Structural Characterization of Coordination Polymers of Nickel(II) and Zinc(II) with Polycarboxylate Ligands

Abstract  

The structural aspects of one-dimensional coordination polymer (1) of nickel(II) with 1,3,5-benzene tricarboxylate and a three-dimensional interpenetrating coordination polymer (2) of zinc(II) with 1,4-benzenedicarboxylate ligand are studied by single crystal X-ray diffraction analysis. Coordination polymer (1) forms a hydrogen bonded three dimensional network structures. The coordination polymer 1 having a composition [Ni₃(TMA)₂(H₂O)₁₂] _n where (TMA = trimesate anion), crystallizes in monoclinic crystal system with C2 space group and has a/?, 17.3387(4); b/?, 12.8748(4); c/?, 6.5302(2); β/°111.620(2); V/?³, 1355.20(7). The zinc coordination polymer 2 crystal system is orthorhombic, with space group Pbca. It has a/?, 14.5049(3); b/?, 17.1616(3); c/?, 18.1389(4); V/?³, 4515.27(16). The 1,4-benzenedicarboxylate three dimensional coordination polymer of zinc(II) comprises of novel hydroxo bridged tetranuclear zinc(II) secondary building units and has a composition [Zn₂(C₆H₄C₂O₄)_1.5{(CH₃)₂SO}₂(OH)] _n . Topological analysis of the three dimensional coordination polymer 2 shows that it has a two fold interpenetrating net topology.     

Resonant structures in24Mg+28Si elastic and inelastic scattering

The data on the excitation functions of²⁴Mg+²⁸Si elastic and inelastic (2⁺ ?0⁺, 2⁺ ?2⁺, 4⁺ ?0⁺ and 4⁺ ?2⁺) scattering fromE _c.m.=48.97 to 57.21 MeV have been subjected to a statistical analysis consisting of the calculations of deviation function, cross-correlation function, summed excitation function, cross-channel correlation coefficients, coherence widths, and the distribution of cross sections. Based on the outcome of the analysis resonant structures atE _c.m.=49.23, 50.02, 50.51, 52.10, 52.53, 53.27 and 54.14 MeV have been confirmed and three new structures of the same nature have been identified atE _c.m.=51.42, 54.88 and 55.60 MeV.     

An Artificial-Neural-Network-Based Integrated Regional Model for Rain Retrieval Over Land and Ocean

An integrated regional model is proposed for rain-rate retrievals over land/ocean from the brightness temperature (Tb) values of the Tropical Rainfall Measuring Mission (TRMM) Microwave Imager (TMI). The polarization-corrected temperature calculated from the 85.5-GHz channels is also considered as one of the inputs along with the nine channel Tb values. This model is applicable over the region between and . For this purpose, an artificial neural network is utilized. The collocated precipitation radar (PR) near-surface rain rates as given by a 2A25 data product is considered as a target value. The methodology consists of the separation of land and ocean pixels, the separation of stratiform and convective pixels over land/ocean, and the selection of important features (inputs) for the multilayer perceptron network by the feature selection technique for each group. For the separation of land/ocean pixels, the Tb values of the 10.65-GHz vertical channel are utilized. The values are utilized to separate the stratiform and convective pixels both over land and ocean. The rain retrieval from the developed model is validated with TRMM PR. Overall result shows the better agreement of the model-retrieved rain rate with the PR observation compared to the TMI (2A12) rain rate particularly over land. The rain retrieved from the developed model is further validated with Doppler weather radar. A reasonably good agreement is observed between these two estimations.     

Edge transport in 2D cold atom optical lattices

We theoretically study the observable response of edge currents in two-dimensional cold atom optical lattices. As an example, we use Gutzwiller mean-field theory to relate persistent edge currents surrounding a Mott insulator in a slowly rotating trapped Bose-Hubbard system to time of flight measurements. We briefly discuss an application, the detection of the Chern number using edge currents of a topologically ordered optical lattice insulator.     

Intergranular magnetoresistance in Sr2FeMoO6 from a magnetic tunnel barrier mechanism across grain boundaries

We present magnetization (M) and magnetoresistance (MR) data for a series of Sr2FeMoO6 samples with independent control on antisite defect and grain-boundary densities, which reveal several unexpected features, including a novel switching-like behavior of MR with M. These, in conjunction with model calculations, establish that the MR in Sr2FeMoO6 is dominantly controlled by a new mechanism, derived from the magnetic polarization of grain-boundary regions acting like spin valves, leading to behavior qualitatively different from that usually encountered in tunneling MR. We show that a simple and useful experimental signature for the presence of this spin-valve-type MR (SVMR) is a wider hysteresis in MR compared to that in M.     

