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A stable nonlinear optical (NLO) film containing “T” type alkoxysilane dye was prepared by sol–gel technology. This crosslinked “T” type alkoxysilane dye was synthesized and fully characterized by FTIR, UV–Vis spectra, and 1H‐NMR. Followed by hydrolysis and copolymerization processes of the alkoxysilane with γ‐glycidoxypropyl trimethoxysilane (KH560) and tetraethoxysilane (TEOS), high quality inorganic–organic hybrid second‐order NLO films were obtained by spin coating. The “T” type structure of the alkoxysilane was found to be effective for improving the temporal stability of the optical nonlinearity due to the reduction in the relaxation of the chromophore in the film materials. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
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One‐pot Synthesis of CdS Nanocrystals Hybridized with Single‐Layer Transition‐Metal Dichalcogenide Nanosheets for Efficient Photocatalytic Hydrogen Evolution
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Junze Chen Dr. Xue‐Jun Wu Lisha Yin Dr. Bing Li Dr. Xun Hong Zhanxi Fan Bo Chen Prof. Can Xue Prof. Hua Zhang 《Angewandte Chemie (International ed. in English)》2015,54(4):1210-1214
Exploration of low‐cost and earth‐abundant photocatalysts for highly efficient solar photocatalytic water splitting is of great importance. Although transition‐metal dichalcogenides (TMDs) showed outstanding performance as co‐catalysts for the hydrogen evolution reaction (HER), designing TMD‐hybridized photocatalysts with abundant active sites for the HER still remains challenge. Here, a facile one‐pot wet‐chemical method is developed to prepare MS2–CdS (M=W or Mo) nanohybrids. Surprisedly, in the obtained nanohybrids, single‐layer MS2 nanosheets with lateral size of 4–10 nm selectively grow on the Cd‐rich (0001) surface of wurtzite CdS nanocrystals. These MS2–CdS nanohybrids possess a large number of edge sites in the MS2 layers, which are active sites for the HER. The photocatalytic performances of WS2–CdS and MoS2–CdS nanohybrids towards the HER under visible light irradiation (>420 nm) are about 16 and 12 times that of pure CdS, respectively. Importantly, the MS2–CdS nanohybrids showed enhanced stability after a long‐time test (16 h), and 70 % of catalytic activity still remained. 相似文献
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研究源自于MapReduce系统的一类排序问题。给定两台恒速机和一组按列表到达的工件,每个工件包含两类任务:Map Task和Reduce Task。假设Map任务和Reduce任务都是不可中断的,Map任务可以并行处理,即可以任意分割成若干小的任务并在两台机器上同时处理,而Reduce任务只可以在单台机器上处理。一旦工件到达,必须为其指派机器和开工时间,目标是使得最后完工时间最小。对LSc算法的竞争比进行了分析,得到其一般情形下的竞争比当$s\geq(1+\sqrt{5})/2$时为$1+1/s$,否则为$1+s/(s+1)$。而当每个工件$J_j$都满足其Map任务总长大于等于Reduce任务总长时,其竞争比当$s\geq(1+\sqrt{3})/2$时不超过$1+1/(2s)$,否则为不超过$1+s/(2s+1)$。 相似文献
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本文主要介绍了开放式投资基金的流动性概念和指标体系设计,并运用指标进行实证检验,分析基金的流动性及其实际意义。 相似文献
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铜合金中金相组织特征参数的测量 总被引:2,自引:0,他引:2
:根据体视学和定量金相分析的基本原理,利用Image—Pro Plus(IPP)图像分析软件测定了铜合金金相组织的相体积分数、晶粒度大小、粒子间距等特征参数,并提出了一种测量粒子间距的近似算法。 相似文献
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Penghao Yang Xia Gao Lisha Wang Qi Wu Zhichun Chen Xianfu Lin 《Mikrochimica acta》2014,181(1-2):231-238
We report on an amperometric sensor for ascorbic acid (AA) that is based on highly dense gold-silver nanotubes in a chitosan film on a glassy carbon electrode. The nanotubes were synthesized by a poly(vinyl pyrrolidone)-mediated polyol method employing a replacement reaction with silver nanowires as templates, and were characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction. Under the optimal conditions, the sensor exhibits good electrocatalytic activity towards the oxidation of AA, and this enables the determination of AA in the 5 μM to 2 mM concentration range, with a detection limit at 2 μM (at an S/N of 3). The response time is 2 s. The sensor displays good reproducibility, selectivity, sensitivity, and long-term stability. Figure
In this paper, an amperometric electrochemical sensor for detection of ascorbic acid was fabricated based on highly dense gold-silver nanotubes and chitosan film. The biosensor showed good reproducibility, anti-interferant ability, high sensitivity, low detection limit, fast response, and long-term stability. 相似文献
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A new supplier price break and discount scheme taking into account order frequency and lead time is introduced and incorporated into an integrated inventory planning model for a serial supply chain that minimizes the overall incurred cost including procurement, inventory holding, production, and transportation. A mixed-integer linear programming (MILP) formulation is presented addressing this multi-period, multi-supplier, and multi-stage problem with predetermined time-varying demand for the case of a single product. Then, the length of the time period is considered as a variable. A new MILP formulation is derived when each period of the model is split into multiple sub-periods, and under certain conditions, it is proved that the optimal solution and objective value of the original model form a feasible solution and an upper bound for the derived model. In a numerical example, three scenarios of the derived model are solved where the number of sub-period is set to 2, 3, and 4. The results further show the decrease of the optimal objective value as the length of the time period is shortened. Sufficient evidence demonstrates that the length of the time period has a significant influence on supplier selection, lot sizing allocation, and inventory planning decisions. This poses the necessity of the selection of appropriate length of a time period, considering the trade-off between model complexity and cost savings. 相似文献