Meso-diacylated calix[4]pyrrole: structural diversities and enhanced binding towards dihydrogenphosphate ion

Meso-diacylated calix[4]pyrrole was obtained via acid catalysed condensation of meso-acylated dipyrromethane with acetone. Selective presence of flexible substituents at the calix[4]pyrrole periphery led to interesting structural motifs in the solid state along with enhanced binding towards anions, especially dihydrogenphosphate ion via anchoring.     

Highly Conductive Carbon Nanotube‐Graphene Hybrid Yarn

An efficient procedure for the fabrication of highly conductive carbon nanotube/graphene hybrid yarns has been developed. To start, arrays of vertically aligned multi‐walled carbon nanotubes (MWNT) are converted into indefinitely long MWNT sheets by drawing. Graphene flakes are then deposited onto the MWNT sheets by electrospinning to form a composite structure that is transformed into yarn filaments by twisting. The process is scalable for yarn fabrication on an industrial scale. Prepared materials are characterized by electron microscopy, electrical, mechanical, and electrochemical measurements. It is found that the electrical conductivity of the composite MWNT‐graphene yarns is over 900 S/cm. This value is 400% and 1250% higher than electrical conductivity of pristine MWNT yarns or graphene paper, respectively. The increase in conductivity is asssociated with the increase of the density of states near the Fermi level by a factor of 100 and a decrease in the hopping distance by an order of magnitude induced by grapene flakes. It is found also that the MWNT‐graphene yarn has a strong electrochemical response with specific capacitance in excess of 111 Fg^?1. This value is 425% higher than the capacitance of pristine MWNT yarn. Such substantial improvements of key properties of the hybrid material can be associated with the synergy of MWNT and graphene layers in the yarn structure. Prepared hybrid yarns can benefit such applications as high‐performance supercapacitors, batteries, high current capable cables, and artificial muscles.     

LHAP: A lightweight network access control protocol for ad hoc networks

Most ad hoc networks do not implement any network access control, leaving these networks vulnerable to resource consumption attacks where a malicious node injects packets into the network with the goal of depleting the resources of the nodes relaying the packets. To thwart or prevent such attacks, it is necessary to employ authentication mechanisms to ensure that only authorized nodes can inject traffic into the network. We propose LHAP, a hop-by-hop authentication protocol for ad hoc networks. LHAP resides in between the network layer and the data link layer, thus providing a layer of protection that can prevent or thwart many attacks from happening, including outsider attacks and insider impersonation attacks. Our detailed performance evaluation shows that LHAP incurs small performance overhead and it also allows a tradeoff between security and performance.     

Electrical properties of a-antimony selenide

This paper reports conduction mechanism in a-Sb₂Se₃ over a wide range of temperature (238 to 338 K) and frequency (5 Hz to 100 kHz). The d.c. conductivity measured as a function of temperature shows semiconducting behaviour with activation energy ΔE=0.42 eV. Thermally induced changes in the electrical and dielectric properties of a-Sb₂Se₃ have been examined. The a.c. conductivity in the material has been explained using modified CBH model. The band conduction and single polaron hopping is dominant above room temperature. However, in the lower temperature range the bipolaron hopping dominates.     

Domain formation and orbital ordering transition in a doped Jahn-Teller insulator

The ground state of a double-exchange model for orbitally degenerate e(g) electrons with Jahn-Teller lattice coupling and weak disorder is found to be spatially inhomogeneous near half filling. Using a real-space Monte Carlo method we show that doping the half-filled orbitally ordered insulator leads to the appearance of hole-rich disordered regions in an orbitally ordered environment. The doping driven orbital order to disorder transition is accompanied by the emergence of metallic behavior. We present results on transport and optical properties along with spatial patterns for lattice distortions and charge densities, providing a basis for an overall understanding of the low-doping phase diagram of La1 - xCaxMnO3.     

Comparative study of asymmetric versus symmetric planar slab dielectric optical waveguides

In this paper we have studied the asymmetric versus symmetric planar waveguide in terms of their usefulness in optical fiber communication systems. We have explored the thin waveguide versus thick waveguide first. Later on usefulness of asymmetric versus symmetric waveguide is carried out to target for WDM optical network application. All kinds of optical network components are fabricated on Si substrate with the point of view of their application. Here asymmetric planar structure may be more useful compared to symmetric waveguide in terms of their non-uniform power confinement properties. However, the symmetric waveguide structure may be more useful for their high power confinement properties. It is well known that the thin symmetric waveguide supports at least one mode. However the thick waveguide may support many even as well as odd modes. We study the power confinement properties for symmetric as well as asymmetric waveguide structure. We conclude that higher order modes show the nonlinear power variations. Mode field profile for various cases is discussed as well. Comparative study between asymmetric versus symmetric waveguide has a lot of significance in optical network area. It has been shown through analysis that in asymmetric waveguide, the power flows more through film region in the case of fundamental mode. Power confinement properties for asymmetric waveguide versus symmetric waveguide have been studied.     

Can multiple subchannels improve the delay performance of RTS/CTS-based MAC schemes?

We analyze the delay performance of RTS/CTS-based (Request-To-Send/Clear-To-Send) multi-channel MAC (Medium Access Control) schemes for wireless networks. These schemes usually employ multiple data subchannels for data transmission and one control subchannel to send the RTS/CTS dialogue for channel reservation. Through theoretical analysis and simulations, we show that, in fully-connected networks, such multi-channel MAC schemes suffer longer delays than the corresponding single channel MAC scheme, that puts the RTS/CTS dialogue on the same channel as data packet transmissions. This conclusion holds even when data packets have different priorities and higher priority traffic is sent ahead of lower priority traffic.     

Phonon Dispersion in Polypyrrole

A study of the normal modes of vibration and their dispersion in polypyrrole (PPY) based on the Urey-Bradley force field is reported. It gives a fuller interpretation of previously reported FTIR spectra. Characterstic features of dispersion curves, such as regions of high density-of-states, repulsion, and character mixing of dispersive modes, are discussed. Predictive values of heat capacity as a function of temperature are reported.     

DLTS and in situ C–V analysis of trap parameters in swift 50 MeV Li3+ ion-irradiated Ni/SiO2/Si MOS capacitors

Ni/SiO₂/Si MOS structures were fabricated on n-type Si wafers and were irradiated with 50 MeV Li³⁺ ions with fluences ranging from 1×10¹⁰ to 1×10¹² ions/cm². High frequency C–V characteristics are studied in situ to estimate the build-up of fixed and oxide charges. The nature of the charge build-up with ion fluence is analyzed. Defect levels in bulk Si and its properties such as activation energy, capture cross-section, trap concentration and carrier lifetimes are studied using deep-level transient spectroscopy. Electron traps with energies ranging from 0.069 to 0.523 eV are observed in Li ion-irradiated devices. The dependence of series resistance, substrate doping and accumulation capacitance on Li ion fluence are clearly explained. The study of dielectric properties (tan δ and quality factor) confirms the degradation of the oxide layer to a greater extent due to ion irradiation.