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141.
Erik Stauffer Ozgur Oyman Ravi Narasimhan Arogyaswami Paulraj 《Selected Areas in Communications, IEEE Journal on》2007,25(2):245-257
We analyze the diversity-multiplexing tradeoff in a fading relay channel at finite signal-to-noise ratios (SNRs). In this framework, the rate adaptation policy is such that the target system data rate is a multiple of the capacity of an additive white Gaussian noise (AWGN) channel. The proportionality constant determines how aggressively the system scales the data rate and can be interpreted as a finite-SNR multiplexing gain. The diversity gain is given by the negative slope of the outage probability with respect to the SNR. Finite-SNR diversity performance is estimated using a constrained max-flow min-cut upper bound on the relay channel capacity. Moreover, the finite-SNR diversity-multiplexing tradeoff is characterized for three practical decode and forward half-duplex cooperative protocols with different amounts of broadcasting and simultaneous reception. For each configuration, system performance is computed as a function of SNR under a system-wide power constraint on the source and relay transmissions. Our analysis yields the following findings; (i) improved multiplexing performance can be achieved at any SNR by allowing the source to transmit constantly, (ii) both broadcasting and simultaneous reception are desirable in half-duplex relay cooperation for superior diversity-multiplexing performance, and (iii) the diversity-multiplexing tradeoff at finite-SNR is impacted by the power partitioning between the source and the relay terminals. Finally, we verify our analytical results by numerical simulations 相似文献
142.
An effort has been made for obtaining the anharmonic properties of rocksalt structure solids starting from primary physical parameters viz. nearest-neighbor distance and hardness parameter assuming long- and short-range potentials at elevated temperatures. The elastic energy density for a deformed crystal can be expanded as power series of strains for obtaining coefficients of quadratic, cubic and quartic terms which are known as the second-, third- and fourth-order elastic constants, respectively. When the values of the higher-order elastic constants are known for a crystal, many of the anharmonic properties of the crystal can be treated within the limit of the continuum approximation in a quantitative manner. In this study, higher-order elastic constants are computed up to their melting temperature for rocksalt structure solids, which are alkali cyanides, sodium and potassium halides. The first order pressure derivatives of second- and third-order elastic constants, the second-order pressure derivatives of second-order elastic constants and partial contractions are also evaluated at different temperatures for these substances. The results thus obtained are compared with experimental data and found in well agreement with present values. 相似文献
143.
Ravi Aggarwal Durairaj Baskaran 《Journal of polymer science. Part A, Polymer chemistry》2011,49(23):5049-5056
Hydrated sodium montmorillonite (Na‐clay) has been used as a catalyst support for the heterogeneous atom transfer radical polymerization of benzyl methacrylate in the presence of various concentrations of water, reducing agent, and CuBr2 in anisole at ambient temperature. The polymerization was promoted via reduction of CuII to CuI through the addition of sodium ascorbate (NaAsc) as a reducing agent in aqueous solution. The polymerizaton proceeded in a controlled manner and produced poly(benzyl methacylate) with moderately narrow molecular weight distribution (MWD) when performed under optimum conditions of hydration (10 wt % ≤ H2O/Na‐clay ≤ 21 wt %) and reducing agent (0.15 ≤ [NaAsc]/[I] ≤ 0.23). The polymerization was uncontrolled if hydration and NaAsc exceed above their optimum range of concentrations. Apparent rate of the polymerization (kapp) increased in the presence of decane–anisole (1/3, v/v) mixture solvent. Selective adsorption of decane at the interfaces of the hydrated clay was attributed for the rate enhancement due to increased polymer and hydrophobic interface interaction. The polymerization progressed in a controlled manner as confirmed by the first‐order time‐conversion plot, linear increase in molecular weights, and moderately narrow MWDs over conversion. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
144.
145.
