Tritium in water bodies around the Kaiga generating station

Tritium concentration was monitored in different water sources collected around Kaiga Nuclear Power plant, India. The concentration was in the ranges?<?1.9–27.4 Bq L^?1 (GM?=?4.0 Bq L^?1) for groundwater,?<?1.9–42.1 Bq L^?1 (GM?=?3.5 Bq L^?1) for surface water and in 12.4–42.0 Bq L^?1 (GM?=?24.07 Bq L^?1) for reservoir water. The concentration values observed in this study are similar to those reported for other PHWR stations of the world. The radiation dose to the public due to ingestion of Tritium through groundwater was computed to be 0.08 μSvy^?1.

     

Electrochemical and Scalable Dehydrogenative C(sp3)−H Amination via Remote Hydrogen Atom Transfer in Batch and Continuous Flow

A hydrogen atom transfer-directed electrochemical intramolecular C−H amination has been developed in which the N-radical species are generated at the anode, and the base required for the reaction is generated at the cathode. A broad range of valuable pyrrolidines were prepared in good yields and with high chemoselectivity. The reaction was easily scaled up in both batch and continuous flow systems.     

Thermo-physical properties of naphthenic-palm oil methyl ester (POME) blended transformer oil

Journal of Thermal Analysis and Calorimetry - This study aims to investigate the thermal conductivity, viscosity and thermal degradation of naphthenic-based mineral oil, palm oil methyl ester...     

CZTS counter electrode in dye-sensitized solar cell: enhancement in photo conversion efficiency with morphology of TiO2 nanostructured thin films

Journal of Solid State Electrochemistry - In the present investigation, kesterite phase Cu2ZnSnS4 (CZTS) nanoparticle, and one-dimensional (1D) nanorods and three-dimensional (3D) flower-like...     

A Modelling of Context-Aware Elderly Healthcare Eco-System-(CA-EHS) Using Signal Analysis and Machine Learning Approach

In cloud computing, more often times cloud assets are underutilized because of poor allocation of task in virtual machine (VM). There exist inconsistent factors affecting the scheduling tasks to VMs. In this paper, an effective scheduling with multi-objective VM selection in cloud data centers is proposed. The proposed multi-objective VM selection and optimized scheduling is described as follows. Initially the input tasks are gathered in a task queue and tasks computational time and trust parameters are measured in the task manager. Then the tasks are prioritized based on the computed measures. Finally, the tasks are scheduled to the VMs in host manager. Here, multi-objectives are considered for VM selection. The objectives such as power usage, load volume, and resource wastage are evaluated for the VMs and the entropy is calculated for the measured objectives and based on the entropy value krill herd optimization algorithm prioritized tasks are scheduled to the VMs. The experimental results prove that the proposed entropy based krill herd optimization scheduling outperforms the existing general krill herd optimization, cuckoo search optimization, cloud list scheduling, minimum completion cloud, cloud task partitioning scheduling and round robin techniques.

     

Q-MOHRA: QoS Assured Multi-objective Hybrid Routing Algorithm for Heterogeneous WSN

Quality of Service (QoS) assurance in Wireless Sensor Network (WSN) is a tough task, and it is more exciting due to the scarcity of resources. The requirement of different WSN applications running over has different constraints. In QoS, routing protocol the network has to balance the traffic. This paper presents a novel heuristic routing algorithm known as QoS assured Multi-objective Hybrid Routing Algorithm (Q-MOHRA) for Heterogeneous WSN. Q-MOHRA takes into account the link (energy, hop count, link quality indicator etc.) and path (jitter) metrics for optimal path selection. The performance of Q-MOHRA is evaluated through intensive simulation and equated with Simple Hybrid Routing Protocol (SHRP) and Dynamic Multi-objective Routing Algorithm (DyMORA). The metrics such as average energy consumption, residual energy, packet delivery ratio, jitter, and normalized routing load are used for comparison. The performance of Q-MOHRA has been observed to outclass SHRP and DyMORA. It improves the packet delivery ratio by 24.31% as compared to SHRP and 11.86% as compared to DyMORA. Q-MOHRA outperforms DyMORA in terms of average energy consumption by a factor of 8.27%.     

