全文获取类型
收费全文 | 818篇 |
免费 | 28篇 |
国内免费 | 4篇 |
专业分类
化学 | 482篇 |
晶体学 | 8篇 |
力学 | 32篇 |
数学 | 87篇 |
物理学 | 121篇 |
无线电 | 120篇 |
出版年
2023年 | 6篇 |
2022年 | 38篇 |
2021年 | 34篇 |
2020年 | 36篇 |
2019年 | 21篇 |
2018年 | 39篇 |
2017年 | 29篇 |
2016年 | 41篇 |
2015年 | 18篇 |
2014年 | 14篇 |
2013年 | 58篇 |
2012年 | 39篇 |
2011年 | 40篇 |
2010年 | 26篇 |
2009年 | 36篇 |
2008年 | 34篇 |
2007年 | 25篇 |
2006年 | 27篇 |
2005年 | 20篇 |
2004年 | 16篇 |
2003年 | 21篇 |
2002年 | 16篇 |
2001年 | 13篇 |
2000年 | 17篇 |
1999年 | 9篇 |
1998年 | 12篇 |
1997年 | 16篇 |
1996年 | 15篇 |
1995年 | 11篇 |
1994年 | 9篇 |
1993年 | 4篇 |
1992年 | 7篇 |
1991年 | 6篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1988年 | 5篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1984年 | 5篇 |
1983年 | 9篇 |
1981年 | 9篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1975年 | 5篇 |
1974年 | 5篇 |
1973年 | 4篇 |
1970年 | 3篇 |
1961年 | 3篇 |
排序方式: 共有850条查询结果,搜索用时 859 毫秒
71.
Cu-doped borate glass co-doped with SnO2 nanoparticles is fabricated by melt quenching. The structure and morphology of the samples are examined by X-ray diffraction and field emission scanning electron microscopy. Up-conversion enhancement is observed in the photoluminescence (PL) and thermolumines- cence (TL) intensities of the glass. PL emission spectra are identified in the blue and green regions, and a fourfold increase in emission intensity may be observed in the presence of embedded SnO2 nanoparticles. The glow curve is recorded at 215℃, and fourfold increases in TL intensity are obtained by addition of 0.1 mol% SnO2 nanoparticles to the glass. Higher TL responses of the samples are observed in the energy range of 15-100 KeV. At energy levels greater than -0.1 MeV, however, flat responses are obtained. The activation energy and frequency factor of the second-order kinetic reaction are calculated by the peak shape method. 相似文献
72.
73.
Darryn E. Bryant Saad El-Zanati Charles Vanden Eynden Dean G. Hoffman 《Graphs and Combinatorics》2001,17(1):55-59
Let S
k
denote the complete bipartite graph K
1,
k
and let Q
n
denote the n-cube. We prove that the obvious necessary conditions for the existence of an S
k
-decomposition of Q
n
are sufficient.
Received: July 21, 1999 Final version received: May 16, 2000 相似文献
74.
Khalid Al‐Osaimi Abdulmohsen Alheraish Saad Haj Bakry 《International Journal of Network Management》2008,18(1):65-75
The STOPE‐based approach is used here for practical e‐readiness assessment case studies. The approach integrates and evaluates the various e‐readiness assessment issues, over its well‐structured domains: strategy, technology, organization, people, and environment. The case studies considered concern three Saudi organizations: a government organization, a bank, and a private sector company. The results obtained provide e‐readiness indicators that illustrate the strengths and weaknesses of each organization with regard to e‐readiness strategic development issues, information and communication technology (ICT) issues, management and organization issues, people issues, and environment issues within which the organization operates. The work shows how the approach can be practically used, and it also provides practical results that direct the organizations concerned toward enhancing their e‐readiness in response to the current trend of globalizing e‐business. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
75.
Ali Saad Manef Abderrabba Mohamed M. Chehimi 《Surface and interface analysis : SIA》2017,49(4):340-344
Mesoporous silica SBA‐15 was synthesized and silanized with azidopropyl triethoxysilane in order to design a clickable material. Fourier transform infrared analysis permitted to prove the attachment of the azidopropylene groups to SBA‐15 resulting in the reactive and functional material N3‐SBA‐15. X‐ray photoelectron spectroscopy was used to determine the surface composition of SBA‐15. However, we unexpectedly found that the surface bound azido groups undergo X‐ray induced decomposition during the X‐ray photoelectron spectroscopy analysis resulting in the formation of nitrenes. These are very reactive groups able to intercalate C―C and C―H bonds of the propylene chains as judged from the N1s peak shape. Possible mechanisms of intercalation are suggested. C1s and N1s peaks were recorded at different exposure time. N/C, N+/N and N+/C undergo exponential decay. N+/N reaches the value of zero in less than 80 min of exposure to the X‐ray source. The N+/C decay plot was fitted with first‐order kinetics, and the decomposition kinetic constant (kdec) was found to equal to 516.4 s?1. This is a fast X‐ray induced degradation which must be considered with care when examining clickable materials with surface bound alkyl azido groups. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
76.
