Dynamics of superionic Rb3H(SeO4)2 single crystals studied by H and Rb spin-lattice relaxation

The ¹H and ⁸⁷Rb spin-lattice relaxation and spin-spin relaxation times in superionic Rb₃H(SeO₄)₂ single crystals grown by the slow evaporation method were measured over the temperature range 160-450 K. The temperature dependencies of the ¹H T₁, T_1ρ, and T₂ are measured. In the ferroelastic phase, T₁ differs from T_1ρ, which is in turn different from T₂, although these three relaxation times converge to similar values near 410 K. This transition seems to occur at temperature which is about 40 K lower than the superionic transition temperature. The observation of liquid-like values of the ¹H T₁, T_1ρ, and T₂ in the high temperature is compatible with the phase being superionic, indicating that the destruction and reconstruction of hydrogen bonds does indeed occur at high temperature. In addition, the ⁸⁷Rb T₁ and T₂ values at high temperature were similar (on the order of milliseconds), a trend that was also observed for ¹H T₁ and T₂. This behavior is expected for most hopping-type ionic conductors, and could be attributed to interactions between the mobile ions and the neighboring group ions within the crystal. The motion giving rise to this liquid-like behavior is related to the superionic motion.     

超声引导椎旁神经阻滞治疗带状疱疹后遗神经痛的疗效及可行性分析

本文对超声引导椎旁神经阻滞治疗带状疱疹后遗神经痛（post-herpetic neuralgia，PHN）的疗效及可行性进行了分析。研究对象为2015年12月~2017年12月于我院就诊的94例PHN患者，按就诊顺序随机均分为两组，对照组给予普瑞巴林常规治疗，观察组在此基础上联合超声引导椎旁神经阻滞治疗，连续治疗4周。本文比较了治疗前、治疗1周、2周、4周后的匹兹堡睡眠质量指数（PSQI）评分、疼痛视觉模拟（VAS）评分，并评价了治疗后的综合疗效，记录了治疗期间发生不良反应情况。结果显示，较治疗前，治疗1周、2周、4周后两组VAS评分均逐渐降低，且观察组治疗后各时间点的VAS评分显著低于对照组，差异具有统计学意义（P<0.05）；较治疗前，两组治疗1周、2周、4周后PSQI评分均逐渐降低，且观察组治疗后各时间点的PSQI评分显著低于对照组，差异具有统计学意义（P<0.05）；观察组治疗总有效率为89.36%，对照组为78.72%，观察组显著高于对照组，差异具有统计学意义（P<0.05）；两组治疗期间各项不良反应发生率差异无统计学意义（P>0.05）。本文证实了超声引导椎旁神经阻滞治疗PHN能显著改善患者神经疼痛症状，提升睡眠质量，同时具有安全性保障。     

新型两亲性混配钌配合物的合成及其对Hg2+的选择性“肉眼”识别

采用与文献不同的路线合成了4,4′-二(p-甲基苯基)-2,2′-二联吡啶,与文献结果相比,总收率由4.0%提高至15.3%.该化合物和4,4′-二羧基-2,2′-二联吡啶组成混合配体与金属钌配位,合成了两亲性、混配型配合物cis-N,N-4,4′-二(p-甲基)苯基-2,2′-二联吡啶-N,N-4,4′-二羧基-2,2′-二联吡啶-N,N-二异硫氰钌配合物,并用IR,UV-Vis,NMR和Maldi-TOF等手段进行表征.将该两亲性混配钌配合物首次用于对Hg2+的识别中,发现此配合物对Hg2+表现出灵敏的选择性“肉眼”识别:在DMF/乙醇溶液(体积比1∶9)中加入Hg2+后,MLCT态吸收由530nm蓝移到485nm.该配合物与Hg2+以1∶1(摩尔比)结合,检测限可低至0.5×10-6mol/L.     