A novel two-channel continuous-time time-interleaved 3rd-order sigma-delta modulator with integrator-sharing topology

This paper presents a 3rd-order two-path continuous-time time-interleaved (CTTI) delta-sigma modulator which is implemented in standard 90 nm CMOS technology. The architecture uses a novel method to resolve the delayless feedback path issue arising from the sharing of integrators between paths. By exploiting the concept of the time-interleaving techniques and through the use time domain equations, a conventional single path 3rd-order discrete-time (DT) ΔΣ modulator is converted into a corresponding two-path discrete-time time-interleaved (DTTI) counterpart. The equivalent CTTI version derived from the DTTI ΔΣ modulator by determining the DT loop filters and converting them to the equivalent continuous-time loop filters through the use of the Impulse Invariant Transformation. Sharing the integrators between two paths of the reported modulator makes it robust to path mismatch effects compared to the typical time-interleaved modulators which have individual integrators in all paths. The modulator achieves a dynamic range of 12 bits with an OverSampling Ratio of 16 over a bandwidth of 10 MHz and dissipates only 28 mW of power from a 1.8-V supply. The clock frequency of the modulator is 320 MHz but integrators, quantizers and DACs operate at 160 MHz.     

Fabrication of a <Emphasis Type="Italic">p</Emphasis>–<Emphasis Type="Italic">n</Emphasis> Heterojunction Using Topological Insulator Bi<Subscript>2</Subscript>Te<Subscript>3</Subscript>–Si and Its Annealing Response

A junction device has been fabricated by growing p-type Bi₂Te₃ topological insulator (TI) film on an n-type silicon (Si) substrate using a thermal evaporation technique. Annealing using different temperatures and durations was employed to improve the quality of the film, as confirmed by microstructural study using x-ray diffraction (XRD) analysis and atomic force microscopy (AFM). The p–n diode characteristics of the junction devices were studied, and the effect of annealing investigated. An improved diode characteristic with good rectification ratio (RR) was observed for devices annealed for longer duration. Reduction in the leakage or reverse saturation current (\( I_{\rm{R}} \)) was observed with increase in the annealing temperature. The forward-bias current (\( I_{\rm{F}} \)) dropped in devices annealed above 400°C. The best results were observed for the sample device annealed at 450°C for 3 h, showing figure of merit (FOM) of 0.621 with RR ≈ 504 and \( I_{\rm{R}} \) = 0.25 μA. In terms of ideality factor, the sample device annealed at 550°C for 2 h was found to be the best with \( n \) = 6.5, RR ≈ 52.4, \( I_{\rm{R}} \) = 0.61 μA, and FOM = 0.358. The majority-carrier density \( \left( {N_{\rm{A}} } \right) \) in the p-Bi₂Te₃ film of the heterojunction was found to be on the order of 10⁹/cm³ to 10¹¹/cm³, quite close to its intrinsic carrier concentration. These results are significant for fundamental understanding of device applications of TI materials as well as future applications in solar cells.     

Unusual structural types in manganese cluster chemistry from the use of N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine: Mn8, Mn12, and Mn20 Clusters

The syntheses, crystal structures, and magnetochemical characterization are reported for three new mixed-valent Mn clusters [Mn(8)O(3)(OH)(OMe)(O(2)CPh)7(edte)(edteH(2))](2)CPh) (1), [Mn(12)O(4)(OH)(2)(edte)(4)C(l6)(H(2)O)(2)] (2), and [Mn(20)O(8)(OH)(4)(O(2)CMe)(6)(edte)(6)](ClO(4))(2) (3) (edteH(4) = (HOCH(2)CH(2))(2)NCH(2)CH(2)N(CH(2)CH(2)OH)(2) = N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine). The reaction of edteH(4) with Mn(O(2)CPh)(2), MnCl(2), or Mn(O(2)CMe)(2) gives 1, 2, and 3, respectively, which all possess unprecedented core topologies. The core of 1 comprises two edge-sharing [Mn(4)O(4)] cubanes connected to an additional Mn ion by a micro(3)-OH- ion and two alkoxide arms of edteH(22-). The core of 2 consists of a [Mn(12)(micro(4-)O)(4)](24+) unit with S4 symmetry. The core of 3 consists of six fused [Mn(4)O(4)] cubanes in a 3 x 2 arrangement and linked to three additional Mn atoms at both ends. Variable-temperature, solid-state dc and ac magnetization (M) studies were carried out on complexes 1-3 in the 5.0-300 K range. Fitting of the obtained M/Nmicro(B) vs H/T data by matrix diagonalization and including only axial zero-field splitting (ZFS) gave ground-state spin (S) and axial ZFS parameter (D) of S = 8, D = -0.30 cm-1 for 1, S = 7, D = -0.16 cm-1 for 2, and S = 8, D = -0.16 cm-1 for 3. The combined work demonstrates that four hydroxyethyl arms on an ethylenediamine backbone can generate novel Mn structural types not accessible with other alcohol-based ligands.