Single crystals of the title compound are obtained from a melt of U3O8, MoO3, and excess Cs2CO3 (Pt crucible, 950 °C, 12 h, cooling rate 5 °C/h). 相似文献
77.
Three sorbent materials (A18C6-MS, DA18C6-MS and AB18C6-MS) based on the crown ether ligands, 1-aza-18-crown-6, 1,4,10,13-tetraoxa-7,16-diazacyclo octadecane and 4′-aminobenzo-18-crown-6, respectively, were prepared by the chemical immobilization of the ligand onto mesoporous silica support. The sorbents were characterized by FT-IR, scanning electron microscopy-energy dispersive X-ray microanalysis, elemental analysis and nitrogen adsorption-desorption test. The applicability of the sorbents for the extraction of biogenic amines by the batch sorption method was extensively studied and evaluated as a function of pH, biogenic amines concentration, contact time and reusability. Under the optimized conditions, all the sorbents exhibited highest selectivity toward spermidine (SPD) compared to other biogenic amines (tryptamine, putrescine, histamine and tyramine). Among the sorbents, AB18C6-MS offer the highest capacity and best selectivity towards SPD in the presence of other biogenic amines. The AB18C6-MS sorbent can be repeatedly used three times as there was no significant degradation in the extraction of the biogenic amines (%E > 85). The optimized procedure was successfully applied for the separation of SPD in food samples prior to the reversed-phase high performance liquid chromatography separation. 相似文献
78.
The development of a two phase hollow fiber liquid-phase microextraction technique, followed by gas-chromatography-flame ionization detection (GC-FID) for the profiling of the fatty acids (FAs) (lauric, myristic, palmitic, stearic, palmitoleic, oleic, linoleic, linolenic and arachidic) in vegetable oils is described. Heptadecanoic acid methyl ester was used as the internal standard. The FAs were transesterified to their corresponding methyl esters prior to the extraction. Extraction parameters such as type of extracting solvent, temperature, extraction time, stirring speed and salt addition were studied and optimized. Recommended conditions were extraction solvent, n-tridecane; extraction time, 35 min; extraction temperature, ambient; without addition of salt. Enrichment factors varying from 37 to 115 were achieved. Calibration curves for the nine FAs were well correlated (r(2)>0.994) within the range of 10-5000 μg L(-1). The limit of detection (signal:noise, 3) was 4.73-13.21 ng L(-1). The method was successfully applied to the profiling of the FAs in palm oils (crude, olein, kernel, and carotino cooking oil) and other vegetable oils (soybean, olive, coconut, rice bran and pumpkin). The encouraging enrichments achieved offer an interesting option for the profiling of the minor and major FAs in palm and other vegetable oils. 相似文献
79.
The quasisteady axisymmetrical flow of an incompressible viscous fluid past an assemblage of slip eccentric spherical particle‐in‐cell models with Happel and Kuwabara boundary conditions is investigated. A linear slip, Basset type, boundary condition on the surface of the spherical particle is used. Under the Stokesian approximation, a general solution is constructed from the superposition of the basic solutions in the two spherical coordinate systems based on the particle and fictitious spherical envelope. The boundary conditions on the particle's surface and fictitious spherical envelope are satisfied by a collocation technique. Numerical results for the normalized drag force acting on the particle are obtained with good convergence for various values of the volume fraction, the relative distance between the centers of the particle and fictitious envelope and the slip coefficient of the particle. In the limits of the motions of the spherical particle in the concentric position with cell surface and near the cell surface with a small curvature, the numerical values of the normalized drag force are in good agreement with the available values in the literature. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
80.
Kherroub Djamal Eddine Belbachir Mohammed Lamouri Saad 《Research on Chemical Intermediates》2017,43(10):5841-5856
Research on Chemical Intermediates - A new green technique to synthesize polysiloxane-type polymers is suggested based on use of chemically modified clay (Maghnite-H+) as heterogeneous,... 相似文献