Structures, stabilities, and electronic and optical properties of c(58) fullerene isomers, ions, and metallofullerenes.

The 1205 classical isomers of fullerene C58, as well as one quasi-fullerene C58 isomer with a heptagonal ring (labeled as Cs:hept) have been investigated by the quantum chemical methods PM3, HCTH/3-21G, and B3LYP/6-31G(d). Isomer C3v:0001, which has the lowest number of adjacent pentagons, is predicted to be the most stable isomer, but the quasi-fullerene isomer Cs:hept is only 2.50 kcal mol-1 higher in energy. Systematic investigations of the electronic properties of C3v:0001 and Cs:hept find that the C3v:0001 isomer has high vertical electron affinity (3.19 eV). The nucleus-independent chemical shifts (NICS) value at the center of Cs:hept (-5.1 ppm) is more negative than that of C60 (-2.8 ppm). The NICS value at the center of the heptagonal ring in Cs:hept (-2.5 ppm) indicates weakly aromatic character. In contrast, the C58(6-) and C58(8-) ions of the C3v:0001 and Cs:hept geometries possess large aromatic character, with NICS values between -14.0 and -26.2 ppm. To clarify the thermodynamic stabilities of C58 isomers at different temperatures, the entropy contributions are taken into account on the basis of the Gibbs energy at the B3LYP/6-31G(d) level. The C3v:0001 isomer prevails in a wide range of temperatures, and the Cs:hept isomer is also an important component around 2800 K. The IR spectra of C58 isomers are simulated to facilitate experimental identification of different isomers. In addition, the electronic spectra and the second-order hyperpolarizabilities are predicted by ZINDO and the sum-over-states model. The static second-order hyperpolarizability of the C3v:0001 isomer is 96.5 % larger than that of C60, and its second-order hyperpolarizabilities at external field frequencies are at least nine times larger than those of C60.     

基于嵌入式人工智能的智慧医疗健康管理系统设计

近年来,基于人工智能的医疗技术取得了丰富的研究成果,在智慧医疗的发展中发挥了重要作用,开启了智慧医疗的新时代。与传统的医疗管理方法相比,传统管理手段在生理参数测量方面的准确性较低,文中提出了一种基于嵌入式人工智能技术的系统。该系统利用AI算法对接收到的信号进行质量评估、滤波、去噪、增强、特征提取、心拍分类等处理,将NBIOT模块加载到云端并进行用户健康管理。其可以实现用户和医生之间的双向交互,甚至可以创建个人生理数据库,以实现疾病监测和动态管理。     

无限远像距中波显微光学系统设计北大核心CSCD

随着红外技术的发展,高性能红外显微系统在热物理化学、微生物及MEMS优化设计等科技领域起到了非常重要的作用,本文讨论了一种无限远像距显微系统的结构形式及设计方法,针对阵列规模320×256,像元尺寸30μm相对孔径为2的中波制冷型红外探测器,设计了一款无限远像距中波显微光学系统,放大倍率为3×,工作距离35 mm,数值孔径(NA)0.75,适合于高帧频下红外显微探测的需求以及类似显微物镜产品的系列化。     

流道缩扩比对半波纹微通道流动和传热特性的影响

为探究流道缩扩比对半波纹微通道流动和传热特性的影响,设计了5种不同缩扩比的半波纹微通道模型,并对各通道内的层流流动(200＜Re＜1000,Re为雷诺数)和传热进行了数值模拟研究。结果表明,半波纹微通道的压降和努塞尔数随着流道缩扩比的减小而增大;与光滑微通道相比,半波纹微通道具有更优的传热性能但压降损失也更高;引入η作为综合性能指标,发现减小流道缩扩比是提高半波纹微通道综合换热能力的有效方式,且当Re＞490时,其综合换热能力均优于光滑微通道。     

基于自注意力机制和CycleGAN的高分三号ScanSAR图像的扇贝效应抑制

高分三号卫星是我国首颗分辨率达到1 m的C波段 多极化合成孔径雷达(synthetic aperture radar,SAR) 卫星,其中扫描 式合成孔径雷达(scan synthetic aperture radar,ScanSAR)模式是高分三号卫星重要的工 作模式之一,由于该模式的工作机制导致生成的图像可能发生扇贝效应,一般呈现为明暗相 间的条纹。本文针对高分三号卫星ScanSAR模式下存在的扇贝效应,提出自注意力机制与循 环一致对抗网络(cycle-consistent adversarial networks,CycleGAN)结合的模型对Scan S AR图像进行处理,从而抑制扇贝效应产生的条纹现象。本文所示方法与传统扇贝效应抑制方 法和深度学习相关算法进行比较,并通过亮度均值、平均梯度等指标进行分析。实验结果表 明,本文方法可以对高分三号ScanSAR图像存在的扇贝效应进行较好的处理,有效抑制图像 的条纹现象,使得图像质量得到提升,具有较大的实用意义。     

基于多域特征融合的旋翼无人机分类识别

为提高雷达旋翼无人机的识别效果,本文提出一种基于多域特征融合的旋翼无人机分类方法。首先利用K波段连续波（Continuous Wave,CW）雷达观测多旋翼无人机,对采集到的雷达回波信号进行信号处理依次得到时频图、节奏速度图（Cadence?Velocity Diagram, CVD）和节奏频谱图（Cadence Frequency Spectrum,CFS）,然后将时频图和CVD图分别输入SqueezeNet网络,CFS数据输入一维卷积神经网络（1?D?CNN）提取回波信号在时频域、节奏速度域和节奏频率域的特征,最后将特征融合输入支持向量机（Support Vector Machine, SVM）进行分类。实测雷达数据处理的结果表明基于多域特征融合的旋翼无人机分类识别方法对三类旋翼无人机的分类准确率达到99.14%。     

A Visible and Near-Infrared Light-Fueled Omnidirectional Twist-Bend Crawling Robot

In recent years, although light-driven soft actuators have attracted intense scientific attention and achieved remarkable progress, the design and construction of an intelligent robotic system with maneuverability, self-adaptability, untethered control, and greater freedom of action, in particular the omnidirectional motion capability on a plane, remains challenging. Herein, four types of photo-thermal fillers and an unprecedented twist-bend actuation mode is introduced into a liquid crystal elastomer-based soft robot. The obtained twist-bend crawling robot not only exhibits in situ rotation, four-way turning, and four-way linear motion under light irradiation with four wavelength bands (520, 655, 808, and 980 nm), but also demonstrates the ability to avoid obstacles in complex geographical environments. This work may bring a new perspective for fabrication and development of soft robots that can adapt to dynamic and complex environmental conditions.     

一种宽带注入锁定三倍频器

文章提出了一种宽带注入锁定三倍频器。在传统注入方式基础上,倍频器采用了推-推差分对输入信号进行二倍频,并将产生的二次谐波通过变压器耦合至注入管的源极共模点,增强了注入管源极共模点二次谐波。由于注入电流是由注入信号与源极共模点二次谐波进行混频而产生,因此注入电流也被增强,从而增大了锁定范围。除此之外,三倍频采用了四阶谐振器,谐振阻抗的相位在过零点被平坦化,锁定范围进一步被增大。采用标准CMOS 65 nm工艺设计三倍频,芯片面积为720×670 μm²,1.2-V供电时的功耗为15.2 mW。0 dBm注入功率下三倍频的锁定范围为19.2~27.6 GHz,对应的基波抑制比大于25 dB,二次谐波抑制大于35 dB。注入锁定三倍频器可满足5G收发机中本振源的要求。