Recent progress and challenges in carboxylation with CO2

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树脂填充EVAL纤维吸附剂的制备及其吸附性能表征

采用具有亲水性的乙烯-乙烯醇共聚物(EVAL)作为纤维吸附剂基质材料,粉末型Lewatit阳离子交换树脂CNP80ws为功能材料,采用可控相分离方法,制备了不同表面形态结构的树脂填充EVAL吸附剂.当使用外部液体调控相分离过程时,在纤维的表面形成了粗糙的开孔结构,并且随树脂的填充量提高纤维表面的粗糙度与开孔度有所提高.研究结果表明:树脂填充EVAL纤维吸附剂具有较大的吸附容量与较高的脱附率,其吸附容量不低于53.9mg BSA/g吸附剂(树脂填充量50%).     

Experimental and density functional studies on two structurally similar antipyrine derivatives: 4-(2-hydroxy-5-nitrobenzylidene-amino)-1,2-dihydro-1,5-dimethyl-2-phenylpyrazol-3-one and 4-(3-bromo-5-chloro-2-hydroxybenzylideneamino)-1,2-dihydro-1,5-dimethyl-2-phenylpyrazol-3-one

The Schiff base compounds, 4-(2-hydroxy-5-nitr- obenzylideneamino)-1,2-dihydro-1,5-dimethyl-2-phenylpy- razol-3-one and 4-(3-bromo-5-chloro-2-hydroxybenz- ylideneamino)-1,2-dihydro-1,5-dimethyl-2-phenylpyrazol-3-one, have been synthesized and characterized by elemental analysis, IR, and X-ray single crystal determination. Density functional calculations of the structures, natural bond orbitals, and frontier molecular orbitals and Mülliken charge analysis on the compounds were performed at B3LYP/6-31+G(d) level of theory. Vibrational frequencies were also predicted, assigned, and compared with the experimental values, which supported each other.     

偏振模色散前馈方案中偏振主态研究

前馈偏振模色散（PMD）补偿系统中重要的一项是要精确得到链路中的偏振主态（PSP）方向。通过在实验中加入扰偏器，分别用矢量法和粒子群优化（PSO）算法来拟合实验结果得到椭球，从而用椭球法得出了主态方向。结果表明：矢量法在获得椭球要比PSO算法更精确、速度更快以及所得到PSP方向更准确，其更适合用于前馈补偿方案中。     

基于EDMA的TMS320C6713片外Flash自举引导

在基于DSP的系统设计中,为了保证掉电时程序不丢失,总是将程序保存在非易失性存储器中,以便系统在上电复位时可将其引导到DSP内部的RAM中执行.以TI公司的TMS320C6713浮点DSP和AMD公司的AM29LV040 Flash存储器为例,通过JTAG加载来设计一个完整的自举引导方案.着重描述了引导引脚以及相关寄存器的设置,分析了采用EDMA传输方式将代码从Flash复制到DSP的过程,并对引导程序给出基于汇编语言的代码实现.工程实践证明,该设计方案是可行、有效的.     

高能激光量热式能量探头的研制

针对输出功率数千瓦的连续波激光能量测量需要,研制了一种量热式高能激光能量探头.该探头主要由高纯石墨激光能量吸收体、测温热电偶、绝热陶瓷等组成.重点介绍了探头的研制和通过探头温升回推激光能量的计算方法研究,以及探头测量标定工作.所研制的能量探头耐受激光破坏能力强、结构紧凑,可以组装成阵列,用于大面积高能激光束的能量分布测量.     

用于大功率半导体激光器的新型焊料

在大功率半导体激光器列阵及叠阵的组装中,焊料的选择是极其关键的,因为焊料直接参与对激光器的导电、导热激光器所需的电流全部从焊料通过,而半导体激光器列阵或叠阵工作时电流是很大的,可达50A～100A。同时半导体激光器工作时产生的热量非常大,如焊料的导热性不好,由于电流的热效应,就会在焊料上产生巨大的热量,使焊料熔化。文中研制了一种新型的焊料,这种焊料在两层铟之间蒸镀几层金,焊料由钨/镍/金/铟/铜等多层金属构成。利用这种焊料研制出脉冲功率达100W的半导体激光器列阵。