Strong comparison result for a class of reflected stochastic differential equations with non-Lipschitzian coefficients

In this paper, we are concerned with a class of reflected stochastic differential equations (reflected SDEs) with non-Lipschitzian coefficients. Under the same coefficients assumptions as Fang and Zhang [Probab. Theory Relat. Fields, 2005, 132(3): 356–390] for a class of SDEs, we establish the pathwise uniqueness for the reflected SDEs. Furthermore, a strong comparison theorem is proved for the reflected SDEs in a one-dimensional case.      

Fast Estimation of Timing Yield Bounds for Process Variations

With aggressive scaling down of feature sizes in VLSI fabrication, process variation has become a critical issue in designs. We show that two necessary conditions for the ldquomaxrdquo operation are actually not satisfied in the moment matching based statistical timing analysis approaches. We propose two correlation-aware block-based statistical timing analysis approaches that keep these necessary conditions, and show that our approaches always achieve the lower bound and the upper bound on the timing yield. Our approach combining with moment-matching based statistical static timing analysis (SSTA) approaches can efficiently estimate the maximal possible errors of moment-matching-based SSTA approaches.     

一种判断城市协调发展的定量分析方法

本文从评价城市协调发展的目的出发，将城市划分为经济、社会和生态环境等三个组成部分．在定量分析城市系统结构的同时也提出了一种城市协调发展状态的判断方法。     

Stability of lithium hydride in argon and air

The oxidation behaviors of LiH under a high purity argon atmosphere, an argon atmosphere with some O2 and H2O impurities, and ambient air at both room and high temperatures, are investigated using a variety of analytical instruments including X-ray diffractometry, thermogravimetry, mass spectrometry, scanning electron microscopy, and specific surface area analysis. The oxidation behaviors of the ball-milled LiH under different atmospheres are also studied and compared with those without ball milling. It is shown that no oxidation of LiH occurs under a high-purity argon atmosphere. However, oxidation of LiH takes place when the argon atmosphere contains some H2O and O2 impurities. At temperatures higher than approximately 55 degrees C, oxidation of LiH proceeds via the reaction of LiH + 1/4 O2 = 1/2 Li2O + 1/2 H2, whereas at room temperature oxidation of LiH is likely caused by the simultaneous reactions of LiH + H2O = LiOH + H2 and LiH + 1/2 O2 = LiOH. The oxidation behavior of LiH in ambient air with a 27% relative humidity can be well described by the Johnson-Mehl-Avrami equation. Furthermore, the ball-milled LiH oxidizes faster than the unmilled one, which is due to the finer particle size and larger surface area of the ball-milled powder.     

一种可适应复杂互连电容结构的边界元形体处理方法

针对当前集成电路中日益复杂的互连结构,提出了一种边界元电容提取中的形体处理方法,可适用于填充气隙、保形介质、多平面介质,以及任意复杂的寄生电容结构.在该处理方法中采用多叉树组织三维形体对象,并有效地生成区域边界表面的信息.数值实验表明,该方法拓宽了边界元电容提取处理复杂结构的能力,且具有较高效率.     

Palladium(II)‐Initiated Catellani‐Type Reactions

The Catellani reaction is known as a powerful strategy for the expeditious synthesis of highly substituted arenes and benzo‐fused rings, which are usually difficult to access through traditional cross‐coupling strategies. It utilizes the synergistic interplay of palladium and norbornene catalysis to facilitate sequential ortho C?H functionalization and ipso termination of aryl halides in a single operation. In classical Catellani‐type reactions, aryl halides are mainly used as the substrates, and a Pd⁰ catalyst is required to initiate the reaction. Nevertheless, recent advances showcase that Catellani‐type reactions can also be initiated by a Pd^II catalyst with different starting materials instead of aryl halides via different reaction mechanisms and under different conditions. This emerging concept of Pd^II/norbornene cooperative catalysis has significantly advanced Catellani‐type reactions, thus enabling future developments of this field. In this Minireview, Pd^II‐initiated Catellani‐type reactions and their application in the synthesis of bioactive molecules are summarized.     

