全文获取类型
收费全文 | 2578篇 |
免费 | 112篇 |
国内免费 | 23篇 |
专业分类
化学 | 1466篇 |
晶体学 | 44篇 |
力学 | 63篇 |
数学 | 406篇 |
物理学 | 466篇 |
无线电 | 268篇 |
出版年
2023年 | 30篇 |
2022年 | 61篇 |
2021年 | 67篇 |
2020年 | 67篇 |
2019年 | 87篇 |
2018年 | 80篇 |
2017年 | 70篇 |
2016年 | 98篇 |
2015年 | 68篇 |
2014年 | 141篇 |
2013年 | 229篇 |
2012年 | 168篇 |
2011年 | 153篇 |
2010年 | 126篇 |
2009年 | 100篇 |
2008年 | 156篇 |
2007年 | 124篇 |
2006年 | 125篇 |
2005年 | 83篇 |
2004年 | 94篇 |
2003年 | 71篇 |
2002年 | 65篇 |
2001年 | 31篇 |
2000年 | 34篇 |
1999年 | 24篇 |
1998年 | 11篇 |
1997年 | 17篇 |
1996年 | 17篇 |
1995年 | 17篇 |
1994年 | 21篇 |
1993年 | 17篇 |
1992年 | 20篇 |
1991年 | 19篇 |
1990年 | 11篇 |
1989年 | 11篇 |
1988年 | 14篇 |
1987年 | 11篇 |
1986年 | 10篇 |
1985年 | 14篇 |
1984年 | 20篇 |
1983年 | 13篇 |
1982年 | 22篇 |
1981年 | 11篇 |
1980年 | 13篇 |
1979年 | 11篇 |
1978年 | 7篇 |
1977年 | 9篇 |
1976年 | 8篇 |
1975年 | 8篇 |
1974年 | 5篇 |
排序方式: 共有2713条查询结果,搜索用时 14 毫秒
1.
2.
Raju Surapuraju Pavan Kumar Narayanam Mallikarjun Kumar Banothu Kranthi Tejaswee Sreeram Singh Saranjit 《Chromatographia》2015,78(19):1245-1250
Alendronate sodium is widely used in the treatment of osteoporosis and Paget’s disease. The HPLC method development for alendronate sodium, in particular, is challenging owing to the absence of chromophoric group and its high polarity. In the present study, a short and simple isocratic method was developed involving hydrophilic interaction liquid chromatography, coupled with a charged aerosol detector. The developed method was validated according to the ICH Q2(R1) guideline and was successfully applied for the analysis of a marketed formulation containing the drug.
相似文献3.
A study of the energy consumption characteristics of cryptographic algorithms and security protocols 总被引:2,自引:0,他引:2
Potlapally N.R. Ravi S. Raghunathan A. Jha N.K. 《Mobile Computing, IEEE Transactions on》2006,5(2):128-143
Security is becoming an everyday concern for a wide range of electronic systems that manipulate, communicate, and store sensitive data. An important and emerging category of such electronic systems are battery-powered mobile appliances, such as personal digital assistants (PDAs) and cell phones, which are severely constrained in the resources they possess, namely, processor, battery, and memory. This work focuses on one important constraint of such devices-battery life-and examines how it is impacted by the use of various security mechanisms. In this paper, we first present a comprehensive analysis of the energy requirements of a wide range of cryptographic algorithms that form the building blocks of security mechanisms such as security protocols. We then study the energy consumption requirements of the most popular transport-layer security protocol: Secure Sockets Layer (SSL). We investigate the impact of various parameters at the protocol level (such as cipher suites, authentication mechanisms, and transaction sizes, etc.) and the cryptographic algorithm level (cipher modes, strength) on the overall energy consumption for secure data transactions. To our knowledge, this is the first comprehensive analysis of the energy requirements of SSL. For our studies, we have developed a measurement-based experimental testbed that consists of an iPAQ PDA connected to a wireless local area network (LAN) and running Linux, a PC-based data acquisition system for real-time current measurement, the OpenSSL implementation of the SSL protocol, and parameterizable SSL client and server test programs. Based on our results, we also discuss various opportunities for realizing energy-efficient implementations of security protocols. We believe such investigations to be an important first step toward addressing the challenges of energy-efficient security for battery-constrained systems. 相似文献
4.
Murugavel Raju 《电子设计应用》2007,(5):100-102
目前,医疗电器OEM厂商正在开发技术含量更高的、用于治疗和监控常见疾病的个人保健设备。这些产品价格合理,极大提高了医疗保健质量。MCU在家用血压计、肺活量计、脉搏血氧计及心率监测器等便携式医疗设备中起着重要作用。大多数此类产品中的实际生理信号是模拟信号,在测量、监控或显示前需要进行放大、过滤等处理。 相似文献
5.
