Dihalodimethyltin(IV) complexes of 2‐(pyrazol‐1‐ylmethyl)pyridine

Reaction of dichloro‐ and dibromodimethyltin(IV) with 2‐(pyrazol‐1‐ylmethyl)pyridine (PMP) afforded [SnMe₂Cl₂(PMP)] and [SnMe₂Br₂(PMP)] respectively. The new complexes were characterized by elemental analysis and mass spectrometry and by IR, Raman and NMR (¹H, ¹³C) spectroscopies. Structural studies by X‐ray diffraction techniques show that the compounds consist of discrete units with the tin atom octahedrally coordinated to the carbon atoms of the two methyl groups in a trans disposition (Sn? C = 2.097(5), 2.120(5) Å and 2.110(6), 2.121(6) Å in the chloro and in the bromo compounds respectively), two cis halogen atoms (Sn? Cl = 2.4908(16), 2.5447(17) Å; Sn? Br = 2.6875(11), 2.7464(9) Å) and the two donor atoms of the ligand (Sn? N = 2.407(4), 2.471(4) Å and 2.360(5), 2.455(5) Å). In both cases, the Sn? N(pyridine) bond length is markedly longer than the Sn? N(pyrazole) distance. Copyright © 2003 John Wiley & Sons, Ltd.     

On some periodic solutions of singularly perturbed parabolic equations

We present results from the theory of singular perturbations and, in particular, from a new branch of this theory (contrast alternating-type structures). __________ Translated from Ukrains’kyi Matematychnyi Zhurnal, Vol. 59, No. 3, pp. 359–369, March, 2007.     

Embedding and wavelet decomposition of spaces of minimal splines

On a sequence of embedded nonuniform grids, chains of embedded spaces of minimal splines (not necessarily polynomial) are constructed. The wavelet decomposition is given. The basis wavelets are compactly supported and admit simple analytic representation. The corresponding decomposition and reconstruction formulas are derived. The variety of spaces under consideration is identified with the variety of complete sequences of points of the direct product of an interval and a projective plane. Bibliography: 20 titles. __________ Translated from Problemy Matematicheskogo Analiza, No. 35, 2007, pp. 15–31     

Features of polystyrene synthesis in the presence of (diphenylbutadiene)tricarbonylchromium

Features of radical polymerization of styrene in the presence of (diphenylbutadiene)tricarbonylchromium were studied.     

Oxidative destruction of dinitrophenols by Fenton’s reagent in the presence of inorganic salts

The influence of inorganic salts on the kinetics of oxidation of 2,4-and 2,6-dinitrophenols by Fenton’s reagent, hydrogen peroxide, in the presence of iron(II) ions was studied.     

Surface modification of polystyrene with the bovine serum albumin-Tween 80 complex and a forecast of biocompatibility

The surface of polystyrene was modified with the bovine serum albumin-Tween 80 complex. The adsorption of the complex and the formation of films on the surface of polystyrene were studied using the piezoelectric weighing method. The state of the modified surface was evaluated by contact angle measurements. The stability of the modifying layer was determined based on the critical interfacial energy values of the surface equilibrated with water. A conclusion was drawn that the complex can be effectively used to enhance the biocompatibility of polymer materials.     

Fault tolerance in FFT arrays: Time redundancy approaches

Fault tolerance in VLSI/WSI FFT arrays acquires relevance when defects and run-time faults become significant, due to large dimensions of processors and arrays. Then, both restructuring to overcome end-of-production defects and reconfiguration to overcome run-time faults are required, to achieve the dual purposes of higher yield and higher reliability.Adopting as basic FFT network the two-dimensions array that directly corresponds to the FFT flow graph, the usual structure redundancy techniques tailored for two-dimensions arrays reconfiguration are not well applicable, since the limited locality of this network leads to relevant area increase due to the augmented interconnection structure.In this paper,time redundancy is suggested as a viable alternative for the two-dimensions FFT array; two different solutions are presented, one based oninter-stage reconfiguration, the other one adoptingintra-state reconfiguration, both allowing for survival to multiple faults with limited increase of network complexity and very small hard-core sections. As usual in many time redundancy methods, both approaches result in a processing speed equal to half the processing speed granted by an ideal, fault-free device.Reliability and survival ratios to multiple faults are evaluated for the two cases, taking into account also the area increments necessary for fault tolerance. The reliability evaluations allow for a direct comparison of the two solutions.     

Deformation of styrene—divinylbenzene copolymers and hypercrosslinked polystyrenes during solvent adsorption and desorption

An automated procedure was developed for monitoring fast changes in the size of spherical samples of polymers during their contact with a solvent or drying. The kinetics of bulk deformation in these processes was studied for a series of cross-linked polymers, viz., gel-type and porous styrene—divinylbenzene copolymers and poly(divinylbenzenes), and hypercrosslinked polystyrenes. Gel, macroporous, and hypercrosslinked polystyrenes are substantially different in the rate, mechanism, and degree of swelling, which is associated with the principal differences in their physical structures. An unusual effect of a sharp decrease followed by a temporary increase in the volume of porous polystyrene and poly(divinylbenzene) materials were observed during desorption (evaporation) of organic solvents. Water desorption is accompanied by an excessive bulk compression of porous granules giving rise to negative deformations, which gradually relax to the state equilibrium for the dry polymer. The results of dynamic desorption porometry (for water desorption) are indicative of a bimodal size distribution of micropores in hypercrosslinked polystyrene. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 467–476, March, 2007.