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991.
992.
A multistage membrane separation process for hydrogen recovery is described and formulated as a signomial programming problem. Two different configurations are examined. A 3-stage and a 5-stage process design problem are solved. The optimal solution to these programs is computed from an initial point that does not satisfy the mass balance or transport constraints of the process, using a primal-based geometric programming code. Also examined is the sensitivity of the optimal solution to changes in purity requirements. In all cases, computation times are very reasonable ranging from 2 to 4 seconds of IBM 370/165 CPU time. 相似文献
993.
We study the erednikDrinfeld p-adic uniformization ofcertain AtkinLehner quotients of Shimura curves overQ. We use it to determine over which local fields they haverational points and divisors of a given degree. Using a criterionof Poonen and Stoll, we show that the ShafarevichTategroup of their jacobians is not of square order for infinitelymany cases. 1991 Mathematics Subject Classification 11G18, 11G20,14G20, 14G35, 14H40. 相似文献
994.
Shi Bai Tancrède Lepoint Adeline Roux-Langlois Amin Sakzad Damien Stehlé Ron Steinfeld 《Journal of Cryptology》2018,31(2):610-640
The Rényi divergence is a measure of closeness of two probability distributions. We show that it can often be used as an alternative to the statistical distance in security proofs for lattice-based cryptography. Using the Rényi divergence is particularly suited for security proofs of primitives in which the attacker is required to solve a search problem (e.g., forging a signature). We show that it may also be used in the case of distinguishing problems (e.g., semantic security of encryption schemes), when they enjoy a public sampleability property. The techniques lead to security proofs for schemes with smaller parameters, and sometimes to simpler security proofs than the existing ones. 相似文献
995.
Rozkiewicz DI Brugman W Kerkhoven RM Ravoo BJ Reinhoudt DN 《Journal of the American Chemical Society》2007,129(37):11593-11599
This paper describes a new method to replicate DNA and RNA microarrays. The technique, which facilitates positioning of DNA and RNA with submicron edge resolution by microcontact printing (muCP), is based on the modification of poly(dimethylsiloxane) (PDMS) stamps with dendrimers ("dendri-stamps"). The modification of PDMS stamps with generation 5 poly(propylene imine) dendrimers (G5-PPI) gives a high density of positive charge on the stamp surface that can attract negatively charged oligonucleotides in a "layer-by-layer" arrangement. DNA as well as RNA is transfer printed from the stamp to a target surface. Imine chemistry is applied to immobilize amino-modified DNA and RNA molecules to an aldehyde-terminated substrate. The labile imine bond is reduced to a stable secondary amine bond, forming a robust connection between the polynucleotide strand and the solid support. Microcontact printed oligonucleotides are distributed homogeneously within the patterned area and available for hybridization. By using a robotic spotting system, an array of hundreds of oligonucleotide spots is deposited on the surface of a flat, dendrimer-modified stamp that is subsequently used for repeated replication of the entire microarray by microcontact printing. The printed microarrays are characterized by homogeneous probe density and regular spot morphology. 相似文献
996.
Lavie G Barliya T Mandel M Blank M Ron Y Orenstein A Livnat T Friedman N Weiner L Sheves M Weinberger D 《Photochemistry and photobiology》2007,83(5):1270-1277
Incorporation of photodynamic therapy into clinical practice for induction of vascular photo-occlusion highlights the need to prevent adverse phototoxicity to sensitive juxtaposed tissues, particularly in the retina. We developed a system termed "competitive quenching" to prevent adverse phototoxic damage. It involves differential compartmentalization of a photoactivator to the intravascular compartment for photoexcitation and delivery of phototoxicity to targeted vessels. A different photodynamic agent is partitioned to the extravascular retinal space to quench reactive oxygen species generated by photosensitization, thereby protecting the adjacent retinal tissues from adverse phototoxicity. The absorption spectra of quenchers must span wavelengths that are shorter and excluded from the spectral range of photoexcitation light to prevent photoactivation of the quencher. Perihydroxylated perylenequinones were found to be suitable to function as "competitive quenchers" with the prototype hypericin identified as a potent quencher. Here we examined the mechanisms operative in competitive quenching and suggest that hypericin forms a complex with verteporfin, thereby quenching singlet oxygen formation. Furthermore, we show that hypericin, with six phenolic hydroxyls, protects retinal and endothelial hybridoma cells from phototoxicity more effectively than the dimethyl tetrahydroxy helianthrone structural analog with only four such phenolic hydroxyls. The findings suggest that hydroxyl numbers contribute to the efficacy of competitive quenching. 相似文献
997.
