A test of a model t-matrix for direct reaction inelastic scattering

Differential cross sections and analyzing powers from the inelastic scattering of 65 MeV protons leading to the 1⁺T=0 (12.71 MeV) and 1⁺T = 1 (15.11 MeV) states in ¹²C have been analysed as tests of a model two-nucleon t-matrix.     

An efficient one—dimensional search procedure for barrier functions

In minimizing interior penalty functions, most of the computational time is spent on the one-dimensional search. This paper presents a method for performing this search on barrier functions which is significantly faster than current techniques. The method exploits the special structure of barrier functions. Comparative computational results are given for a set of six test problems.This research was partially supported by the National Aeronautics and Space Administration under Research Grant NSG 110-61 and by the Office of Naval Research under Grant No. N00014-67-A-0404-0010.     

Abiotic metallofoldamers as electrochemically responsive molecules

Described are the design, synthesis, and study of nonbiological molecules based on salophen and salen ligands that fold into single-stranded helices in the presence of either Ni(II) or Cu(II). X-ray diffraction studies show that the materials fold into helical structures in the solid state, and a series of NMR studies provide strong evidence that the folded structures are conserved in solution. Metal coordination is required for folding, as NMR and X-ray show that the free ligands do not adopt helical structures. Two of the racemic metallofoldamers spontaneously resolve during crystallization from CHCl3/acetonitrile, and CD spectroscopy and optical rotation show that the resolved, crystalline materials racemize quickly when dissolved at 5 degrees C. This shows that the secondary structures can reorganize easily and can, therefore, provide the basis for responsive materials. By comparison, an analogue from enantiomerically pure (R,R)-(-)-trans-cyclohexanediamine showed a strong CD signal and a large specific rotation. Electrochemical experiments show that a structural reorganization occurs upon metal-centered reduction of a Cu(II)-containing foldamer. When the reduction is carried out in the presence of coordinating ligands, it is proposed that apical binding of those ligands gives square pyramidal complexes. Semiempirical (AM1) calculations support that the helical structure would be disrupted by the reduction to Cu(I) with concomitant reorganization to a square pyramidal complex.     

Rat lymphocytes in cell culture exposed to 2450 MHz (CW) microwave radiation.

Rat lymphocytes were exposed to continuous wave microwave radiation at a frequency of 2450 MHz at intensities of 5, 10 and 20 mW/cm2. The corresponding rates of absorption of energy were determined to be 0.7, 1.4 and 2.8 mW/g. The lymphocytes were exposed for 4, 24 or 44 h either with or without the addition of a mitogen (phytohemagglutinin). The transformation of lymphocytes into lyphoblasts was monitored by the addition of tritiated thymidine. No significant differences (P less than .05) were found in the uptake of tritiated thymidine between exposed and control cultures.