Series solution for unsteady axisymmetric flow and heat transfer over a radially stretching sheet

This paper deals with the unsteady axisymmetric flow and heat transfer of a viscous fluid over a radially stretching sheet. The heat is prescribed at the surface. The modelled non-linear partial differential equations are solved using an analytic approach namely the homotopy analysis method. Unlike perturbation technique, this approach gives accurate analytic approximation uniformly valid for all dimensionless time. The explicit expressions for velocity, temperature and skin friction coefficient are developed. The influence of time on the velocity, temperature and skin friction coefficient is discussed.     

CFD analysis of an oscillating wing at various reduced frequencies

The effect of various reduced frequencies has been examined for an oscillating aspect ratio 10 NACA 0015 wing. An unsteady, compressible three‐dimensional (3D) Navier–Stokes code based on Beam and Warming algorithm with the Baldwin–Lomax turbulence model has been used. The code is validated for the study against published experimental data. The 3D unsteady flow field is simulated for reduced frequency values of 0.1, 0.2 and 0.3 for a fixed mean angle of attack position and fixed amplitude. The type of motion is sinusoidal harmonic. The force coefficients, pressure distributions and flow visualization show that at the given conditions the flow remains attached to the wing surface even at high angles of attack with no clear separation or typical light‐to‐deep category of dynamic stall. Increased magnitude of hysteresis and higher gradients are seen at higher reduced frequencies. The 3D effects are even found at midspan locations. In addition, the rate of decrease in lift near the wing tips compared with the wing root is not much like in the static cases. Copyright © 2008 John Wiley & Sons, Ltd.     

Existence and approximation of solutions for a class of nonlinear impulsive functional differential equations with anti-periodic boundary conditions

This paper describes the method of quasilinearization for first-order nonlinear impulsive functional differential equations with anti-periodic boundary conditions. A monotone iterative technique coupled with lower and upper solutions is employed to obtain sequences of approximate solutions converging monotonically and quadratically to the unique solution of the problem at hand.     

Metal ion-catalysed reduction of indolic imides,a facile β-carboline synthesis

A novel procedure for the synthesis of β-carbolines by metal catalysed reduction of imides with sodium borohydride is described.     

Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry of dextran and dextrin derivatives

Application of matrix-assisted laser desorption/ionization (MALDI) to the analysis of dextran and dextrin derivatives, specifically glucose saccharides, by time-of-flight (TOF) mass spectrometry has been reported. MALDI-TOF analysis was carried out on alpha-, beta- and gamma-cyclodextrin, two O-methylated-beta-cyclodextrins of differing degrees of substitution (DS) and dextrans (a linear glucose saccharide), as pure and doped solutions and as mixtures of two or more of these. Doping was carried out with trace amounts of inorganic salts. The purpose of the analysis of the cyclodextrins was to determine whether they would form inclusion complexes with the various cations added, or whether less specific cation addition/exchange was occurring either prior to desorption or in the gas phase.     

Non-trivial temperature effects on the cation exchange chromatography and chelation ion chromatography of metal ions

The effect of column temperature upon the retention of metal ions on sulfonated and mono-, di-, and amino-carboxylated cation exchange columns has been investigated. The retention of alkali, alkaline earth and transition metal ions on each of the above types of cation exchanger was studied over the temperature range 19-65 degrees C. A major difference between the behaviour of mono- and divalent metal ions was shown on each of the above stationary phases, with the monovalent alkali metals exhibiting clearly exothermic behaviour (a decrease in retention with increased temperature) under acidic eluent conditions and an apparent relationship between retention factor and the magnitude of the temperature effect. The effect of temperature upon alkaline earth metal ions was less defined, although strongly endothermic behaviour (increase in retention with temperature) could be seen on all stationary phases through correct choice of eluent. The transition metal ions studied showed endothermic behaviour on all four stationary phases, with the sulfonated column unexpectedly showing the largest increases in retention. The above behaviour can be partially explained through the dominance of the type of solute-stationary phase interaction governing retention. In several of the above columns, both ion-exchange and surface complexation interactions can occur, with the effects of temperature indicating which process dominates under specific eluent conditions.     

Analytical performance of a high-pressure radio frequency-only quadrupole collision cell with an axial field applied by using conical rods

The effect on triple-quadrupole performance of applying an axial field, in an rf-only quadrupole collision cell operated at pressures sufficiently high that collisional focusing is operating, has been investigated. The advantages of such cells have been shown previously to include increased transmission and much improved resolution in fragment ion spectra relative to the performance of collision cells operating at lower gas pressures. The disadvantages of high-pressure collision cells all derive from the relatively long transit times for the ions, which can be long relative to characteristic times for scanning the first mass filter (precursor ion selector) or for switching its setting in multiple reaction monitoring (MRM) cycles. The present work describes experiments on a high-pressure cell in which an axial field is created through use of conical rather than cylindrical or hyperbolic rods. In addition, results of computations of the electric fields within such a cell, and of ion trajectories through it, are presented. It is shown that application of axial fields of the order of 0. 1 V/cm can remove all hysteresis effects associated with the long ion transit times, and thus provide excellent performance in quantitation work using MRM, as well as in other scan modes. Furthermore, the advantages of collisional focusing in quadrupole collision cells are shown to be unimpaired by these low axial fields.     

A Digital Image Confidentiality Scheme Based on Pseudo-Quantum Chaos and Lucas Sequence

Several secure image encryption systems have been researched and formed by chaotic mechanisms in current decades. This work recommends an innovative quantum color image encryption method focused on the Lucas series-based substitution box to enhance the competence of encryption. The suggested encryption technique has more excellent key space and significant confidentiality. The chaotic system, along with the substitution box, exhibits additional complicated dynamical behavior, sufficient arbitrariness, and uncertainty than all others focused on just chaotic models. Theoretical and simulation assessments show that the offered image encryption performs admirably, its traditional equivalents in terms by efficiency in terms of statistical analysis.     

DTW Based Classification of Diverse Pre-Processed Time Series Obtained from Handwritten PIN Words and Signatures

Personal identity verification by means of signature handwriting dynamics is a widely researched aspect of behavioral biometrics. The Dynamic Time Warping (DTW) technique has been successfully used for accessing the similarity of time series of handwritten objects by minimizing non-linear time distortions. Generally, in DTW based classifiers, the sequences are normalized in time and amplitude domains. In the paper, different length and amplitude normalization techniques are applied on signatures and handwritten PIN word sequences and their influence on accuracy of recognition are examined. A special approach to amplitude normalization based on reference level assigned Dynamic Time Warping (DTW) technique is presented. The standard deviation values calculated from the time series are used as so called bio-reference levels to improve the performance of classification. For this, they are added to the time series of query and sample datasets prior to DTW matching. The acquisition of online data is carried out by a digital pen equipped with pressure and inclination sensors. The time series obtained from the pen during handwriting provide valuable insight into the unique characteristics of the writers. Experimental results show that with the help of proposed length and amplitude normalizations of sequences including the bio-reference levels, the computational time is reduced and false acceptance rates are decreased.