Experimental determination technique for magnetic anisotropy of individual nanowires

We present an experimental technique to determine the magnetic anisotropy of ferromagnetic nanowires. In the technique, the magnetization state is monitored by measuring the anisotropic magnetoresistance with rotating the external magnetic field. The measured magnetoresistance curves exhibit basically the same curves typically appeared in the torque magnetometric measurements, which are then readily analyzed based on the Stoner–Wohlfarth theory with a single fitting parameter – the magnetic anisotropy. By applying the present technique to Permalloy nanowires, it is shown that the shape anisotropy in real nanowires is significantly influenced by the edge roughness.     

Electronic structures of imidazolium-based ionic liquids

Electronic structures of ionic liquids formed by 1-buthyl-3-alkylimidazolium ion [C_nmim]⁺ (n = 4 and 8) with various inorganic and organic anions have been investigated by ultraviolet photoemission, X-ray photoemission, inverse photoemission and soft X-ray emission spectroscopies (SXES). The comparison of the calculated density of states with the observed spectra revealed that the molecular orbital energies of these ionic liquids are significantly affected by the electrostatic Madelung potential among the ions. The SXES results clearly show that the both highest occupied and lowest unoccupied states of [C₄mim]⁺PF₆⁻ are derived from the cation as a result of strong Madelung potential. On the other hand, the SXES results show the valence electronic structures of ionic liquids with larger anion molecules, [C_nmim]⁺Tf₂N⁻ and [C_nmim]⁺OTf⁻ are contributed from the both cation and anion.     

Piston error characteristics of the self-phase-controlled stimulated Brillouin scattering phase conjugate mirrors

It was reported by Kong et al. that the self-phase-controlled stimulated Brillouin scattering phase conjugate mirror (SBS-PCM) is useful for the beam combination laser amplifier system, which generally introduces a phase delay (piston error) between combined beams along separate optical paths. In this work, we have investigated the piston error characteristics of two schemes for self-phase-controlled SBS-PCMs, a collinear scheme and a triangular scheme. Experimental results show that the piston errors of the reflected beams are 2kδ and kδ for the former and the latter scheme, respectively, where k is the wave number and δ is the optical path difference (OPD) variation introduced into the pass.     

Point defects along metallic atomic wires on vicinal Si surfaces: Si(5 5 7)–Au and Si(5 5 3)–Au

Point defects on the metallic atomic wires induced by Au adsorbates on vicinal Si surfaces were investigated using scanning tunneling microscopy and spectroscopy (STM and STS). High-resolution STM images revealed that there exist several different types of defects on the Si(5 5 7)–Au surface, which are categorized by their apparent bias-dependent images and compared to the previous report on Si(5 5 3)–Au [Phys. Rev. B (2007) 205325]. The chemical characteristics of these defects were investigated by monitoring them upon the variation of the Au coverage and the adsorption of water molecules. The chemical origins and the tentative atomic structures of the defects are suggested as Si adatoms (and dimers) in different registries, the Au deficiency on terraces, and water molecules adsorbed dissociatively on step edges, respectively. STS measurements disclosed the electronic property of the majority kinds of defects on both Si(5 5 7)–Au and Si(5 5 3)–Au surfaces. In particular, the dominating water-induced defects on both surfaces induce a substantial band gap of about 0.5 eV in clear contrast to Si adatom-type defects. The conduction channels along the metallic step-edge chains thus must be very susceptible to the contamination through the electronic termination by the water adsorption.     

Modified smart pixel mapping method for displaying orthoscopic 3D images in integral imaging

In this paper, we propose a modified smart pixel mapping (MSPM) method for displaying orthoscopic three-dimensional (3D) images with a function of depth control in integral imaging system. In the proposed MSPM, the depth-converted elemental image array (EIA) is obtained through the pixel mapping process and the image interpolation technique. The proposed method gives us the depth conversion at distances different from the position of 3D object and provides various types of EIAs using only an original EIA for orthoscopic images. To show the usefulness of the proposed method, we carry out the preliminary experiments and present the experimental results.     

Chemo- and regioselective halogenation of 4-(pyrazol-4-yl)-pyrimidines

A convenient and selective halogenation of 4-(pyrazol-4-yl)-pyrimidines is described herein. This method allows quick access to a diverse set of pyrazolyl-pyrimidine derivatives.     

Versatile Photophysical Properties of meso‐Aryl‐Substituted Subporphyrins: Dipolar and Octupolar Charge‐Transfer Interactions

Donor–acceptor systems based on subporphyrins with nitro and amino substituents at meta and para positions of the meso‐phenyl groups were synthesized and their photophysical properties have been systematically investigated. These molecules show two types of charge‐transfer interactions, that is, from center to periphery and periphery to center depending on the peripheral substitution, in which the subporphyrin moiety plays a dual role as both donor and acceptor. Based on the solvent‐polarity‐dependent photophysical properties, we have shown that the fluorescence emission of para isomers originates from the solvatochromic, dipolar, symmetry‐broken, and relaxed excited states, whereas the non‐solvatochromic fluorescence of meta isomers is of the octupolar type with false symmetry breaking. The restricted meso‐(4‐aminophenyl) rotation at low temperature prevents the intramolecular charge‐transfer (ICT)‐forming process. The two‐photon absorption (TPA) cross‐section values were determined by photoexcitation at 800 nm in nonpolar toluene and polar acetonitrile solvents to see the effect of ICT on the TPA processes. The large enhancement in the TPA cross‐section value of approximately 3200 GM (1 GM=10^?50 cm⁴ s photon^?1) with donor–acceptor substitution has been attributed to the octupolar effect and ICT interactions. A correlation was found between the electron‐donating/‐withdrawing abilities of the peripheral groups and the TPA cross‐section values, that is, p‐aminophenyl>m‐aminophenyl>nitrophenyl. The increased stability of octupolar ICT interactions in highly polar solvents enhances the TPA cross‐section value by a factor of approximately 2 and 4, respectively, for p‐amino‐ and m‐nitrophenyl‐substituted subporphyrins. On the other hand, the stabilization of the symmetry‐broken, dipolar ICT state gives rise to a negligible impact on the TPA processes.