低电平扫描电流高强辐射场试验方法研究

低电平扫描电流试验(LLSC)是飞机高强辐射场(HIRF)试验的一部分,其实质是在2~400 MHz 频段 内对飞机进行电磁辐照,以确定外部HIRF 环境与设备线束感应电流之间的传递函数。基于RTCA/ DO-160G 和SAE ARP5583A 标准建立HIRF 测试环境,通过对AC312E 直升机开展低电平扫描电流试验,得到了线束传递函数随频 率、天线极化方式、电磁辐照方向、线束布置的变化规律并分析了其影响机理。结果表明:发射天线以不同极化方式 辐照机体时,不同布置的线束其传递函数有一定差别;发射天线以垂直极化在0°方向辐照时,行李舱附近右发动机 控制单元(EECUR)线束的传递函数比位于驾驶舱的座舱显示器(MFD)线束的传递函数要小;发射天线以垂直极化 方式在不同方向辐照机体时,EECUR 线束在某些频段下在右侧90°方向辐照比左侧270°方向辐照的传递函数要大。 所得结论可为直升机适航符合性验证和低电平扫描电流试验的开展提供参考与支撑。     

声透镜指向性换能器研究

该文利用声学透镜使声波能量聚焦,实现小尺寸换能器窄波束声辐射。利用有限元方法分别建立了单凹面声透镜及双凹面声透镜仿真模型,优化了声透镜结构参数,设计并制作了双凹面声透镜指向性换能器,并在消声水池内对换能器样机和声透镜进行了性能测试。换能器样机辐射面积直径?120 mm,设置声透镜后,提高发送电压响应级4 dB,发射指向性-3 dB波束开角由76°变为约30°(@10 kHz),与仿真计算结果相符。实验结果表明,声透镜有效减小了换能器发射波束宽度,提高了换能器主瓣发送电压响应,验证了双凹面声透镜对优化换能器指向性的效果。     

基于光子多普勒测速的长景深动态测试研究

目前光子多普勒测速的应用场景多为瞬时、短时的冲击、震动、飞片等测量,采集时间少、景深距离短,缺少长景深动态测试的应用。为此我们搭建了一套全光纤结构PDV以及基于LabWindows的上位机解调软件,以15 kHz线宽1550.12 nm激光器为光源,300 mm工作距离非球面镜作为探头,针对运动距离为1.33 m、最高速度14 m/s的无杆气缸滑块进行速度测量。通过多次实验,得出了无杆气缸滑块运动的全程速度曲线,并用积分反推出运动距离与实际滑块运动距离相符,平均相对误差为-0.5266%。实验结果表明,光子多普勒测速系统健壮性良好,在信号光耦合功率低的情况下仍可以得到16 dB以上信噪比的干涉信号,大气环境稳定时可在长景深范围内进行动态测量。     

铟锡氧化物纳米网的微波法制备及其光催化特性研究

By using ultrasonic and chemical liquid coprecipitation, the precursor was prepared with high purity In, SnCl₄·5H₂O and urea. The In₂O₃·SnO₂ nanonets were obtained from precursor by heating in microwave oven. The powders were characterized by XRD, TEM. The analyzed results show the sample is In₂O₃·SnO₂, and In₂O₃is rhombohedral system while SnO₂ is tetragonal system. The sample is in spherical grain shape, with average granularity of 35 nm, and the mesh diameter of 10～80 nm. The sample was with fluorescence and good photocatalytic performance for degradation of organic dyestuff.     

次甲基硅SiH与H2X(X=O,S)反应的热力学及动力学性质研究

在量子化学对SiH与H₂O和H₂S反应计算的基础上,运用统计热力学和Wigner校正的Eyring过渡态理论,计算了上述两反应在200～2000 K温度范围内的热力学函数、平衡常数、频率因子A和速率常数随温度的变化。计算结果表明,两反应在低温下具有热力学优势,而在高温下具有动力学优势。比较两反应的计算结果发现,在相同的温度下,SiH与H₂O反应比SiH与H₂S反应放热较多,但速率常数却较小。SiH与H₂O反应和前文报道的SiH与HF反应的比较表明,SiH与H₂O反应放热较少,而且在相同温度下,速率常数也较小。     

Fingerprint quality control of Tianjihuang by high-performance liquid chromatography-photodiode array detection

A novel, simple and accurate fingerprint method was developed using high-performance liquid chromatography-photodiode array detection (HPLC-DAD) for the quality control of Hypericum japonicum thunb (Tianjihuang), a Chinese herbal medicine used for the treatment of several bacterial diseases, infectious hepatitis, gastrointestinal disorder, internal hemorrhage and tumors. For the first time, the feasibility and advantages of employing chromatographic fingerprint were investigated and demonstrated for the evaluation of Tianjihuang by systematically comparing chromatograms with a professional analytical software recommended by State Food and Drug Administration (SFDA). Our results revealed that the chromatographic fingerprint combining similarity evaluation could efficiently identify and distinguish raw herbs of Tianjihuang from different sources. The effects resulted from collecting locations, harvesting time and storage time on herbal chromatographic fingerprints were also examined.     

Synthesis,structure, and thermal decomposition of a novel one-dimensional chain complex of manganese(II) with 2,2-diphenic acid and 1,10-phenanthroline

A novel one-dimensional (1D) chain coordination polymer [Mn₂(2,2′-dipha)₂(phen)]_n has been synthesized by hydrothermal reaction, and characterized by elemental analysis, IR spectroscopy, TGA, and X-ray diffraction. Orange crystals crystallized in the monoclinic system, space group C2/c with a = 19.393(7) Å, b = 19.183(7) Å, c = 19.729(7) Å, β = 90.826(6)°, V = 7338(5) ų, Z = 8. In the crystal structure, one manganese atom is six-coordinated with four carboxylate oxygen atoms from one pentadentate 2,2′-dipha ligand and two tetradentate 2,2′-dipha ligands, and with two nitrogen atoms of one phen ligand, giving a slightly distorted octahedral geometry. The other manganese atom is five-coordinated with five oxygen atoms from two tetradentate 2,2′-dipha ligands and two pentadentate 2,2′-dipha ligands and has a trigonal bipyramidal environment. The TGA curve shows that the compound is stable below 310°.     

西松烷型二萜内酯的全合成进展

按照内酯环的大小综述了西松烷二萜的合成方法。     

新型杀菌剂氟吗啉在黄瓜植株体内的吸收传导行为

利用生物测定技术和高效液相色谱法研究了氟吗啉在黄瓜植株体内的吸收、传导和分布行为及其机制. 结果表明, 氟吗啉能被黄瓜植株被动吸收, 并通过木质部在体内传导和分布.     

分光光度法测定脱氧核糖核酸——基于其与亚甲蓝的反应

试验发现在pH 6.5的B-R缓冲溶液中在加脱氧核糖核酸(DNA)后亚甲蓝溶液在其吸收峰666 nm波长处的吸收明显减弱(即色泽减褪),而且吸光度的减弱(ΔA)程度与DNA的质量浓度在10.0 mg.L-1以内保持线性关系,其相关系数为0.9998,此反应对DNA的检出限为0.10 mg.L-1,分别以蛋白酶、胰蛋白酶及溶菌酶作为基体定量加入DNA配制成3种合成样品,按所提出方法进行分析,测得回收率结果在98.4%~101.0%之间,分析结果的RSD(n=11)值在1.1%~3.1%之间。对反应条件(包括亚甲蓝的浓度、反应的温度、酸度及时间等因素)作了试验和选定,还对反应机理作了简要的讨论。