Exergy and energy performance for wavy fin radiator with a new coolant of various shape nanoparticle-based hybrid nanofluids

Journal of Thermal Analysis and Calorimetry - Energetic and exergetic performance for an automotive radiator with wavy fin configuration has been investigated and compared for water-based 1% vol....     

Motor car acoustic response modelling and order reduction viabalanced model truncation

A novel practical application of the balanced model truncation (BMT) technique for the accurate and reduced order/complexity magnitude and phase modelling of the acoustic response of a motor car is described and demonstrated. The effectiveness and viability are illustrated through a sample car response modelling example     

Regioselective synthesis of 2-carbonyl furans in a one pot three component reaction

Regioselective synthesis of 2-benzoyl-6,6-dimethyl-6,7-dihydrobenzofuran-4(5H)-ones have been accomplished through a novel protocol involving β-amino enone, N-chlorosuccinimide and dimedone in a one pot catalyst-free reaction at an ambient temperature. On the other hand, the same reaction when conducted with two equivalents of N-chlorosuccinimide under similar reaction conditions, exclusive formation of 2-benzoyl-3-(dimethylamino)-6,6-dimethyl-6,7-dihydrobenzofuran-4(5H)-ones were observed. Simple and metal-free reaction conditions, selective product formation and excellent yields are the advantages of this protocol.     

Therapeutic importance of synthetic thiophene

Thiophene and its substituted derivatives are very important class of heterocyclic compounds which shows interesting applications in the field of medicinal chemistry. It has made an indispensable anchor for medicinal chemists to produce combinatorial library and carry out exhaustive efforts in the search of lead molecules. It has been reported to possess a wide range of therapeutic properties with diverse applications in medicinal chemistry and material science, attracting great interest in industry as well as academia. It has been proven to be effectual drugs in present respective disease scenario. They are remarkably effective compounds both with respect to their biological and physiological functions such as anti-inflammatory, anti-psychotic, anti-arrhythmic, anti-anxiety, anti-fungal, antioxidant, estrogen receptor modulating, anti-mitotic, anti-microbial, kinases inhibiting and anti-cancer. Thus the synthesis and characterization of novel thiophene moieties with wider therapeutic activity is a topic of interest for the medicinal chemist to synthesize and investigate new structural prototypes with more effective pharmacological activity. However, several commercially available drugs such as Tipepidine, Tiquizium Bromides, Timepidium Bromide, Dorzolamide, Tioconazole, Citizolam, Sertaconazole Nitrate and Benocyclidine also contain thiophene nucleus. Therefore, it seems to be a requirement to collect recent information in order to understand the current status of the thiophene nucleus in medicinal chemistry research.     

Random Mobility and Heterogeneity-Aware Hybrid Synchronization for Wireless Sensor Network

Random mobility of a node in wireless sensor networks (WSNs) causes the frequent changes in the network dynamics with increased cost in terms of energy and bandwidth. During data collections and transmission, they need the additional efforts to synchronize and schedule the activities of nodes. A key challenge is to maintain the global clock scale for synchronization of nodes at different levels to minimize the energy consumption and clock skew. It is also difficult to schedule the activities for effective utilization of slots allocated for aggregated data transmission. The paper proposes the Random Mobility and Heterogeneity-aware Hybrid Synchronization Algorithm (MHS) for WSN. The proposed algorithm uses the cluster-tree for efficient synchronization of CH and nodes in the cluster and network, level-by-level. The network consists of three nodes with random mobility and are heterogeneous regarding energy with static sink. All the nodes and CH are synchronized with the notion of the global timescale provided by the sink as a root node. With the random mobility of the node, the network structure frequently changes causing an increase in energy consumption. To mitigate this problem, MHS aggregate data with the notion of a global timescale throughout the network. Also, the hierarchical structure along with pair-wise synchronization reduces the clock skews hence energy consumption. In the second phase of MHS, the aggregated data packets are passed through the scheduled and synchronized slots using TDMA as basic MAC layer protocol to reduce the collision of packets. The results are extended by using the hybrid approach of scheduling and synchronization algorithm on the base protocol. The comparative results show that MHS is energy and bandwidth efficient, with increased throughput and reduced delay as compared with state-of-the-art solutions.     

Simple and efficient synthesis of substituted 2-pyrrolidinones, 2-pyrrolones, and pyrrolidines from enaminones of Baylis-Hillman derivatives of 3-isoxazolecarbaldehydes

The enaminones, generated from derivatives of appropriately substituted Baylis-Hillman adducts of 3-isoxazolecarbaldehydes, undergo intramolecular ring-closure reactions to afford substituted 2-pyrrolidinones, 1,5-dihydro-2-pyrrolones, and N-substituted pyrrolidines in good yields.     

Matrix summability of a factored Fourier series

This paper reports a result for proving a triangular matrix summability of a factored Fourier series by extending the theorem on Nörlund summability of a factored Fourier series att =x when ?(t)∈B.V in (0, π) due to Singh [4] (Indian J. Math. 9 227–236). The result generalizes the theorem of Varshney [5] (Proc. Am. Math. Soc. 10, 784–789) and that of Singh.     

Polymerization of styrene with chromium acetylacetonate–triisobutylaluminum catalyst system

Styrene is polymerized with chromium acetylacetonate–triisobutylaluminum catalyst at 40°C in a benzene medium. At the stoichiometric ratio of Al/Cr of 4, the activity for polymerization was found to be maximum. Further, the kinetic studies were carried out at this ratio of Al/Cr of maximum activity. The kinetics of polymerization and the total activation energy around 10.00 kcal/mole suggest a coordinate anionic mechanism.