Synthesis and properties of ZnO nanofibers prepared by electrospinning

ZnO nanofibers were prepared from zinc acetate/polyvinyl alcohol (PVA) by electrospun method. The morphological features, crystallinity, mechanical and optical properties of the ZnO nanofibers were studied. The results show the specific surface area of the ZnO nanofibers was influenced by the electrospun conditions. The specific surface area reached 389.7 m²g⁻¹ as the average diameter was 232 nm. The XRD date reveals the nanofibers consist of a single phase of well-crystallized ZnO with hexagonal structure. The elastic modulus of a single ZnO nanofiber was also characterized by nano-scale three-point bending test.     

一种新的两道工序柔性流水车间排序问题

本文针对F_2(p),h11.1|m_1=1,m_2=μ≥2|C_(max)这一问题给出了几种近似算法,并对每种近似算法进行了最坏情形分析,给出了最坏情形界.     

Evolution of TiO2 coating layers on lamellar sericite in the presence of La and the pigmentary properties

TiO₂-coated sericite powders were prepared by the chemical deposition method starting from lamellar sericite and TiCl₄ in the presence or absence of La³⁺ cations. After calcination at 900 °C for 1 h, the resultant TiO₂ nanoparticles on the sericite surfaces existed in anatase phase. The light scattering indexes of the TiO₂-coated lamellar sericite powders were dozens of times higher than that of the naked lamellar sericite powders. The presence of La³⁺ in the deposition solution was beneficial to the formation of the small-sized anatase TiO₂ nanoparticles, resulting in the formation of the dense and uniform island-like TiO₂ coating layers in a large range of the weight ratios of TiO₂ to sericite from 5% to 20%. The TiO₂-coated lamellar sericite powders prepared in the presence of La³⁺ had higher light scattering index than that prepared in the absence of La³⁺. XPS analysis shows that when La³⁺ cations were absent in the reaction solution, TiO₂ coating layers anchored at the sericite surface via the Ti-O-Si and Ti-O-Al bonds. The presence of La³⁺ cations caused the formation of Si-O-La and Al-O-La bonds at the sericite surface and Ti-O-La bond at the surface of TiO₂ coating layers. After coating TiO₂ on the sericite surface, the yellowness of the TiO₂-coated sericite powders obviously increased and the brightness slightly decreased.     

2000年钦州数据和多媒体业务发展的思路和实践

介绍了钦州电信分公司2000年发展数据和多媒体业务的成功经验：在转变观念、加强对现代经营管理的认识的基础上，通过市场调研及对调研结果进行分析，制定出加强宣传、在资费上采取一定的优惠政策，重点突破大中专学校，通过社会代理让IP业务走向社会等措施，从而取得IP业务的大发展。     

单晶SiNd：YAG激光连续退火的数值计算

应用固相外延模型来模拟单晶Si的连续Nd：YAG激光退火过程,在低功率密度连续激光退火下,用准静态模型模拟辐照区向非辐照区的径向传导散热。在数值计算中，应用部分线性法处理非线性非齐次热传导方程,得到相应的隐格式差分方程，再用追赶法求解隐格式差分方程,得出绝热边界条件下的温度的时间和空间分布，从而得出激光退火的再结晶厚度。当激光波长λ=1．06μm、功率密度io=700W／cm^2。预热温度T0=523K时，经过0．7秒，表面温度度升到1290K左右，再结晶厚度约为0．5μm。     

Asymptotic behavior of vortices in axisymmetric flow without swirl

We investigate the confinement properties of bounded, nonnegative, compactly supported vortices of axisymmetric incompressible Euler flows without swirl. We show that along one direction of the symmetry axis, its support can grow no faster than O[(t log t)^1/2]. The rate at which it approaches the symmetry axis is also estimated. Together with the result of Maffei–Marchioro on the radial growth rate of the support, it is contained in a slowly expanding tubular region. The techniques of the above‐mentioned authors, Iftimie–Lopes–Nussenzveig and Iftimie–Sideris–Gamblin, are used. Copyright © 2008 John Wiley & Sons, Ltd.     

New chiral ionic liquids based on imidazolinium salts

The preparation and application of a new series of chiral ionic liquids are described. The salts are based on imidazolinium cations. Some of the cations also incorporated an axial chirality at the C(2) position next to the central chirality. These cations display a very high rotational barrier along the arene–imidazolinium axis. Furthermore, an analogue with a chiral anion was prepared. The salts have low melting points. Their potential as solvents and as chiral shift reagents was explored, resulting for the first time in an example of a chiral ionic liquid as a shift reagent for a neutral compound.     

PPY催化合成乙酸沉香酯

利用吡啶与二氯亚砜反应 ,制成双吡啶盐 ,进而与四氢吡咯反应 ,一步法合成 4 ( 1 四氢吡咯 )吡啶(PPY)。利用PPY为催化剂进行沉香醇的酰化反应 ,并对影响反应的诸因素进行了讨论 ,醇的转化率为 99% ,酯的收率为 88.2 %。     

An X‐shaped π‐conjugated polymer comprising of fluorene units and anthracene units with high efficiency. Synthesis and optical and electrochemical properties

A new X‐shaped π‐conjugated monomer comprising of fluorene units and anthracene units was synthesized, and it was used to fabricate the new X‐shaped π‐conjugated polymers and investigate the properties of the new polymers. Using different molar ratios between such monomer and a fluorene monomer gave three polymers that showed higher absolute PL quantum yields than the linear polyfluorene (PF) in the solid state. After thermal annealing at 200 °C for 4 h, the linear PF showed an additional bathochromic emission at about 550 nm, whereas such red‐shifted emission was fully eliminated for the X‐shaped polymers. The electroluminescent devices based on the X‐shaped polymers with a configuration of ITO/PEDOT:PSS/polymer/LiF/Ca/Al displayed blue emission with low turn‐on voltage and high brightness. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 5616–5625, 2008