全文获取类型
收费全文 | 698篇 |
免费 | 10篇 |
国内免费 | 3篇 |
专业分类
化学 | 304篇 |
晶体学 | 11篇 |
力学 | 60篇 |
数学 | 47篇 |
物理学 | 211篇 |
无线电 | 78篇 |
出版年
2022年 | 4篇 |
2021年 | 6篇 |
2020年 | 8篇 |
2019年 | 3篇 |
2018年 | 5篇 |
2017年 | 4篇 |
2016年 | 12篇 |
2015年 | 5篇 |
2014年 | 14篇 |
2013年 | 20篇 |
2012年 | 31篇 |
2011年 | 43篇 |
2010年 | 17篇 |
2009年 | 27篇 |
2008年 | 49篇 |
2007年 | 33篇 |
2006年 | 24篇 |
2005年 | 41篇 |
2004年 | 24篇 |
2003年 | 31篇 |
2002年 | 19篇 |
2001年 | 17篇 |
2000年 | 22篇 |
1999年 | 18篇 |
1998年 | 14篇 |
1997年 | 15篇 |
1996年 | 12篇 |
1995年 | 12篇 |
1994年 | 10篇 |
1993年 | 21篇 |
1992年 | 7篇 |
1991年 | 15篇 |
1990年 | 8篇 |
1989年 | 9篇 |
1988年 | 12篇 |
1987年 | 8篇 |
1986年 | 3篇 |
1985年 | 5篇 |
1984年 | 10篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 6篇 |
1980年 | 11篇 |
1978年 | 7篇 |
1976年 | 3篇 |
1974年 | 6篇 |
1973年 | 6篇 |
1922年 | 2篇 |
1906年 | 2篇 |
1882年 | 2篇 |
排序方式: 共有711条查询结果,搜索用时 15 毫秒
31.
Use of gel-permeation chromatography in the determination of the composition of two-polymer mixtures
Jean-Pierre Menin Ren Roux 《Journal of polymer science. Part A, Polymer chemistry》1972,10(3):855-866
The possibility of evaluating with acceptable accuracy the composition of a two-polymer mixture which is well separated by GPC, was studied by using mixtures of high molecular weight polybutadiene (M?w = 4.5 × 105) and low molecular weight polyiso-butylene (M?n in the range of 103). It was concluded that a satisfactory evaluation of the composition of a polymer mixture can be achieved, provided that the variations of the refractive index with the molecular weight are taken into account for the low molecular weight polymer (the polyisobutylene). 相似文献
32.
Whitfield TW Varma S Harder E Lamoureux G Rempe SB Roux B 《Journal of chemical theory and computation》2007,3(6):2068-2082
The hydration of K(+) is studied using a hierarchy of theoretical approaches, including ab initio Born-Oppenheimer molecular dynamics and Car-Parrinello molecular dynamics, a polarizable force field model based on classical Drude oscillators, and a nonpolarizable fixed-charge potential based on the TIP3P water model. While models based more directly on quantum mechanics offer the possibility to account for complex electronic effects, polarizable and fixed-charges force fields allow for simulations of large systems and the calculation of thermodynamic observables with relatively modest computational costs. A particular emphasis is placed on investigating the sensitivity of the polarizable model to reproduce key aspects of aqueous K(+), such as the coordination structure, the bulk hydration free energy, and the self diffusion of K(+). It is generally found that, while the simple functional form of the polarizable Drude model imposes some restrictions on the range of properties that can simultaneously be fitted, the resulting hydration structure for aqueous K(+) agrees well with experiment and with more sophisticated computational models. A counterintuitive result, seen in Car-Parrinello molecular dynamics and in simulations with the Drude polarizable force field, is that the average induced molecular dipole of the water molecules within the first hydration shell around K(+) is slightly smaller than the corresponding value in the bulk. In final analysis, the perspective of K(+) hydration emerging from the various computational models is broadly consistent with experimental data, though at a finer level there remain a number of issues that should be resolved to further our ability in modeling ion hydration accurately. 相似文献
33.
Francisco Ros Pilar Jiménez María Victoria Roux 《Monatshefte für Chemie / Chemical Monthly》2007,28(4):941-949
The cohesion potential energy of the crystal of one enantiomer of ethyl 3-cyano-3-(3,4-dimethyloxyphenyl)-2,2,4-trimethylpentanoate,
−47.7 ± 0.1 kJ mol−1 (0–90°C), was found out from the heat of sublimation (123.2 ± 5.1 kJ mol−1, 78.6°C) and the kinetic energies for the gas phase and the crystal. It was found that the entropy function of Debye’s theory of solids mathematically agreed with the vibrational entropy of the gas (variationally obtained), allowing to disclose
the vibrational energy using the Debye energy function (E
vib 835.0 kJ mol−1 (78.6°C), E
0 included). E
kin for the crystal (771.1 kJ mol−1 (78.6°C)) was obtained by Debye’s theory with the experimental heat capacity. The cohesion energy represented a moderate part of the sublimation energy.