K. Srinivasa Rao Y. Lingappa M. Ravi Prakash Reddy T.L. Prakash 《Phase Transitions》2013,86(3):235-243
In this study, we successfully synthesized single-phase hexagonal closed packed (HCP) and face-centered cubic (FCC) nickel nanoparticles via reduction of nickel nitrate hexahydrate and nickel acetate tetrahydrate, respectively, in polyethylene glycol-200. Structural information of the as-synthesized nickel nanoparticles are studied by X-ray diffraction (XRD) as a function of the molar concentration of the nickel precursor. XRD results reveal that low concentrations of nickel precursor (0.005?M and below) favor the HCP, while high concentrations favor the mixture of HCP and FCC crystal structures. Particle size of HCP structure is found in the range of ~15?nm via transmission electron microscope analysis. Vibratory sample magnetometer is employed to study its magnetic behavior and the results reveal that FCC crystalline phase shows ferromagnetic nature with high saturation magnetization (M s?~?39.6?emu?gm?1) as compared to metastable HCP crystalline structure (M s?~?2?emu?gm?1). The surfactants bonding on the surface of nickel nanoparticles are studied. 相似文献
146.
Raju Suresh Kumar Stephen Michael Rajesh Subbu Perumal Perumal Yogeeswari Dharmarajan Sriram 《Tetrahedron: Asymmetry》2010,21(11-12):1315-1327
Enantiomerically pure (R)-(1-phenylethyl)-3,5-bis[(E)-arylmethylidene]tetrahydro-4(1H)-pyridinones were synthesized for the first time, and their 1,3-dipolar cycloaddition with nitrile oxides affording di- and trispiroheterocycles regio- and stereoselectively in moderate yields was investigated. These compounds were evaluated against Mycobacterium tuberculosis H37Rv (MTB) and multi-drug-resistant M. tuberculosis (MDR-TB). Among the compounds screened, the dispiroheterocycle, namely, (5R,6R,10S)-3,9-bis(4-chlorophenyl)-10-(2,4-dichlorophenyl)-14-[(E)-(2,4-dichlorophenyl)methylidene]-12-[(R)-1-phenylethyl]-1,4,7-trioxa-2,8,12-tri-azadispiro[4.0.4.4]tetradeca-2,8-diene 5m was found to possess the maximum activity with MIC of 0.49 μM against MTB, being 9.6 and 15.6 times more potent than ciprofloxacin and ethambutol, respectively. Against MDR-TB, 5m displayed maximum activity with an MIC of 0.49 μM, with it thus being more active than rifampicin, isoniazid, ciprofloxacin and ethambutol by 7.8, 23, 77 and 124 times, respectively. 相似文献
147.
C. Yohannan Panicker Hema Tresa Varghese K. Madhusoodanan Pillai Y. Sheena Mary K. Raju T.K. Manojkumar Anna Bielenica Christian Van Alsenoy 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2010,75(5):1559-1565
Fourier-transform-Raman and infrared spectrum of 4-azatricyclo [5.2.2.02,6] undecane-3,5,8-trione were recorded and analyzed. The vibrational wavenumbers were examined theoretically using the Gaussian03 set of quantum chemistry codes, and the normal modes were assigned by potential energy distribution (PED) calculations. The first hyperpolarizability, predicted infrared intensities and Raman activities are reported. The calculated first hyperpolarizability is comparable with reported values of similar structures which makes this compound an attractive object for future studies of nonlinear optics. Optimized geometrical parameters of the compound are in agreement with similar reported structures. The red shift of the NH stretching wavenumber in the infrared spectrum from the computational wavenumber indicates the weakening of NH bond. 相似文献
148.
149.
Ravi Jasuja Theodore L. Hazlett Michael K. Helms Suk-Hyung Lee David M. Jameson Randy W. Larsen 《Chemical physics letters》2001,350(5-6):515-521
In the current report, the temperature dependence of photoinduced electron transfer between tetrakis-(4-tetramethylpyridyl)porphine (T4MPyP) and guanine monophosphate (GMP) has been examined. In the presence of GMP the fluorescence lifetime analysis reveals a Lorentzian distribution of lifetimes centered at 0.7 ns with a width of 0.9 ns displaying significant temperature dependence. Fitting temperature dependent data to the Marcus equation gives a reorganizational energy (λ) for the electron transfer reaction of 0.6 eV and an electronic coupling factor (HAB) of 3×10−3 eV. These results suggest conformational regulation of electron transfer within the non-covalent porphyrin:nucleotide complex. 相似文献
150.