全文获取类型
收费全文 | 965篇 |
免费 | 13篇 |
国内免费 | 8篇 |
专业分类
化学 | 507篇 |
晶体学 | 9篇 |
力学 | 27篇 |
数学 | 118篇 |
物理学 | 197篇 |
无线电 | 128篇 |
出版年
2022年 | 7篇 |
2021年 | 11篇 |
2018年 | 9篇 |
2016年 | 10篇 |
2015年 | 9篇 |
2014年 | 14篇 |
2013年 | 29篇 |
2012年 | 44篇 |
2011年 | 46篇 |
2010年 | 21篇 |
2009年 | 24篇 |
2008年 | 45篇 |
2007年 | 52篇 |
2006年 | 53篇 |
2005年 | 33篇 |
2004年 | 37篇 |
2003年 | 24篇 |
2002年 | 23篇 |
2001年 | 32篇 |
2000年 | 23篇 |
1999年 | 14篇 |
1998年 | 7篇 |
1997年 | 25篇 |
1996年 | 21篇 |
1995年 | 13篇 |
1994年 | 21篇 |
1993年 | 18篇 |
1992年 | 13篇 |
1991年 | 21篇 |
1990年 | 22篇 |
1989年 | 16篇 |
1988年 | 7篇 |
1987年 | 12篇 |
1986年 | 11篇 |
1985年 | 14篇 |
1984年 | 9篇 |
1983年 | 6篇 |
1982年 | 11篇 |
1980年 | 11篇 |
1979年 | 11篇 |
1978年 | 13篇 |
1977年 | 11篇 |
1976年 | 16篇 |
1975年 | 11篇 |
1974年 | 15篇 |
1973年 | 7篇 |
1972年 | 8篇 |
1971年 | 6篇 |
1970年 | 5篇 |
1967年 | 5篇 |
排序方式: 共有986条查询结果,搜索用时 15 毫秒
81.
Ga2O3/GdGaO dielectric stacks have been grown on GaAs for MOSFETs. This paper highlights variations in the characteristics of GdGaO as the Gd flux, Ga2O flux and substrate temperature are changed. The growth rate, composition, crystallinity are discussed and the sheet resistance of final MOSFET structures are presented. The Gd compositional variation with depth is examined using Rutherford back scattering (RBS) and electron energy loss spectroscopy (EELS). 相似文献
82.
We describe theoretically a method of obtaining pulse compression and simultaneously improving amplification in a degenerate optical parametric amplifier by use of quasi-phase-matched engineered crystals. The scheme combines the possibility of increasing the signal spectral bandwidth that is offered by a degenerate parametric amplifier with the ability of engineered aperiodically poled crystals to compensate for group-velocity mismatch. 相似文献
83.
Kurnik, R.T. and Reid, R.C., 1982. Solubility of solid mixtures in supercritical fluids. Fluid Phase Equilibria, 8: 93-105Supercritical fluids are receiving widespread attention as possible extraction agents for relatively non-volatile solids and liquids. Previous studies of the solubility of solids in supercritical fluids have been limited to pure solids. These pure-component data are interesting and indicate novel properties of supercritical fluids in this respect. The more general problem, however, lies in determining the solubility of multicomponent solids in supercritical fluids. Experimental data have now been obtained on the solubilities of binary, solid hydrocarbon mixtures in both supercritical carbon dioxide and supercritical ethylene. Most of the behavior exhibited by pure solids in supercritical fluids still exists for multicomponent solid solute systems (e.g., retrograde solidification, solubility extrema), but new phenomena were also found. The most interesting finding is that the solubility of a solid component when in a multicomponent solute system can be as much as 300% higher than the component solubility in a pure solid system at the same operating conditions. The multicomponent-solid-fluid data usually correlate well with thermodynamic theory. 相似文献
84.
The number of vertices in a digraph G having a particular outdegree (indegree) is called the frequency of the outdegree (indegree). A set F of distinct positive integers {f1, f2, …, fn} is the frequency set of the digraph G if every outdegree and indegree occurs with frequency fj∈F and for each fj∈F there is a least one outdegree and at least one indegree with frequency fj. We prove that each nonempty set F of positive integers is the frequency set of some tournament, and we determine the smallest possible order for such a tournament. Similar results for asymmetric digraphs are also given. The results and techniques for frequency sets are used to derive corresponding results for vertex frequency partitions. 相似文献
85.
James L. Reid 《Physics letters. A》1983,97(8):309-310
An autonomous system of n coupled homogeneous Riccati equations of the projective type linearizes to its linear part by means of a map which is analytic for almost all initial data. The explicit form of the map is presented. 相似文献
86.