The cohesion energy of the racemic crystal, −44.2 kJ mol−1, was obtained by the heat of formation of the crystal in the solid state (3.0 kJ mol−1, 83.3°C) and E
kin for the crystal (by Debye’s theory). The decrease in cohesion on formation of the crystal accounted for the energy of formation. The change in potential
energy on liquefaction of the racemate from the gas state was disclosed obtaining added-up E
vib + rot for the liquid in the way as to E
vib for the gas, the Debye entropy function being increasedly suited for the liquid (E
vib + rot 763.4 kJ mol−1 (115.4°C)). Positive ΔE
pot, 13.0 kJ mol−1, arised from the increase in electronic energy (Δ
l
νmean − 154.3 cm−1, by the dielectric nature of the liquid), added to the cohesion energy. 相似文献
34.
A M Le Roux C A Wium J R Joubert P P Van Jaarsveld 《Journal of chromatography. A》1992,581(2):306-309
Salbutamol concentrations were determined by high-performance thin-layer chromatography in the sera of two sets of ten volunteers at hourly intervals for 6 h after taking one 8-mg slow-release tablet. The influence of time lapse in processing of serum samples, i.e. centrifugation, extraction and chromatography, was studied. A statistical significant instability of salbutamol in the sera of patients was found which was not present in standard drug-free serum samples spiked with salbutamol and used for construction of standard curves. 相似文献
35.
The aim of this study is the evaluation by mechanical testing of the durability of rigid PVC. The prediction of mechanical durability is made by following the change in the brittle temperature TB at a constant speed by an indentation test after artificial and natural weathering. TB is presented as a possible durability index for thin, extruded rigid PVC profiles. 相似文献
36.
Importance of the Correlation between Width and Length in the Shape Analysis of Nanorods: Use of a 2D Size Plot To Probe Such a Correlation 下载免费PDF全文
Prof. Clément Roux Dr. Céline Delmas Prof. Jean‐Daniel Marty Dr. Myrtil L. Kahn Dr. Christophe Mingotaud 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(35):12424-12429
Analysis of nanoparticle size through a simple 2D plot is proposed in order to extract the correlation between length and width in a collection or a mixture of anisotropic particles. Compared to the usual statistics on the length associated with a second and independent statistical analysis of the width, this simple plot easily points out the various types of nanoparticles and their (an)isotropy. For each class of nano‐objects, the relationship between width and length (i.e., the strong or weak correlations between these two parameters) may suggest information concerning the nucleation/growth processes. It allows one to follow the effect on the shape and size distribution of physical or chemical processes such as simple ripening. Various electron microscopy pictures from the literature or from the authors′ own syntheses are used as examples to demonstrate the efficiency and simplicity of the proposed 2D plot combined with a multivariate analysis. 相似文献
37.
Pascal Moucheront François BertrandGeorg Koval Laurent Tocquer Stéphane RodtsJean-Noël Roux Alain CorfdirFrançois Chevoir 《Magnetic resonance imaging》2010
The rheology of granular materials near an interface is investigated through proton magnetic resonance imaging. A new cylinder shear apparatus has been inserted in the magnetic resonance imaging device, which allows the control of the radial confining pressure exerted by the outer wall on the grains and the measurement of the torque on the inner shearing cylinder. A multi-layer velocimetry sequence has been developed for the simultaneous measurement of velocity profiles in different sample zones, while the measurement of the solid fraction profile is based on static imaging of the sample. This study describes the influence of the roughness of the shearing interface and of the transverse confining walls on the granular interface rheology. 相似文献
38.
39.
Franklin David Rincón Marcelo Esposito Pedro Henrique Hermes de Araújo Claudia Sayer Galo Antonio Carrillo Le Roux 《大分子反应工程》2013,7(1):24-35
Reaction calorimetry is a very useful tool to monitor exothermic polymerization reactions as it is based on the estimation of the heat generated by the reaction. The objective of this work is to analyze the performance of an unscented Kalman filter (UKF) for online monitoring of batch vinyl acetate emulsion polymerization reactions. Reactions are performed in isoperibolic and isothermal conditions. The UKF is compared to an extended Kalman filter that has a very poor performance. The results show that the UKF is able to provide good estimates for the conversion, for the reactor and jacket temperatures, for the overall heat transfer coefficient between the reaction medium and the jacket, and for the heat loss from the jacket to the surroundings.
40.
Gouillart E Kuncio N Dauchot O Dubrulle B Roux S Thiffeault JL 《Physical review letters》2007,99(11):114501
We report on experiments of chaotic mixing in a closed vessel, in which a highly viscous fluid is stirred by a moving rod. We analyze quantitatively how the concentration field of a low-diffusivity dye relaxes towards homogeneity, and we observe a slow algebraic decay of the inhomogeneity, at odds with the exponential decay predicted by most previous studies. Visual observations reveal the dominant role of the vessel wall, which strongly influences the concentration field in the entire domain and causes the anomalous scaling. A simplified 1D model supports our experimental results. Quantitative analysis of the concentration pattern leads to scalings for the distributions and the variance of the concentration field consistent with experimental and numerical results. 相似文献