Fully Conjugated Two‐Dimensional sp2‐Carbon Covalent Organic Frameworks as Artificial Photosystem I with High Efficiency

The synthesis of fully conjugated sp²‐carbon covalent organic frameworks (COF) is extremely challenging given the difficulty of the formation of very stable carbon‐carbon double bonds (‐C=C‐). Here, we report the successful preparation of a 2D COF (TP‐COF) based on triazine as central planar units bridged by sp²‐carbon linkers through the ‐C=C‐ condensation reaction. High‐resolution‐transmission electron microscopy (HRTEM) clearly confirmed the tessellated hexagonal pore structure with a pore center‐to‐center distance of 2 nm. Powder X‐ray diffraction (PXRD) together with structural simulations revealed an AA stacking mode of the obtained layered structure. TP‐COF turned out to be an excellent semiconductor material with a LUMO energy of ?3.23 eV and a band gap of 2.36 eV. Excitingly, this novel sp²‐carbon conjugated TP‐COF exhibited unprecedented coenzyme regeneration efficiency and can significantly boost the coenzyme‐assisted synthesis of l ‐glutamate to a record‐breaking 97 % yield within 12 minutes.     

基于调制谱图卷积神经网络的空中目标识别技术

雷达对空中目标的分类识别技术是雷达信号处理领域中的关键技术.目前大部分雷达目标识别方法通用性较差且对雷达具有较高的要求.针对该问题,提出一种将目标回波的周期性调制谱信息图像化后,基于卷积神经网络调制谱图处理的空中目标识别方法.目标调制谱图像通过卷积神经网络逐层变换自动学习到目标特征信息,最终通过分类器进行分类识别.该方法避免了传统人工拟定调制谱特征的方式,实现了端对端的空中目标识别方法.实验结果表明,基于调制谱图的卷积神经网络模型具有较高的空中目标识别准确率,且模型的鲁棒性和泛化能力较好.     

Improved adsorption and desorption behavior of Cd on thiol-modified bentonite grafted with cysteamine hydrochloride

Clay adsorbents are considered an inexpensive and readily available solution for removing heavy metals, including cadmium, from the environment to reduce pollution. In this study, thiol-modified bentonite (SH-Bent) was prepared by grafting cysteamine hydrochloride onto natural bentonite (Bent). The effects of pH, equilibrium contact time, and temperature on the adsorption–desorption behavior of Cd²⁺ were studied, and adsorption isotherm models were applied to examine the adsorption behavior of SH-bent. SH-Bent demonstrated better performance and stability for Cd²⁺ adsorption than Bent. SH-Bent exhibited an enhanced adsorption capacity for Cd²⁺ at equilibrium of 49.3 mg/g at pH 6, 120 min, and 303 K, which was 42-fold higher than that of Bent under the same conditions. An investigation of the desorption behavior of Cd²⁺ adsorbed on Bent and SH-Bent in simulated acid rain revealed that SH-Bent has high stability, with a desorption rate of 5.73% at pH 4.5, 60 min, and 303 K, which was much lower than that demonstrated by Bent under the same conditions (45.68%). The Langmuir equation was the best-fitted adsorption isotherm model, closely followed by the Freundlich, Tempkin, and Dubinin–Radushkevich models. A significant difference in diffusion was observed between the two types of clay according to the intraparticle diffusion model. The adsorption–desorption processes of SH-Bent and Bent fit the pseudo-second-order model best among the five kinetic models examined. The information provided in this study can be used to apply thiol-modified clay for wastewater treatment or for the removal of cadmium from soil.

Graphical abstract

     

新型紫罗兰酮基双查尔酮缩氨基硫脲的合成及抗肿瘤活性

根据活性亚结构拼接原理,通过紫罗兰酮与(取代)苯甲醛反应合成了紫罗兰酮基双查尔酮,然后经与氨基硫脲缩合得到一系列未见报道的新型含紫罗兰酮、查尔酮及氨基硫脲3种优势结构单元的杂化体,它们的化学结构经傅里叶变换红外光谱(FT-IR)、核磁共振波谱(~1H NMR、~(13)C NMR)、元素分析及质谱(MS)等测试技术所证实。采用溴化噻唑蓝四氮唑(MTT)法初步测定其体外抗肿瘤活性(乳腺癌细胞(MCF-7),肝癌细胞(Hep G2),肺癌细胞(A549)),结果表明,对于不同类型的肿瘤细胞,化合物展现较好的增殖抑制活性。尤其是化合物3a与3b对MCF-7细胞展现较强的抗增殖活性,半数致死量(IC_(50))值分别为10.83和7.62μmol/L,化合物3e对A549细胞显示一定的增殖抑制活性效果(IC_(50)值为13.36μmol/L),化合物3f对Hep G2细胞表现了高效的抗增殖活性(IC_(50)值为8.55μmol/L)。目标物的抗增殖活性与紫罗兰酮结构及查尔酮环上不同电子效应的取代基有关。