Reid Tingley Valerio Bertolasi Keith Vaughan 《Journal of chemical crystallography》2006,36(12):831-839
A new series of bis-triazenes, the 1-aryl-2-[3-(3-[2-aryl-1-diazenyl]-1,3-diazepan-1-ylmethyl)-1,3-diazepan-1-yl]-1-diazenes has been synthesized from the reaction of diazonium salts with a mixture of 1,4-diaminobutane and formaldehyde. The structures of 1-(p-bromophenyl)-2-[3-{3-[2-(p-bromophenyl)-1-diazenyl]-1,3-diazepan-1-ylmethyl}-1,3-diazepan-1-yl]-1-diazene(1), 1-(p-cyanophenyl)-2-[3-{3-[2-(p-cyanophenyl)-1-diazenyl]-1,3-di azepan-1-ylmethyl}-1,3-diazepan-1-yl]-1-diazene(2), and 1-(p-methoxyphenyl)-2-[3-{3-[2-(p-methoxy-phenyl)-1-diazenyl]-1,3-diazepan-1-ylmethyl}-1,3-diazepan-1-yl]-1 diazene(3) have been unequivocally determined by X-ray crystallography. The new bis-triazenes are important since the structure contains the novel saturated heterocycle, 1,3-diazepane. The general conclusion of this study is that alkanediamines with 3 or 4 carbon atoms in the spacer link between the nitrogen atoms give rise to the linear bicyclic molecules of type 5, in contrast to the case of ethylenediamine (spacer link 2 carbon atoms), which affords molecules of type 6, which exemplify the general cage structure of type 4. The crystal structures of 1, 2 and 3 are compared with the previously reported structure of the hexahydropyrimidine analogue 8a(X=CN); compounds 2 and 8a(X=CN) are homologous with respect to the alkane spacer moiety. The structures of 2 and 8a(X=CN) are very different in one respect; in 2 the aryldiazenyl-1,3-diazepanyl groups are in the s-trans orientation around the central methylene group whereas in 8a(X=CN) the arrangement of the aryldiazenyl-hexahydropyrimidinyl groups is the s-cis orientation.Crystal data: 1 C23H30N8Br2, triclinic, space group P-1, a=8.3979(2), b=10.7828(3), c=14.4692(5) ?, α=83.670(1), β=78.662(1), γ=78.758(1)°, V=1256.48(6) ?3, for Z=2. 2 C25H30N10, monoclinic, space group P2
1
/n, a=13.4046(6), b=9.4482(4), c=10.6913(4)?, β=103.239(2)°, V=2490.5(2) ?3, for Z=4. 3 C25H36N8O2, triclinic, space group P-1, a=8.5223(3), b=10.6913(4), c=14.4034(7)?, α=85.657(2), β=78.731(2), γ=80.153(1)°, V=1266.88(9) ?3, for Z=2. 相似文献
87.
Benjamin M. Gray Andrew L. Hector William Levason Gillian Reid Michael Webster Wenjian Zhang Marek Jura 《Polyhedron》2010
The reaction of o-C6H4(AsMe2)2 with VCl4 in anhydrous CCl4 produces orange eight-coordinate [VCl4{o-C6H4(AsMe2)2}2], whilst in CH2Cl2 the product is the brown, six-coordinate [VCl4{o-C6H4(AsMe2)2}]. In dilute CH2Cl2 solution slow decomposition occurs to form the VIII complex [V2Cl6{o-C6H4(AsMe2)2}2]. Six-coordination is also found in [VCl4{MeC(CH2AsMe2)3}] and [VCl4{Et3As)2]. Hydrolysis of these complexes occurs readily to form vanadyl (VO2+) species, pure samples of which are obtained by reaction of [VOCl2(thf)2(H2O)] with the arsines to form green [VOCl2{o-C6H4(AsMe2)2}], [VOCl2{MeC(CH2AsMe2)3}(H2O)] and [VOCl2(Et3As)2]. Green [VOCl2(o-C6H4(PMe2)2}] is formed from [VOCl2(thf)2(H2O)] and the ligand. The [VOCl2{o-C6H4(PMe2)2}] decomposes in thf solution open to air to form the diphosphine dioxide complex [VO{o-C6H4(P(O)Me2)2}2(H2O)]Cl2, but in contrast, the products formed from similar treatment of [VCl4{o-C6H4(AsMe2)2}x] or [VOCl2{o-C6H4(AsMe2)2}] contain the novel arsenic(V) cation [o-C6H4(AsMe2Cl)(μ-O)(AsMe2)]+. X-ray crystal structures are reported for [V2Cl6{o-C6H4(AsMe2)2}2], [VO(H2O){o-C6H4(P(O)Me2)2}2]Cl2, [o-C6H4(AsMe2Cl)(μ-O)(AsMe2)]Cl·[VO(H2O)3Cl2] and powder neutron diffraction data for [VCl4{o-C6H4(AsMe2)2}2]. 相似文献
88.
We have observed seven infrared laser transitions when exciting a He discharge in a silver hollow cathode. To our knowledge, five of the seven laser transitions have not been reported previously in the literature. 相似文献
89.
Ohne Zusammenfassung 相似文献
90.
Ke J Bartlett PN Cook D Easun TL George MW Levason W Reid G Smith D Su W Zhang W 《Physical chemistry chemical physics : PCCP》2012,14(4):1517-1528
Several Ge(II) and Ge(IV) compounds were investigated as possible reagents for the electrodeposition of Ge from liquid CH(3)CN and CH(2)F(2) and supercritical CO(2) containing as a co-solvent CH(3)CN (scCO(2)) and supercritical CH(2)F(2) (scCH(2)F(2)). For Ge(II) reagents the most promising results were obtained using [NBu(n)(4)][GeCl(3)]. However the reproducibility was poor and the reduction currents were significantly less than the estimated mass transport limited values. Deposition of Ge containing films was possible at high cathodic potential from [NBu(n)(4)][GeCl(3)] in liquid CH(3)CN and supercritical CO(2) containing CH(3)CN but in all cases they were heavily contaminated by C, O, F and Cl. Much more promising results were obtained using GeCl(4) in liquid CH(2)F(2) and supercritical CH(2)F(2). In this case the reduction currents were consistent with mass transport limited reduction and bulk electrodeposition produced amorphous films of Ge. Characterisation by XPS showed the presence of low levels of O, F and C, XPS confirmed the presence of Ge together with germanium oxides, and Raman spectroscopy showed that the as deposited amorphous Ge could be crystallised by the laser used in obtaining the Raman measurements. 相似文献