G Padmaja A V Ravi Kumar V Vidyalal P Radhakrishnan V P N Nampoori C P G Vallabhan 《Pramana》1989,32(5):L693-L698
Laser induced plasma emission spectra from highT
c superconducting samples of YBa2Cu3O7 and GdBa2Cu3O7 obtained with 1.06μm radiation from a Q switched Nd:YAG laser beam has been analysed. The results clearly show the presence of diatomic oxides
in addition to ionized species of the constituent metals in the plasma thus produced. 相似文献
6.
Alvaro Carrillo Ravi S. Kane 《Journal of polymer science. Part A, Polymer chemistry》2004,42(13):3352-3359
This article describes the formation and characterization of self‐assembled nanoparticles of controlled sizes based on amphiphilic block copolymers synthesized by ring‐opening metathesis polymerization. We synthesized a novel hydrophobic derivative of norbornene; this monomer could be polymerized using Grubbs' catalyst [Cl2Ru(CHPh)(PCy3)2] forming polymers of controlled molecular weight. We synthesized amphiphilic block copolymers of controlled composition and showed that they assemble into nanoparticles of controlled size. The nanoparticles were characterized using dynamic light scattering and transmission electron microscopy. Tuning the composition of the block copolymer enables the tuning of the diameters of the nanoparticles in the 30‐ to 80‐nm range. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3352–3359, 2004 相似文献
7.
N. Raju T. Špaček J. Ježek I. M. Caminiti F. Leinisch K. Hideg P. Ježek W. E. Trommer 《Applied magnetic resonance》2006,30(3-4):373-383
Electron paramagnetic resonance (EPR) spectroscopy of spin-labeled fatty acids was used to investigate their interaction withEscherichia coli-expressed human mitochondrial uncoupling protein UCP2 refolded from inclusion bodies in nonaethylene glycol monododecyl ether (C12E9) micelles. 5-DOXYL-stearic acid and 4-PROXYL-palmitic acid bound to UCP2 exhibited additional clearly separated h+1I, h?1I “immobile” peaks in the low- and high-field region, respectively, separated by 42 and 44 Gauss, and extensively reduced h+1M, h?1M “mobile” peaks, separated by about 30 G, whereas with 7-DOXYL-stearic acid the I and M peaks were smoothed together into one wide peak. Competition of 4-PROXYL-palmitic acid with added palmitic acid, arachidonic acid, and all-cis-8,11,14-eicosatrienoic acid and of 7-DOXYL-stearic acid with arachidonic acid was indicated by the disappearance of the h+1I, h?1I “immobile” peaks, whereas redistribution in micelles without protein was indicated by the rising of the h+1M, h?1M “mobile” peaks. In conclusion, a competition of palmitic, arachidonic, and eicosatrienoic acid within a putative fatty acid binding site was observed for mitochondrial uncoupling protein UCP2. This finding together with the observation of EPR spectra of highly immobilized probes exclusively in the presence of the recombinant UCP2 suggest the existence of a fatty acid binding site on UCP2 which is a prerequisite of the fatty acid cycling mechanism as previously postulated for UCP1. 相似文献
8.
Leong‐Huat Gan Palaniswamy Ravi Bao Wei Mao Kam‐Chiu Tam 《Journal of polymer science. Part A, Polymer chemistry》2003,41(17):2688-2695
Polymerization of 2‐(diethylamino)ethyl methacrylate (DEAEMA) via homogeneous atom transfer radical polymerization under various reaction conditions is described. The effects of the initiators and solvents were examined. With 1,1,4,7,10,10‐hexamethyl triethylenetetramine/copper(I) chloride/p‐toluenesulfonyl chloride as the ligand/catalyst/initiator system in methanol, poly(DEAEMA) with a polydispersity index as low as 1.07 was synthesized. Kinetic studies demonstrated the polymerization was very well controlled and exhibited the living characteristic of the process. Well‐defined block copolymers of DEAEMA and tert‐butyl methacrylate (tBMA) were successfully synthesized. The copolymers could be synthesized with equally good results by starting with either p(DEAEMA) or p(tBMA) as the macroinitiators. However, only the macroinitiators terminated with chlorine should be used. The corresponding macroinitiators with bromine as a transferable group did not yield well‐defined copolymers. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2688–2695, 2003 相似文献
9.
10.
We have given design of a very small residual dispersion fiber system consisting of a small dispersion fiber(SDF) with flat modal field and a corresponding dual core coaxial dispersion compensating fiber (DCF). 相似文献