基于高光谱激光雷达的滞尘叶片光谱特征分析

城市绿植为城市生态系统提供自净功能, 起到净化空气以及滞尘降尘等多种环境保护作用, 而滞尘等因素也 会对绿植产生影响。为了研究滞尘对城市绿植叶片光谱特征的影响, 采集了四种常绿绿植 (八角金盘、石楠、香樟和 玉兰) 叶片样本, 使用高光谱激光雷达系统获取高光谱点云数据, 分析了滞尘对叶片光谱特征的影响。分析结果表明: 对于不同种类叶片, 滞尘对可见光波段反射率均有较大影响; 对于同种类叶片, 滞尘对近红外波段的反射率差异影响 较大, 可见光波段的反射率差异为 1.21%∼3.41%, 近红外为 1.76%∼8.49%; 线性四点内插法计算和光谱导数分析表明 滞尘对四种叶片的红边位置无显著影响; 四种叶片的叶面水含量指数 (LWI) 对滞尘的响应程度最小 (均小于 3.7%), 而 比值植被指数 (RVI) 对滞尘的响应程度最大 (除香樟外, 均大于 20.0%), 红边指数 (SDr)、简单比值指数 (SR) 和叶面叶 绿素指数 (LCI) 的响应程度稳定性较差。进一步建立了滞尘植被指数和响应程度的线性相关性拟合模型并进行了检 验, 其中以 LCI 为自变量建立的模型为最稳定拟合模型, 可表示为 y = −1.527x + 0.6597, 决定系数约为 0.88。     

基于相对生成对抗网络的低清小脸幻构

针对当前代表性低清小脸幻构方法存在的视觉真实感弱、网络结构复杂等问题,提出了一种基于相对生成对抗网络的低清小脸幻构方法(tfh-RGAN).该文方法的网络架构包括幻构生成器和判别器两个部分,通过像素损失函数和相对生成对抗损失函数的联合最小化,实现生成器和判别器的交替迭代训练.其中,幻构生成器结合了残差块、稠密块以及深度可分离卷积算子,保证幻构效果和网络深度的同时降低生成器的参数量;判别器采用图像分类问题中的全卷积网络,通过先后去除批归一化层、添加全连接层,充分挖掘相对生成对抗网络在低清小脸幻构问题上的能力极限.实验结果表明,在不额外显式引入任何人脸结构先验的条件下,该文方法能够以更简练的网络架构输出清晰度更高、真实感更强的幻构人脸.从定量角度看,该文方法的峰值信噪比相较之前的若干代表性方法可提高0.25～1.51 dB.     

聚合物固体电解质基体的研究进展

综述了聚合物固体电解质基体的设计原理、分类和研究进展，并对今后在聚合物基体设计方面的研究前景作了展望。     

CuO/TiO2的制备及对NO＋CO反应性能的研究

以三种不同的TiO2为载体，负载6%CuO，在色谱-微反装置上考察了三种Cu6-Ti催化剂对NO＋CO反应的活性。结果表明，由于制备方法不同，活性差别很大，三者活性顺序依次为：Cu6-Ti(T)> Cu6-Ti(S)> Cu6-Ti(nm)，TiO2的比表面积及晶型对活性的影响不明显。H2-TPR结果表明，Cu6-Ti在整个TPR过程中出现了3或4个还原峰，表明有多种CuO物种存在。不同预处理Cu6-Ti的TPR显示，在反应中Cu物种可能以多种价态同时存在。NO-TPD结果亦证明，Cu6-Ti对NO＋CO的反应活性与NO在催化剂表面的解离难易密切相关，而与NO的吸附量关系不大。     

Synthesis and Structure of 〔Cu(μ-C_6H_5COO)_2(C_4H_8O)〕_2

1mTRODUCT1ONBinuclearcoppercomplexesareimportantnotonlyincoordinationchemistryandmagnetostructuralstudiesbutalsoinpracticalapplication.tliInanattempttoseekthedisPersionandemulationreagentsofCWM(themixtureofcoalandwater),thetitlecomP0undwassynthesizedbyanoxidativepreparationmethodt2i,whosesynthesisandstructurearedifferentfromthosedescribedbyWangetoft3i.Here,0nlythesynthesisandstructureofthetitlecomP0undarereportedandthestudiesofitsappli-cationareinprogress.2EXPERIMENTAL2.1Preparati0n…     

Preparation of Co3O4 Nanofibers via an Electrospinning Technique

Thin PVA/cobalt acetate composite fibers were prepared by using sol-gel processing and electrospinning technique.After calcination of the above precursor fibers,Co3O4 nanofibers with a diameter of 50-150 nm could be successfully obtained.The fibers were characterized by SEM,FT-IR,WAXD,respectively.     

Zr柱撑蒙脱土上负载稀土铈及铜铈催化剂的制备与表征

The Zr-pillaraed montmorillonite supported Ce and Cu-Ce catalysts were prepared by impregnation method. The performance of the catalysts was evaluated via the catalytic oxidation of volatile organic compounds (acetone, ethyl acetate, and toluene). The results showed that after supporting with Ce and Cu-Ce, the catalysts had a better reducibility. Moreover, the surface areas of the samples were increased. In addition，it was found that the Zr-pillared montmorillonite supported Cu-Ce catalysts had a higher activity and the reaction temperature decreased by 150～200 ℃ compared with the sample without Cu-Ce modification.     

Design and Synthesis of Glycosylated Aromatic Nitrogen Mustard Derivatives

Antibody-directed enzyme prodrug therapy(ADEPT) is a new strategy for the treatment of cancer that has arisen in recent twenty years, the main merits of which are that it can improve the selectivity of anticancer drugs and reduce the side effects in remote tissue. In the present study, two prodrugs-glycosylated aromatic nitrogen mustard derivatives were synthesized. Glucose and lactose were converted into glycosyl donors-trichloroacetimidate; the obtained glycosyl donors were glycosylated with p-nitrophenol(glycosyl donors) to form β-glucosyl p-nitrobenzene and β-lactosyl p-nitrobenzene that were protected by acetyl in a stereoselective manner; the two products were reduced by zinc dust and then treated with ethylene oxide, afforded two glycosylated nitrogen mustard derivatives that were protected by acetyl; the last step was to deacetylate and then afforded the two target compounds that could be used as prodrugs of ADEPT for further Anti-tumor research.     

对氟苯甲醛水杨酰腙镍(II)配合物的合成、表征及其晶体结构

A nickel(II) complex Ni(C₁₄H₁₀N₂O₂F)₂ was synthesized from p-fluorobenzaldehyde salicylhydrazone and Ni(CH₃COO)₂·4H₂O and crystallized by diffusion, the structure of which was characterized by IR spectrum, ¹H NMR, and X-ray single-crystal diffraction. The complex crystallizes in monoclinic space group C2/c with a=2.460 6(2) nm, b=0.774 1(1) nm, c=1.534 9(1) nm, β=122.300(1)°, and V=2.471 1(4), Z=8, D_c=1.541 g·cm^-3. We reported the IR, ¹H NMR, crystal structure. CCDC: 638652.