全文获取类型
收费全文 | 525篇 |
免费 | 20篇 |
国内免费 | 1篇 |
专业分类
化学 | 232篇 |
晶体学 | 1篇 |
力学 | 79篇 |
数学 | 115篇 |
物理学 | 94篇 |
无线电 | 25篇 |
出版年
2022年 | 10篇 |
2021年 | 11篇 |
2020年 | 10篇 |
2019年 | 10篇 |
2018年 | 15篇 |
2017年 | 11篇 |
2016年 | 26篇 |
2015年 | 21篇 |
2014年 | 24篇 |
2013年 | 24篇 |
2012年 | 22篇 |
2011年 | 25篇 |
2010年 | 21篇 |
2009年 | 19篇 |
2008年 | 24篇 |
2007年 | 20篇 |
2006年 | 13篇 |
2005年 | 12篇 |
2004年 | 17篇 |
2003年 | 14篇 |
2002年 | 11篇 |
2001年 | 9篇 |
2000年 | 7篇 |
1999年 | 8篇 |
1997年 | 10篇 |
1996年 | 7篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 12篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 7篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1986年 | 8篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1980年 | 7篇 |
1979年 | 4篇 |
1977年 | 7篇 |
1975年 | 6篇 |
1974年 | 8篇 |
1973年 | 7篇 |
1970年 | 3篇 |
1969年 | 3篇 |
1968年 | 6篇 |
排序方式: 共有546条查询结果,搜索用时 54 毫秒
21.
22.
23.
24.
Oleg Tkachenko Abdur Rahim Andrey Baraban Ruslan Sukhov Inna Khristenko Yoshitaka Gushikem Yuriy Kholin 《Journal of Sol-Gel Science and Technology》2013,66(1):145-154
A sol–gel based hybrid process was developed by manipulating different techniques in sol–gel process to synthesize γ-alumina and (CuO, CuO + ZnO) doped γ-alumina spherical particles. Catalysts having spherical geometry have an important advantage over powders or pellets which are impervious to fluids, when packed in a reactor. Boehmite sol was used as alumina precursor for synthesizing porous γ-alumina and doped materials. γ-alumina particles having 5 wt% CuO, 4 wt% CuO + 1 wt% ZnO, 3 wt% CuO + 2 wt% ZnO and 2 wt% CuO + 3 wt% ZnO were prepared by adding required amounts of Cu(NO3)2 and Zn(NO3)2 solutions prior to gelation of the sol. Methanol dehydration studies were carried out by employing these synthesized catalysts. Hundred percent conversion of methanol to dimethyl ether was observed with (4 wt% CuO + 1 wt% ZnO)-γ-alumina and (5 wt% CuO)-γ-alumina microspheres at 325 and 350 °C, respectively. 相似文献
25.
Victor P. Arkhipov Ruslan V. Arkhipov Andrei Filippov 《Magnetic resonance in chemistry : MRC》2022,60(3):359-368
We examined a series of amino acid-based surfactants with two carboxylic groups separated by a spacer of one, two, or three carbon atoms with sodium and calcium counterions in the premicellar concentration region near the CMC. 1H nuclear magnetic resonance (NMR) spectroscopy and NMR diffusometry techniques were used to study the local environment, association, and translational dynamics of the surfactant's molecules. We measured the self-diffusion coefficients of the micelles, calculated the effective hydrodynamic radii, and determined the temperature region in which the premicelles exist. With an increase in temperature from 295 to 335 K, the premicellar state of the surfactant is replaced by the monomeric state. 相似文献
26.
M. Yu. Artyushenko A. A. Baldin A. I. Berlev O. V. Bukhal V. A. Voronko K. V. Gusak I. V. Zhuk I. V. Kudashkin M. Paraipan A. S. Potapenko A. A. Safronova V. V. Sotnikov S. I. Tyutyunnikov 《Physics of Particles and Nuclei Letters》2016,13(4):466-470
The cross sections for the spallation of the heavy-metal nuclei 181Ta, 197Au, 207Pb, 209Bi, 232Th, and 238U induced by relativistic deuterons with energies of 2, 2.94, and 3.5 GeV per nucleon are measured using the deuteron beam from the Nuclotron accelerator of the JINR Laboratory of High Energy Physics in Dubna, Russia. The cross-section measurements employ a combined experimental technique involving the solidstate nuclear-track detectors and the activation gamma spectrometry. Adding our measurements to the database of experimental nuclear data will make it possible to test the computer codes used for selecting the parameters of the ADS-type facilities. 相似文献
27.
Reversible phase transitions of bismuth niobate Bi3NbO7 have been observed: from the lowtemperature cubic modification to the tetragonal one at 860°C and from the tetragonal modification to the hightemperature cubic one at 950–980°C. With increasing temperature of the cubic modification preparation, the unit cell parameter has been decreasing. Electrophysical properties of the cubic phases have matched at the frequencies below 1 kHz (up to 650 K). The specific conductivity of the tetragonal phase exceeds that of the cubic phase by no more than an order of magnitude (below 1000 K). 相似文献
28.
Dmitriy V. Steglenko Nikolay V. Tkachenko Alexander I. Boldyrev Ruslan M. Minyaev Vladimir I. Minkin 《Journal of computational chemistry》2020,41(15):1456-1463
The structure and properties of two-dimensional phosphoborane sheets were computationally investigated using Density Functional Theory calculations. The calculated phonon spectrum and band structure point to dynamic stability and allowed characterization of the predicted two-dimensional material as a direct-gap semiconductor with a band gap of ~1.5 eV. The calculation of the optical properties showed that the two-dimensional material has a relatively small absorptivity coefficient. The parameters of the mechanical properties characterize the two-dimensional phosphoborane as a relatively soft material, similar to the monolayer of MoS2. Assessment of thermal stability by the method of molecular dynamics indicates sufficient stability of the predicted material, which makes it possible to observe it experimentally. 相似文献
29.
Ruslan I. Vaskevych Alla I. Vaskevych Eduard B. Rusanov Oksana Ya. Mel'nyk Mykhailo V. Vovk 《Journal of heterocyclic chemistry》2020,57(8):3202-3212
Selective iodocyclization of 6-(alkenylamino)-1-allylpyrazolo[3,4-d]pyrimidines provided hydrogenated derivatives of 1-allyl-8(9)-iodomethylimidazo(pyrimido)[1,2-a]pyrazolo[4,3-e]pyrimidines which were further reacted with NaN3 at 75°С to 80°С to give a series of new-type 1,3,6-triazocines annulated with the pyrazole, pyrimidine, imidazole (or pyrimidine), and 1,2,3-triazole rings. The compounds synthesized were structurally characterized by analytical, spectral (IR, 1H and 13C NMR, HPLC-mass), and X-ray diffraction data. 相似文献
30.
A. A. Berlin A. V. Zhuk N. N. Knunjantz V. G. Oshmjan V. A. Topolkaraev 《Macromolecular Symposia》1991,44(1):295-302
The effect of adhesion between matrix and filler on mechanical properties of composites is analyzed. It is shown, that the loss of adhesion (extension of exfoliated surface) leads to a marked reduction of uniaxial tension modulus. Regularities of interphase crack growth were found and dependences of initial (critical) and final angles of exfoliation upon mechanical and scale factors were obtained. 相似文献