铜合金中金相组织特征参数的测量

：根据体视学和定量金相分析的基本原理，利用Image—Pro Plus(IPP)图像分析软件测定了铜合金金相组织的相体积分数、晶粒度大小、粒子间距等特征参数，并提出了一种测量粒子间距的近似算法。     

五子棋中的博弈智能设计

博彝是人工智能的主要研究领域之一，他涉及人工智能中的推理技术、搜索方法和决策规划。本文将这些技术用于五子棋中．设计了一个智能五子棋系统，实现人和计算机两方进行博弈。     

Study on Combined Method Based on 3-D ESPI

The finite element method (FEM),whether the calculation is accurate or not,depends closely on object boundary condition.If the three dimensional displacement of the object obtained in experiment is regarded as its boundary condition,a new method combining the results of experiment and calculation,called combined method (CM),is formed.The combined method possess advantages of experiment and calculation.It can correct calculation and improve the accuracy of FEM.Accordingly it has more practicability.In this paper,the three dimensional displacement fields of a typical beam loaded at three points are tested by using 3-D electric speckle pattern interferometry (ESPI).Using the experimental results as boundary condition the whole three-dimensional displacement fields can be calculated by FEM.The beam′s three-dimensional displacement fields obtained by FEM agree very well with those obtained by experiment.This proves that the combined method is effective and practicable.     

具有不同耦合强度且带有时滞的振子网络上的同步

本文研究了具有不同耦合强度且带有时滞的振子网络上的同步问题．我们给出了该网络同步状态的稳定性准则，证实了其同步状态的稳定性与网络的拓扑性无关．最后，通过数值模拟验证了我们的理论结果．     

Graphitic‐Carbon Layers on Oxides: Toward Stable Heterogeneous Catalysts for Biomass Conversion Reactions

Conversion of biomass‐derived molecules involves catalytic reactions under harsh conditions in the liquid phase (e.g., temperatures of 250 °C and possibly under either acidic or basic conditions). Conventional oxide‐supported catalysts undergo pore structure collapse and surface area reduction leading to deactivation under these conditions. Here we demonstrate an approach to deposit graphitic carbon to protect the oxide surface. The heterogeneous catalysts supported on the graphitic carbon/oxide composite exhibit excellent stability (even under acidic conditions) for biomass conversion reactions.     

Chain‐Growth Click Polymerization of AB2 Monomers for the Formation of Hyperbranched Polymers with Low Polydispersities in a One‐Pot Process

Hyperbranched polymers are important soft nanomaterials but robust synthetic methods with which the polymer structures can be easily controlled have rarely been reported. For the first time, we present a one‐pot one‐batch synthesis of polytriazole‐based hyperbranched polymers with both low polydispersity and a high degree of branching (DB) using a copper‐catalyzed azide–alkyne cycloaddition (CuAAC) polymerization. The use of a trifunctional AB₂ monomer that contains one alkyne and two azide groups ensures that all Cu catalysts are bound to polytriazole polymers at low monomer conversion. Subsequent CuAAC polymerization displayed the features of a “living” chain‐growth mechanism with a linear increase in molecular weight with conversion and clean chain extension for repeated monomer additions. Furthermore, the triazole group in a linear (L) monomer unit complexed Cu^I, which catalyzed a faster reaction of the second azide group to quickly convert the L unit into a dendritic unit, producing hyperbranched polymers with DB=0.83.     

Regio‐ and Enantioselective Aza‐Diels–Alder Reactions of 3‐Vinylindoles: A Concise Synthesis of the Antimalarial Spiroindolone NITD609

An asymmetric aza‐Diels–Alder reaction of 3‐vinylindoles with isatin‐derived ketimines has been developed. A series of spiroindolone derivatives were thus obtained in good to excellent yields with excellent enantioselectivity (up to 96 % yield and 99 % ee). Furthermore, the antimalarial compound NITD609 could be obtained in three steps with an overall yield of 40.6 %. Control experiments and operando IR experiments imply a concerted reaction pathway. The regioselectivity and exo selectivity result from π–π interactions between the two indoline rings of the two reactants.     

A Highly cis‐Selective and Enantioselective Metal‐Free Hydrogenation of 2,3‐Disubstituted Quinoxalines

A wide range of 2,3‐disubstituted quinoxalines have been successfully hydrogenated with H₂ using borane catalysts to produce the desired tetrahydroquinoxalines in 80–99 % yields with excellent cis selectivity. Significantly, the asymmetric reaction employing chiral borane catalysts generated by the in situ hydroboration of chiral dienes with HB(C₆F₅)₂ under mild reaction conditions has also been achieved with up to 96 % ee, and represents the first catalytic asymmetric system to furnish optically active cis‐2,3‐disubstituted 1,2,3,4‐tetrahydroquinoxalines.