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121.
122.
JitKang Lim David X. Tan Robert D. Tilton Sara A. Majetich 《Journal of magnetism and magnetic materials》2009,321(10):1557-1562
Peclet number analysis is performed to probe the convective motion of nanospheres and nanorods under the influence of magnetophoresis and diffusion. Under most circumstances, magnetophoretic behaviour dominates diffusion for nanorods, as the magnetic field lines tend to align the magnetic moment along the rod axis. The synthesis and dispersion of fluorophore-tagged nanorods are described. Fluorescence microscopy is employed to image the nanorod motion in a magnetic field gradient. The preliminary experimental data are consistent with the Peclet number analysis. 相似文献
123.
High diffusion barrier and piezoelectric nanocomposites based on polyvinylidene fluoride‐trifluoroethylene copolymer and hydrophobized clay 下载免费PDF全文
Sara Dalle Vacche Fabiane Oliveira Olha Sereda Antonia Neels Alex Dommann Dragan Damjanovic Yves Leterrier 《Journal of Polymer Science.Polymer Physics》2017,55(24):1828-1836
Nanocomposites based on polyvinylidene fluoride–trifluoroethylene copolymer and up to 4 vol % of hydrophobized clay nanoparticles are investigated. The structure, piezoelectric properties, and oxygen permeability of solvent cast films are analyzed before and after annealing above the Curie temperature of the polymer. Exfoliation of the clay takes place at concentrations up to 1 vol %, beyond which it rapidly drops and is absent at a concentration of 4 vol %. The presence of clay does not change the crystallinity of the polymer, but leads to a threefold decrease of the oxygen permeability at a concentration of 0.5 vol %. Annealing at 130 °C increases the crystallinity, the proportion of β phase up to 94%, and the piezoelectric coefficient by 20–40% at clay fractions below 1 vol %. Annealing also leads to a remarkable 3‐ to 10‐fold decrease of O2 permeability and to intriguing changes of the activation energy for O2 transport, which decreases from 56 kJ/mol for the as‐cast polymer to below 10 kJ/mol for the polymer and exfoliated composite. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 1828–1836 相似文献
124.
Novel intermediates based on the Corey skeleton for preparation of the ω-chain of non-halogenated unnatural prostaglandin analogues containing a triple bond at position 13–14 (PG numbering) were synthesized. The utilization of a novel synthetic approach towards a new tin intermediate, and subsequent Stille coupling opens up new possibilities for preparing these important pharmaceutical intermediates. 相似文献
125.
MaxwellD. Cummings Jimmy Lindberg Tse‐I Lin Herman deKock Oliver Lenz Elisabet Lilja Sara Fellnder Vera Baraznenok Susanne Nystrm Magnus Nilsson Lotta Vrang Michael Edlund sa Rosenquist Bertil Samuelsson Pierre Raboisson Kenneth Simmen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2010,122(9):1552-1552
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The objective of any night vision system is to enable a person to see in the dark. A low-contrast image puts a contrast constraint on the human observer visibility at night. This is the basic reason for the large number of accidents at night. This research presents two proposed approaches to enhance the visibility of the infrared (IR) night vision images through an efficient histogram processing. The first approach is based on contrast limited adaptive histogram equalization. The second proposed approach depends on histogram matching. The histogram matching uses a reference visual image for converting night vision images into good quality images. The obtained results are evaluated with quality metrics such as entropy, average gradient, contrast improvement factor and sobel edge magnitude. 相似文献
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Ernesto C. Tuazon Pilar Martin Sara M. Aschmann Janet Arey Roger Atkinson 《国际化学动力学杂志》2011,43(11):631-638
Rate constants for the reactions of 2‐methoxy‐6‐(trifluoromethyl)pyridine, diethylamine, and 1,1,3,3,3‐pentamethyldisiloxan‐1‐ol with OH radicals have been measured at 298 ± 2 K using a relative rate method. The measured rate constants (cm3 molecule?1 s?1) are (1.54 ± 0.21) × 10?12 for 2‐methoxy‐6‐(trifluoromethyl)pyridine, (1.19 ± 0.25) × 10?10 for diethylamine, and (1.76 ± 0.38) × 10?12 for 1,1,3,3,3‐pentamethyldisiloxan‐1‐ol, where the indicated errors are the estimated overall uncertainties including those in the rate constants for the reference compounds. No reaction of 2‐methoxy‐6‐(trifluoromethyl)pyridine with gaseous nitric acid was observed, and an upper limit to the rate constant for the reaction of 1,1,3,3,3‐pentamethyldisiloxan‐1‐ol with O3 of <7 × 10? 20 cm3 molecule?1 s?1 was determined. Using a 12‐h average daytime OH radical concentration of 2 × 106 molecule cm?3, the lifetimes of the volatile organic compounds studied here with respect to reaction with OH radicals are 7.5 days for 2‐methoxy‐6‐(trifluoromethyl)pyridine, 1.2 h for diethylamine, and 6.6 days for 1,1,3,3,3‐pentamethyldisiloxan‐1‐ol. Likely reaction mechanisms are discussed. © 2011 Wiley Periodicals, Inc. Int J Chem Kinet 43: 631–638, 2011 相似文献
130.
Christopher J. Morris Brian Mary Sara Barron Omar Knio Ralph Hodgin Chadd May 《Journal of Physics and Chemistry of Solids》2010,71(2):84-1650
Research into nanoenergetic materials is enabling new capabilities for controlling exothermic reaction rates and energy output, as well as new methods for integrating these materials with conventional electronics fabrication techniques. Many reactions produce primarily heat, and in some cases it is desirable to increase the rate of heat release beyond what is typically observed. Here we investigate the Al-Ni intermetallic reaction, which normally propagates across films or foils at rates lower than 10 m/s. However, models and experiments indicate that local heating rates can be very high (107 K/s), and uniform heating of such a multilayer film can lead to a rapid, thermally explosive type of reaction. With the hopes of using a device to transduce electrical energy to kinetic energy of a flyer plate in the timescale of 100's of nanoseconds, we have incorporated a Ni/Al nanolayer film that locally heats upon application of a large electrical current. We observed flyer plate velocities in the 2-6 km/s range, corresponding to 4-36 kJ/g in terms of specific kinetic energy. Several samples containing Ni/Al films with different bilayer thicknesses were tested, and many produced additional kinetic energy in the 1.1-2.3 kJ/g range, as would be expected from the Ni-Al intermetallic reaction. These results provide evidence that nanoscale Ni/Al layers reacted in the timescale necessary to contribute to device output. 相似文献