A Novel Artificial Intelligence Based Timing Synchronization Scheme for Smart Grid Applications

The smart grid control applications necessitate real-time communication systems with time efficiency for real-time monitoring, measurement, and control. Time-efficient communication systems should have the ability to function in severe propagation conditions in smart grid applications. The data/packet communications need to be maintained by synchronized timing and reliability through equally considering the signal deterioration occurrences, which are propagation delay, phase errors and channel conditions. Phase synchronization plays a vital part in the digital smart grid to get precise and real-time control measurement information. IEEE C37.118 and IEC 61850 had implemented for the synchronization communication to measure as well as control the smart grid applications. Both IEEE C37.118 and IEC 61850 experienced a huge propagation and packet delays due to synchronization precision issues. Because of these delays and errors, measurement and monitoring of the smart grid application in real-time is not accurate. Therefore, it has been investigated that the time synchronization in real-time is a critical challenge in smart grid applications, and for this issue, other errors raised consequently. The existing communication systems are designed with the phasor measurement unit (PMU) along with communication protocol IEEE C37.118 and uses the GPS timestamps as the reference clock stamps. The absence of GPS increases the clock offsets, which surely can hamper the synchronization process and the full control measurement system that can be imprecise. Therefore, to reduce this clock offsets, a new algorithm is needed which may consider any alternative reference timestamps rather than GPS. The revolutionary Artificial Intelligence (AI) enables the industrial revolution to provide a significant performance to engineering solutions. Therefore, this article proposed the AI-based Synchronization scheme to mitigate smart grid timing issues. The backpropagation neural network is applied as the AI method that employs the timing estimations and error corrections for the precise performances. The novel AIFS scheme is considered the radio communication functionalities in order to connect the external timing server. The performance of the proposed AIFS scheme is evaluated using a MATLAB-based simulation approach. Simulation results show that the proposed scheme performs better than the existing system.

     

A framework for harmonizing internet of things (IoT) in cloud: analyses and implementation

Internet of Things (IoT) refers to uniquely identifiable entities. Its vision is the world of connected objects. Due to its connected nature the data produced by IoT is being used for different purposes. Since IoT generates huge amount of data, we need some scalable storage to store and compute the data sensed from the sensors. To overcome this issue, we need the integration of cloud and IoT, so that the data might be stored and computed in a scalable environment. Harmonization of IoT in Cloud might be a novel solution in this regard. IoT devices will interact with each other using Constrained Application Protocol (CoAP). In this paper, we have implemented harmonizing IoT in Cloud. We have used CoAP to get things connected to each other through the Internet. For the implementation we have used two sensors, fire detector and the sensor attached with the door which is responsible for opening it. Thus our implementation will be storing and retrieving the sensed data from the cloud. We have also compared our implementation with different parameters. The comparison shows that our implementation significantly improves the performance compared to the existing system.

     

A comparative study on the electronic and optical properties of Sb<Subscript>2</Subscript>Se<Subscript>3</Subscript> thin film

The thin film of Sb₂Se₃ was deposited by thermal evaporation method and the film was annealed in N₂ flow in a three zone furnace at a temperature of 290°С for 30 min. The structural properties were characterized by scanning electron microscopy (SEM), transmission electron microscopy (ТЕМ), X-ray diffraction (XRD) and Raman spectroscopy, respectively. It is seen that the as-deposited film is amorphous and the annealed film is polycrystalline in nature. The surface of Sb₂Se₃ film is oxidized with a thickness of 1.15 nm investigated by X-ray photolecetron spectroscopy (XPS) measurement. Spectroscopic ellipsometry (SE) and UV–vis spectroscopy measurements were carried out to study the optical properties of Sb₂Se₃ film. In addition, the first principles calculations were applied to study the electronic and optical properties of Sb₂Se₃. From the theoretical calculation it is seen that Sb₂Se₃ is intrinsically an indirect band gap semiconductor. Importantly, the experimental band gap is in good agreement with the theoretical band gap. Furthermore, the experimental values of n, k, ε₁, and ε₂ are much closer to the theoretical results. However, the obtained large dielectric constants and refractive index values suggest that exciton binding energy in Sb₂Se₃ should be relatively small and an antireflective coating is recommended to enhance the light absorption of Sb₂Se₃ for thin film solar cells application.     

Characterization of Langmuir-Blodgett film using differential charging in X-ray photoelectron spectroscopy

Differential charging is often regarded as a problem in X-ray photoelectron spectroscopy (XPS) studies, especially for insulating or partially conducting samples. Neutralization techniques have been developed to circumvent this effect. Instead of neutralizing the positive charge, which is often the technique to obtain good quality data, it is possible to exploit this phenomenon to get useful information about the sample. An attempt is made here to use this differential charging to study the mono- and multilayer Langmuir-Blodgett (LB) films of cadmium arachidate on silicon substrate. The surface potential was probed by measuring XPS line shift with respect to their neutral position and was found to have correlation with the thickness of the films. No differential charging was observed in the monolayer LB film where there was only one layer of cadmium headgroup. Significant differential charging was observed for multilayer films, the total charging as well as the differential charging in these films increase with increasing number of layers. Angle-resolved XPS measurements were performed to obtain additional information about the structure of the films. Charging of the upper layer of the films close to the vacuum interface was found to be less compared to that of the interior. The discrete cadmium layers were found to be more differentially charged compared to the continuous hydrocarbon stacks in the multilayer LB films. Charging of the discrete cadmium layers has been utilized to obtain quantitative information of the multilayer LB films.     

