Synthesis, structure, and metalation of two new highly porous zirconium metal-organic frameworks

Three new metal-organic frameworks [MOF-525, Zr(6)O(4)(OH)(4)(TCPP-H(2))(3); MOF-535, Zr(6)O(4)(OH)(4)(XF)(3); MOF-545, Zr(6)O(8)(H(2)O)(8)(TCPP-H(2))(2), where porphyrin H(4)-TCPP-H(2) = (C(48)H(24)O(8)N(4)) and cruciform H(4)-XF = (C(42)O(8)H(22))] based on two new topologies, ftw and csq, have been synthesized and structurally characterized. MOF-525 and -535 are composed of Zr(6)O(4)(OH)(4) cuboctahedral units linked by either porphyrin (MOF-525) or cruciform (MOF-535). Another zirconium-containing unit, Zr(6)O(8)(H(2)O)(8), is linked by porphyrin to give the MOF-545 structure. The structure of MOF-525 was obtained by analysis of powder X-ray diffraction data. The structures of MOF-535 and -545 were resolved from synchrotron single-crystal data. MOF-525, -535, and -545 have Brunauer-Emmett-Teller surface areas of 2620, 1120, and 2260 m(2)/g, respectively. In addition to their large surface areas, both porphyrin-containing MOFs are exceptionally chemically stable, maintaining their structures under aqueous and organic conditions. MOF-525 and -545 were metalated with iron(III) and copper(II) to yield the metalated analogues without losing their high surface area and chemical stability.     

Quantum theory of a free electron in a tapered wiggler field

It is pointed out that a slight modification of the relativistic quantum theory of a free electron in a uniform wiggler field enables the study of motion in a tapered wiggler field of the form $\text{k}{}_{\mathrm{w}}{}^1\text{= k}{}_{\mathrm{w}}\text{?}\text{b}\text{z}$ which merits attention. The lower limit of z is 800 cm. The exact relativistic quantum mechanical calculation shows an enhancement in the gain for single pass. The frequencies are up-shifted by amounts depending on the parameter b.     

N‐(2‐Hydroxyethyl)ethylenediammonium hydrogenphosphate monohydrate

The title compound, C₄H₁₄N₂O²⁺·HPO₄^2?·H₂O, contains alternating interleaved layers of hydrogenphosphate and N‐(2‐hydroxyethyl)ethyl­enedi­ammonium moieties. The water mol­ecules are associated with channel‐like voids in the structure and a network of hydrogen bonds stabilizes the crystal packing.     

Classification of design parameters for E-commerce websites: A novel fuzzy Kano approach

Websites have gained vital importance for organizations along with the growing competition in the world market. It is known that usability requirements heavily depend on the type, audience and purpose of websites. For the e-commerce environment, usability assessment of a website is required to figure out the impact of website design on customer purchases. Thus, usability assessment and design of online pages have become the subject of many scientific studies. However, in any of these studies, design parameters were not identified in such a detailed way, and they were not classified in line with customer expectations to assess the overall usability of an e-commerce website. This study therefore aims to analyze and classify design parameters according to customer expectations in order to evaluate the usability of e-commerce websites in a more comprehensive manner. Four websites are assessed using the proposed novel approach with respect to the identified design parameters and the usability scores of the websites are examined. It is revealed that the websites with high usability score are more preferred by customers. Therefore, it is indicated that usability of e-commerce websites affects customer purchases.     

Electroanalytical Investigation and Simultaneous Determination of Etodolac and Thiocolchicoside at a Non-modified Glassy Carbon Electrode in Anionic Surfactant Media

In this study, a differential pulse voltammetry method was designed for the simultaneous determination of etodolac and thiocolchicoside in a tablet dosage form. This method is a sensitive, costless and reproducible one initially designed for the simultaneous determination of etodolac and thiocolchicoside using bare/unmodified glassy carbon electrode in the presence of sodium dodecyl sulfate. At optimized conditions, the method showed linear responses with etodolac and thiocolchicoside concentration in the range of 1 μM to 80 μM. The limits of detection and quantification were calculated as 0.11 μM and 0.38 μM for etodolac and 0.20 μM and 0.67 μM for thiocolchicoside, respectively.     

Generation of long plasma channels in air by focusing ultrashort laser pulses with an axicon

We show that by focusing ultrashort-pulsed laser beams in air with an axicon, relatively long plasma channels can be generated. The axicon generates Bessel-like beams, where the on-axis intensity stays high over distances much longer compared to focusing with conventional lenses. We developed a scheme to detect the presence of the plasma, based on its screening property. Using this scheme, we detected plasma channels longer than 1 m and 3.5 m generated by 8 mJ and 90 mJ input pulse energies, respectively. Our simulations show that axicon focusing can yield self-guided propagation with or without contribution of plasma, depending on the input pulse power.     

Unexpected regioselectivity observed in the bromination and epoxidation reactions of p-benzoquinone-fused norbornadiene: An experimental and computational study

The bromination reaction of p-benzoquinone-fused norbornadiene was studied at various temperatures (?78, ?50, 0, 25, and 77 °C). At room temperature, the double bonds of the p-benzoquinone units were mainly brominated. The double bond of the norbornene unit also underwent a bromination reaction in a yield of only 2%. However, the reaction at ?78 °C resulted in the formation of products derived from the attack of bromine on the norbornene double bond with higher charge density. In contrast to the bromination reaction, the epoxidation reaction of the same compound with m-chloroperbenzoic acid and dimethyldioxirane exclusively resulted in the formation of products derived from the addition to the double bond of norbornadiene. The regioselectivity observed was investigated and the results were supported by theoretical calculations.     

Online video scene clustering by competitive incremental NMF

Efficient clustering and categorizing of video are becoming more and more vital in various applications including video summarization, content-based representation and so on. The large volume of video data is the biggest challenge that this task presents, for most the clustering techniques suffer from high dimensional data in terms of both accuracy and efficiency. In addition to this, most video applications require online processing; therefore, clustering should also be done online for such tasks. This paper presents an online video scene clustering/segmentation method that is based on incremental nonnegative matrix factorization (INMF), which has been shown to be a powerful content representation tool for high dimensional data. The proposed algorithm (Comp-INMF) enables online representation of video content and increases efficiency significantly by integrating a competitive learning scheme into INMF. It brings a systematic solution to the issue of rank selection in nonnegative matrix factorization, which is equivalent to specifying the number of clusters. The clustering performance is evaluated by tests on TRECVID video sequences, and a performance comparison to baseline methods including Adaptive Resonance Theory (ART) is provided in order to demonstrate the efficiency and efficacy of the proposed video clustering scheme. Clustering performance reported in terms of recall, precision and F1 measures shows that the labeling accuracy of the algorithm is notable, especially at edit effect regions that constitute a challenging point in video analysis.     

Poptube approach for ultrafast carbon nanotube growth

Microwave irradiation can be used to heat conductive materials and metallocene precursors to initiate ultrafast CNT growth. It takes only 15-30 seconds to grow CNTs at room temperature in air, without the need for any inert gas protection and additional feed stock gases.