and homogeneity of pixels, through the contrast (Cont) and inverse difference moment (IDM) for numerical and experimental results. According to the two desired intensity distributions processed theoretically and experimentally, the results of MRAF algorithm were found to be in the highly accurate recovered phase, the quality of image was enhanced, and the dc term was decreased. Image quality estimation of full reference objective relay on the feedback algorithms experimental attestation has not been implemented yet.     

Weak amenability of weighted Orlicz algebras

Let G be a locally compact abelian group, \(\omega :G\rightarrow (0,\infty )\) be a weight, and (\(\Phi ,\Psi \)) be a complementary pair of strictly increasing continuous Young functions. We show that for the weighted Orlicz algebra \(L^\Phi _\omega (G)\), the weak amenability is obtained under conditions similar to the ones considered in Zhang (Proc Amer Math Soc 142:1649–1661, 2014) for weighted group algebras. Our methods can be applied to various families of weighted Orlicz algebras, including weighted \(L^p\)-spaces.     

A pattern recognition framework to blind audio watermark decoding

Conventional blind audio watermark (WM) decoders use matched-filtering techniques because of their simplicity. In these methods, WM decoding and WM detection are often considered as separate problems and the WM signal embedded by spreading a secret key through the spectrum of a host signal is extracted by maximizing correlation between the secret key and the received audio. Conventionally decoding is achieved by using a pre-defined decoding/detection threshold and tradeoff between the false rejection ratio and false acceptance ratio constitutes main drawback of the conventional decoders. Unlike the conventional methods, this paper introduces a pattern recognition (PR) framework to WM extraction and integrates WM decoding and detection problems into a unique classification problem that eliminates thresholding. The proposed method models statistics of watermarked and original audio signals by a Gaussian mixture model (GMM) with K components. Learning of the embedded WM data is achieved in a principal component analysis (PCA) transformed wavelet space and a maximum likelihood (ML) classifier is designed for WM decoding. Robustness of the proposed method is evaluated under compression, additive noise and Stirmark benchmark attacks. It is shown that both WM decoding and detection performances of the introduced decoder outperform the conventional decoders.     

Finite-parameter feedback stabilization of original Burgers' equations and Burgers' equation with nonlocal nonlinearities

We study the problem of global exponential stabilization of original Burgers' equations and the Burgers' equation with nonlocal nonlinearities by controllers depending on finitely many parameters. We investigate both equations by employing controllers based on finitely many Fourier modes and the latter equation by employing finitely many volume elements. To ensure global exponential stabilization, we have provided sufficient conditions on the control parameters for each problem. We also show that solutions of the controlled equations are steering a concrete solution of the non-controlled system as t → ∞ with an exponential decay rate.     

Synthesis and antitumor activity of new silver(I)-N-heterocyclic carbene complexes

Abstract

In this study, two novel benzimidazole-based N-heterocyclic carbene ligands (1a-b) and their silver(I) complexes (2a-b) were synthesized. All new compounds were characterized by FT-IR, LC-MS, ¹H NMR, and ¹³C NMR spectroscopies. The in vitro antitumor activities of NHC ligands (1a-b) and their silver(I) complexes (2a-b) against DU-145 human prostate cancer cells, MDA-MB-231 and MCF-7 human breast cancer cells and L-929 (normal cells adipose from mouse) were also determined using MTT analysis for 24?h, 48?h, and 72?h. The results showed that while NHC ligands did not have in vitro antitumor activity on MCF-7, MDA-MB-231 and DU-145 cells, Ag(I)-NHC complexes have in vitro antitumor activities. The in vitro antitumor activity of 2a was found to be lower than that of 2b. Ag(I)-NHC complexes were observed to have higher IC₅₀ values for non-cancerous cell lines than cancer cells.     

