Modified structural,morphological and photoelectrochemical properties of 120 MeV Ag9+ ion irradiated BaTiO3 thin films

The effects of high electronic energy deposition on the structure, surface topography, optical property and photoelectrochemical behavior of barium titanate thin (BaTiO₃) films have been investigated by irradiating films with 120 MeV Ag⁹⁺ ions at different ion fluences in the range of 1 × 10¹¹–3 × 10¹² ions cm^?2. Barium titanate thin films were deposited on indium tin oxide-coated glass substrate by sol–gel spin coating method. The structure of the film was crystalline with tetragonal phase. Surface topography was studied by atomic force microscopy detailing the values of roughness of the films. Maximum photocurrent density of 1.78 mA cm^?2 at 0.4 V/SCE and applied bias photon-to-current efficiency (ABPE) of 0.91% was observed for BaTiO₃ film irradiated at 1 × 10¹¹ ions cm^?2.     

Nanoparticle-assembled capsule synthesis: formation of colloidal polyamine-salt intermediates

There is current interest in developing new synthesis strategies for multifunctional hollow spheres with tunable structural properties that would be useful in encapsulation and controlled release applications. A new route was reported recently, in which the sequential reaction of polyamines, multivalent anions, and charged nanoparticles leads to the formation of polymer-filled and water-filled organic/inorganic micron-sized structures known as nanoparticle-assembled capsules. This technique is unique among other capsule preparation routes, as it allows the rapid and scalable formation of robust shells at room temperature, in near-neutral water, and with readily available precursors. This nanoparticle assembly synthesis route involves two steps: the formation of polymer aggregates and the subsequent deposition of particles around the aggregates. The purpose of this paper is to understand in greater detail the noncovalent chemistry of the polymer-salt aggregation step. With poly(allylamine hydrochloride) (PAH) as the model polymer, aggregate formation was investigated as a function of charge ratio, pH, and time through dynamic light scattering, electrophoretic mobility measurements, chloride ion measurements, and optical microscopy. PAH formed aggregates by the cross-linking action of divalent and higher-valent anions above a critical charge ratio and in a pH range defined by the pKa values of PAH and the anion. The aggregates grew in size through coalescence and with growth rates that depended on their surface charge. Controlling polymer aggregate growth provided a direct and simple means to adjust the size of the resultant capsule materials.     

Isotropic-nematic phase transition in the Lebwohl-Lasher model from density of states simulations

Density of states Monte Carlo simulations have been performed to study the isotropic-nematic (IN) transition of the Lebwohl-Lasher model for liquid crystals. The IN transition temperature was calculated as a function of system size using expanded ensemble density of states simulations with histogram reweighting. The IN temperature for infinite system size was obtained by extrapolation of three independent measures. A subsequent analysis of the kinetics in the model showed that the transition occurs via spinodal decomposition through aggregation of clusters of liquid crystal molecules.     

Electronic states of self stabilized L10 FePt alloy nanoparticles

The ligand capped bimetallic FePt alloys were prepared by using the chemical coreduction method in the presence of oleic acid and oleylamine. An X-ray photoelectron spectroscopy (XPS) study on the as prepared and annealed samples reveals the degradation of hydrocarbon capping with annealing temperature along with a phase transformation to a L1₀ phase. This degradation of organic capping results in formation of capping layer over FePt which has been observed using High Resolution Transmission electron microscopy (HRTEM). This capping layer over the FePt nanoparticles was further investigated with Raman studies confirming the presence of the graphitic carbon. The presence of the graphitic layer enhances the stability of FePt nanoparticles by protecting the surface against oxidation. This was confirmed by the magnetic measurements which show a high coercivity of 11.8 kOe, retained over a period of one year.     

Generalized co-phasing for multiple transmit and receive antennas

We propose and study a class of transmit beamforming techniques for systems with multiple transmit and multiple receive antennas with a per-antenna transmit power constraint. The per-antenna transmit power constraint is more realistic than the widely used total (across all transmit antennas) power constraint, since in practice each transmit antenna is driven by a separate power amplifier with a maximum power rating. Under the per-antenna power constraint, from an implementation perspective, it becomes desirable to vary only the phases (as opposed to both power and phase variation) of the signals departing from the transmit antennas. We name this class of techniques generalized co-phasing and formulate an optimization problem to calculate the transmit antenna phases. Furthermore, we propose five heuristic algorithms to solve the optimization problem. All the proposed algorithms except one are optimal for the case of two transmit antennas and an arbitrary number of receive antennas. For an arbitrary number of transmit and receive antennas, simulations indicate that the proposed algorithms perform very close to the optimal solution calculated through an exhaustive search of all possible transmit phases.     

Optimal production and rationing policies of a make-to-stock production system with batch demand and backordering

In this paper, we consider the stock rationing problem of a single-item make-to-stock production/inventory system with multiple demand classes. Demand arrives as a Poisson process with a randomly distributed batch size. It is assumed that the batch demand can be partially satisfied. The facility can produce a batch up to a certain capacity at the same time. Production time follows an exponential distribution. We show that the optimal policy is characterized by multiple rationing levels.     

Selective filling for patterning in microfluidic channels

The ability to pattern different polymers in microfluidic channels is indispensable for the development of multifunctional, "lab-on-a-chip" devices. A simple method, based on the concept of selective filling, is described for introducing different polymers at defined locations in microfluidic channels. Selective filling is based on the difference in the free energy of filling between an open and a covered part of the channel. It is implemented by covering part of the channel, along its length, with a temporary poly(dimethylsiloxane) (PDMS) slab. Preferential filling is related to the contact angle of the liquid solution on the chip surface. An expression for the critical contact angle is derived, and its dependence on the geometry of the channel is established. It is further shown that a trapezoidal geometry of the cross-section of the channel is optimal for selective filling. Experimental verification of the applicability of the critical contact angle in predicting selective filling is demonstrated by introducing liquid prepolymer solutions of different contact angles in the glass channel that was etched using photolithography and wet etching. Finally, patterning of two different polymers along the axial direction of the microfluidic channel is demonstrated using this selective filling technique.     

Effect of nucleic acid contamination on partitioning of proteins in two-phase PEG-Dextran system

Downstream processing of bioproducts results in considerable losses of compounds of interest in a large number of cases. For the intracellular enzyme tartrate dehydrogenase, an analysis of the laboratory process for enzyme recovery revealed that maximum losses occur in the initial stages of purification when the enzyme is separated from nucleic acids and other undesirable enzymes. Hence, aqueous twophase extraction was studied to investigate the separation of several enzymes from nucleic acids. Single-component and binary equilibria for three commercially available enzymes (bovine serum albumin, trypsin, chymotrypsin) and yeast RNA were studied in a two-phase system consisting of dextran and polyethylene glycol (PEG). The effects of pH and concentrations of the components and salts (NaC1) were investigated.     

Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered Suzuki-Miyaura couplings

[reaction: see text] A simplified synthesis of N-heterocyclic carbene (NHC)Pd-carboxylate complexes and their activity in Suzuki-Miyaura cross-coupling reactions are described. Coupling of sterically hindered aryl and activated alkyl chlorides bearing beta-hydrogens has been successfully achieved.