Synthesis of polyhydroxy piperidines and their analogues: a novel approach towards selective inhibitors of alpha-glucosidase

Various polyhydroxy piperidine azasugars have been synthesized from precursors 18a and 18b, obtained in both enantiomeric forms from d-ribose. Out of these polyhydroxy piperidine azasugars, 22, 39 and 20 were found to be potent as well as selective inhibitors of alpha-glucosidase with K(i) values ranging as low as 1.07 microM, 16.4 microM, and 88.2 microM, respectively. Replacement of the hydroxy methylene moiety of (K(i) 33% at 1 mM) by an amino methylene moiety (32, K(i) 36.8 microM) showed a remarkable increase in the activity (almost 30 times). Furthermore, increasing the lipophilicity of by N-alkylation with a dodecyl group (36) showed a three-fold enhancement in the activity (K(i) 217 microM to K(i) 72.3 microM).     

Synthesis and characterization of silicalite-1/carbon-graphite membranes

Silicalite-1/carbon-graphite composite membranes have been prepared using a standard hydrothermal synthesis method and characterized by XRD, SEM, TGA, BET and permeation experiments. Single gas permeation fluxes and binary mixtures separation and selectivity data are reported for methane, ethane and propane using the composite membranes. Carbon-graphite oxidized for 4 h prior to membrane preparation had the most promising separation properties. The permeation fluxes for the binary mixtures reflect that of the single component flux ratios. At 20 degrees C the membranes show high separation selectivity toward lighter component in binary mixtures. Single gas permeances for methane and ethane were found to decrease with increasing temperatures while that of propane fluctuates.     

Amphiphilic block copolymer-stabilized gold nanoparticles for aerobic oxidation of alcohols in aqueous solution

Stable Au nanoparticles in P123 aqueous solution using a simple method have been developed and the colloidal Au nanoparticles were successfully applied for the effective oxidation of various alcohols using molecular O(2) as oxidant at 30 degrees C in aqueous solution.     

Two-Dimensional Supramolecular Polymerization of a Bis-Urea Macrocycle into a Brick-Like Hydrogen-Bonded Network

We report on a dendronized bis-urea macrocycle 1 self-assembling via a cooperative mechanism into two-dimensional (2D) nanosheets formed solely by alternated urea-urea hydrogen bonding interactions. The pure macrocycle self-assembles in bulk into one-dimensional liquid-crystalline columnar phases. In contrast, its self-assembly mode drastically changes in CHCl₃ or tetrachloroethane, leading to 2D hydrogen-bonded networks. Theoretical calculations, complemented by previously reported crystalline structures, indicate that the 2D assembly is formed by a brick-like hydrogen bonding pattern between bis-urea macrocycles. This assembly is promoted by the swelling of the trisdodecyloxyphenyl groups upon solvation, which frustrates, due to steric effects, the formation of the thermodynamically more stable columnar macrocycle stacks. This work proposes a new design strategy to access 2D supramolecular polymers by means of a single non-covalent interaction motif, which is of great interest for materials development.     

Through-bond excited energy transfer mediated by an amidinium-carboxylate salt bridge in Zn-porphyrin free-base porphyrin dyads

Excited energy-transfer processes were investigated for a supramolecular Zn-porphyrin free-base porphyrin dyad, ZnPA-2 x FbPC-2, in which beta-octaalkylated meso-diarylporphyrins are connected through an amidinium-carboxylate salt bridge. The rate of energy transfer in the dyad (1.3 x 10(9) s(-1)) is substantially slower than that in the previously reported dyad, ZnPA-1FbPC-1 (4.0 x 10(9) s(-1)), in which meso-tetraarylporphyrins are connected through the same amidinium-carboxylate salt bridge. The F?rster-type mechanism can explain only minor parts of these rates (3.3 x 10(8) and 5.1 x 10(8) s(-1), respectively). Thus, Dexter-type through-bond energy transfer may be invoked. Indeed, bridge-mediated electronic processes would be favored in ZnPA-1 x FbPC-1 over ZnPA-2 x FbPC-2 on the basis of steric and electronic factors. Sterically, the phenyl groups in ZnPA-2 and FbPC-2 are more closely perpendicular to the porphyrin planes than those in ZnPA-1 and FbPC-1. Electronically, the energy and symmetry of the occupied frontier orbitals should favor ZnPA-1 x FbPC-1 over ZnPA-2 x FbPC-2 in terms of electronic interactions through the bridge. Therefore, the observed trend (ZnPA-1 x FbPC-1>ZnPA-2 x FbPC-2), consistent with these considerations, lends further support to the through-bond mechanism. Thus, the amidinium-carboxylate salt bridge is effective in mediating through-bond energy transfer even though the bond is noncovalent.