An encryption scheme is non-malleable if giving an encryption of a message to an adversary does not increase its chances of producing an encryption of a related message (under a given public key). Fischlin introduced a stronger notion, known as complete non-malleability, which requires attackers to have negligible advantage, even if they are allowed to transform the public key under which the related message is encrypted. Ventre and Visconti later proposed a comparison-based definition of this security notion, which is more in line with the well-studied definitions proposed by Bellare et al. The authors also provide additional feasibility results by proposing two constructions of completely non-malleable schemes, one in the common reference string model using non-interactive zero-knowledge proofs, and another using interactive encryption schemes. Therefore, the only previously known completely non-malleable (and non-interactive) scheme in the standard model, is quite inefficient as it relies on generic NIZK approach. They left the existence of efficient schemes in the common reference string model as an open problem. Recently, two efficient public-key encryption schemes have been proposed by Libert and Yung, and Barbosa and Farshim, both of them are based on pairing identity-based encryption. At ACISP 2011, Sepahi et al. proposed a method to achieve completely non-malleable encryption in the public-key setting using lattices but there is no security proof for the proposed scheme. In this paper we review the mentioned scheme and provide its security proof in the standard model. Our study shows that Sepahi’s scheme will remain secure even for post-quantum world since there are currently no known quantum algorithms for solving lattice problems that perform significantly better than the best known classical (i.e., non-quantum) algorithms. 相似文献
998.
Raluca I. Gearba Travis Mills Josh Morris Ron Pindak Charles T. Black Xiaoyang Zhu 《Advanced functional materials》2011,21(14):2666-2673
The challenges of experimentally probing the physical and electronic structures of the highly intermixed organic semiconductor blends that comprise active layers in high‐performance organic photovoltaic (OPV) cells ultimately limit the fundamental understanding of the device performance. We use Fourier‐transform IR (FTIR)‐absorption spectroscopy to quantitatively determine the interfacial electric field in blended poly(3‐hexylthiophene) (P3HT):phenyl‐ C61‐butyric acid methyl ester (PCBM) thin films. The interfacial electric field is ≈0.2 V nm?1 in the as‐spun film and blends annealing at temperatures as high as 150 °C, which is the optimal annealing temperature in terms of OPV performance. The field decreases to a negligible value upon further annealing to 170 °C, at which temperature PCBM changes from amorphous to crystalline and the open‐circuit voltage of the solar cell decreases from 0.62 to 0.4 V. In addition, our measurements also allow determination of the absolute degree of crystallinity within the acceptor material. The roles of interfacial field and local crystallinity in OPV device performance are discussed. 相似文献
999.
Jan Zeman Ron H.J. Peerlings Marc G.D. Geers 《Journal of the mechanics and physics of solids》2011,59(6):1214-1230
In this paper, we study the mechanics of statistically non-uniform two-phase elastic discrete structures. In particular, following the methodology proposed in Luciano and Willis (2005) [Journal of the Mechanics and Physics of Solids 53, 1505-1522], energetic bounds and estimates of the Hashin-Shtrikman-Willis type are developed for discrete systems with a heterogeneity distribution quantified by second-order spatial statistics. As illustrated by three numerical case studies, the resulting expressions for the ensemble average of the potential energy are fully explicit, computationally feasible and free of adjustable parameters. Moreover, the comparison with reference Monte-Carlo simulations confirms a notable improvement in accuracy with respect to approaches based solely on the first-order statistics. 相似文献
1000.
We report an optimized version of the molecular dynamics program MOIL that runs on a shared memory system with OpenMP and exploits the power of a Graphics Processing Unit (GPU). The model is of heterogeneous computing system on a single node with several cores sharing the same memory and a GPU. This is a typical laboratory tool, which provides excellent performance at minimal cost. Besides performance, emphasis is made on accuracy and stability of the algorithm probed by energy conservation for explicit-solvent atomically-detailed-models. Especially for long simulations energy conservation is critical due to the phenomenon known as "energy drift" in which energy errors accumulate linearly as a function of simulation time. To achieve long time dynamics with acceptable accuracy the drift must be particularly small. We identify several means of controlling long-time numerical accuracy while maintaining excellent speedup. To maintain a high level of energy conservation SHAKE and the Ewald reciprocal summation are run in double precision. Double precision summation of real-space non-bonded interactions improves energy conservation. In our best option, the energy drift using 1fs for a time step while constraining the distances of all bonds, is undetectable in 10ns simulation of solvated DHFR (Dihydrofolate reductase). Faster options, shaking only bonds with hydrogen atoms, are also very well behaved and have drifts of less than 1kcal/mol per nanosecond of the same system. CPU/GPU implementations require changes in programming models. We consider the use of a list of neighbors and quadratic versus linear interpolation in lookup tables of different sizes. Quadratic interpolation with a smaller number of grid points is faster than linear lookup tables (with finer representation) without loss of accuracy. Atomic neighbor lists were found most efficient. Typical speedups are about a factor of 10 compared to a single-core single-precision code. 相似文献