Bell's inequality and universal quantum gates in a cold-atom chiral fermionic p-wave superfluid

We propose and analyze a probabilistic scheme to entangle two spatially separated topological qubits in a p{x}+ip{y} superfluid using controlled collisions between atoms in movable dipole traps and unpaired atoms inside vortex cores in the superfluid. We discuss how to test the violation of Bell's inequality with the generated entanglement. A set of universal quantum gates is shown to be implementable deterministically using the entanglement despite the fact that the entangled states can be created only probabilistically.     

Quantum computation using vortices and majorana zero modes of a px + ipy superfluid of fermionic cold atoms

We propose to use the recently predicted two-dimensional "weak-pairing" px + ipy superfluid state of fermionic cold atoms as a platform for topological quantum computation. In the core of a vortex, this state supports a zero-energy Majorana mode, which moves to finite energy in the corresponding topologically trivial "strong-pairing" state. By braiding vortices in the "weak-pairing" state, unitary quantum gates can be applied to the Hilbert space of Majorana zero modes. For readout of the topological qubits, we propose realistic schemes suitable for atomic superfluids.     

Turbulent film boiling from a vertical non-isothermal surface

The turbulent film boiling from a vertical non-isothermal surface is formulated with due consideration to thermal radiation from its lateral face. It is observed that the application of Reynolds analogy together with thermal conduction in the test surface has yielded a conjugate solution from which the case of an isothermal condition can be generated as a special case. The analysis has further paved the way in establishing a functional relation between the Nusselt numberNu, radiation parameterN _R , fin parameterM, temperature ratio termT _s /(T _w,0?T _s ), and a product of characteristic modified Grashof, Prandtl and superheating parameter defined as (Gr ² Pr S). In a fully developed turbulent film boiling i.e., modified Grashof number being greater than 10¹⁰, the temperature ratio term accounts for the non-linearities arising due to the inclusion of radiation from the lateral face of the fin. The results are in good agreement with experimental data over a wide range of system conditions.     

Interaction of thermal radiation with laminar natural convection from a horizontal cylinder in air

The heat transfer rates from a horizontal cylindrical surface of an internally heated tube under constant heat flux conditions are evaluated with the aid of integral analysis giving due consideration to both natural convection and thermal radiation to ambient medium of air. It is observed that non-isothermal conditions around the periphery of the tube arise due to the conjugate effects of the three modes of energy transmission viz., conduction, convection and radiation. The theoretical analysis is further validated with the experimental results and the coincidence is found to be very satisfactory.Die Wärmeübertragungsraten einer horizontalen zylindrischen Oberfläche eines innen erwärmten Rohres mit konstantem Wärmestrom sind mit Hilfe von Integralrechnungen berechnet worden, die sich auf die freie Konvektion und thermische Strahlung mit Luft als Umgebungsmedium beziehen. Es ist beobachtet worden, daß nicht-isotherme Bedingungen am Umfang des Rohres aus den drei Energieübertragungsarten Leitung, Konvektion und Strahlung entstehen. Die theoretische Berechnung wurde mit experimentellen Ergebnissen bestätigt und die Koinzidenz stellte sich als sehr zufriedenstellend heraus.     

Heating of non-Newtonian falling liquid film on a horizontal tube

The problem of heat transfer to non-Newtonian laminar falling liquid films on horizontal tubes is investigated theoretically for constant heat flux and isothermal conditions imposed at the inner periphery of the tube. The local and average heat transfer coefficients are obtained as function of the system parameters by conjugating the convective transport of heat to the liquid film to the thermal conduction in the material of the tube in the peripheral direction. The results indicate that the average heat transfer coefficient can be described successfully by three dimensionless groups characterizing the dynamic flow characteristics of the film, modified Prandtl number and the index of the power law variation of the rate of angular shear deformation of the fluid with respect to the shear stress.Das Problem des Wärmeübergangs an laminar ablaufende Fallfilme nicht-Newtonscher Flüssigkeiten an horizontalen Rohren wird unter Voraussetzungen konstanter Temperatur bzw. konstanten Wärmeflusses bezüglich des Rohrinnenumfangs theoretisch untersucht. Die örtlichen und gemittelten Wärmeübergangskoeffizienten erhält man als Funktion der Systemparameter unter gleichzeitiger Berücksichtigung des konvektiven Wärmetransportes an dem Flüssigkeitsfilm und der Wärmeleitung im Rohrmaterial in Umfangsrichtung. Die Ergebnisse zeigen, daß sich der gemittelte Wärmeübergangskoeffizient zufriedenstellend in Abhängigkeit von drei dimensionslosen Kenngrößen darstellen läßt. Diese charakterisieren das dynamische Fließverhalten des Films bzw. entsprechen einer modifizierten Prandtl-Zahl und dem Exponenten des Potenzgesetzes, welches die Abhängigkeit der Scherdeformation der Flüssigkeit von der Schubspannung wiedergibt.