Comparison of adsorption performances of metal–chelated polyamide hollow fibre membranes in lysozyme separation

Commercially available microporous polyamide hollow fibres are modified by acid hydrolysis to activate the reactive groups and subsequently binding of the ligand, i.e. Cibacron Blue F3GA. Then the Cibacron Blue F3GA-derived hollow fibres were loaded with different metal ions (i.e. Zn(II), Cu(II), Ni(II)) to form the metal chelate. The internal polymer matrix was characterised by scanning electron microscopy. The effects of pH, initial concentration of lysozyme, metal type and temperature on the adsorption of lysozyme to the metal–chelated hollow fibres were examined in a batch reactor. The non-specific adsorption of lysozyme onto the polyamide hollow fibres was 1.8 mg/g. Cibacron Blue F3GA immobilisation increased the lysozyme adsorption up to 62.3 mg/g. Metal–chelated hollow fibres showed a significant increase of the adsorption efficiency. Lysozyme adsorption capacities of Zn(II), Cu(II) and Ni(II)-chelated hollow fibres were different. The maximum capacities of Zn(II), Cu(II) or Ni(II)-chelated hollow fibres were 144.2, 75.2 and 68.6 mg/g, respectively. Significant amount of the adsorbed lysozyme (up to 97%) was eluted in 1 h in the elution medium containing 1.0 M NaSCN at pH 8.0 and 25 mM EDTA at pH 4.9. Repeated adsorption–desorption process showed that this novel metal–chelated polyamide hollow fibres are suitable for lysozyme adsorption.     

Hydrolytic Behavior of La<Superscript>3+</Superscript> and Sm<Superscript>3+</Superscript> at Various Temperatures

The hydrolytic species of lanthanide ions, La³⁺ and Sm³⁺, in water at I = 0.1 mol·dm^?3 KCl ionic strength and temperatures of 298.15, 310.15 and 318.15 K were investigated by potentiometry. The hydrolytic species were modeled by the HySS simulation program. From the results, the hydrolytic species of each metal ion at different temperatures were calculated using the program HYPERQUAD2013. The hydrolysis constants (log₁₀ β) of [La(OH)]²⁺ and La(OH)₃ were calculated as ?8.52 ± 0.46, ?26.84 ± 0.48, and log₁₀ β values of [Sm(OH)]²⁺, [Sm(OH)₂]⁺, Sm(OH)₃ were calculated as ?7.11 ± 0.21, ?15.84 ± 0.25 and ?23.44 ± 0.52 in aqueous media at 298.15 K, respectively. The dependence of the hydrolysis constants on the temperature allowed us to calculate the enthalpy, entropy, and Gibbs energy of hydrolysis values of each species.     

Solid phase extractive preconcentration of trace metals using p-tert-butylcalix[4]arene-1,2-crown-4-anchored chloromethylated polymeric resin beads

5,11,17,23-Tetrakis(1,1-dimethylethyl)-25,26-dihydroxy-27,28-crown-4-calix[4]arene in the cone conformation was synthesized. This p-tert-butylcalix[4]arene-1,2-crown-4 compound was then anchored with Merrifield chloromethylated resin beads. The modified polymeric resin was characterized by ¹H NMR, FT-IR and elemental analysis and used successfully for the separation and preconcentration of Cu(II), Cd(II), Co(II), Ni(II) and Zn(II) prior to their determination by FAAS. Effective extraction conditions were optimized in both batch and column methods. The resin exhibits good separating ability with maximum between pH 6.0-7.0 for Cu(II), pH 6.0 for Cd(II), pH 5.0 for Co(II), pH 4.0-4.5 for Ni(II), and pH 4.5 for Zn(II). The elution studies were carried out with 0.5 mol L⁻¹ HCl for Cu(II), Co(II) and Co(II), 1.0 mol L⁻¹ HCl for Cd(II) and Zn(II). The sorption capacity, preconcentration factor and distribution coefficient of each metal ion were determined. The detection limits were 1.10, 1.25, 1.83, 1.68 and 2.01 μg L⁻¹ for Cu(II), Cd(II), Co(II), Ni(II) and Zn(II). The influence of several ions on the resin performance was also investigated. The validity of the proposed method was checked for these metal ions in NIST standard reference material 2709 (San Joaquin Soil) and 2711 (Montana Soil).     

Evaluation of modified CMC and CMC-PVA as miscible polymer blend membranes for hepatocytes

CMC and CMC-PVA were blended either with type I collagen, BSA or CS to obtain biocompatible membranes for evaluation as potential hepatocyte culture substrates. Pure and modified forms of CMC showed distinct surface, mechanical, and cell attachment properties. While the hydrophilicity decreased, the mechanical stability and the porosity of CMC membranes increased after blending. Serum proteins were adsorbed by all types of membranes. Among eight membranes tested, collagen-modified CMC was found to be a suitable membrane material for hepatocyte culture, in terms of mechanical and cell interaction properties.