Structural modifications induced in Bayfol polycarbonate due to heavy highly energetic ions irradiations

The effects of 28 GeV ⁵⁶Fe and 13.72 GeV ²⁸Si ion irradiation on the structural properties of two types of Bayfol, namely DPF 5023 and CR 1–4 polycarbonates, have been investigated. It is worth mentioning that this report is almost the first one dealing with the topic of material changes in such a high energy range. Samples from each type of Bayfol were classified into two groups. The first group has been exposed to Fe ion fluences at levels between 2000 and 8000 ion/cm². The second group has been exposed to Si ions with similar fluences. The total energy deposited is between 27.44 and 224 E12 eV. The modifications induced in Bayfol samples due to ion irradiation have been studied using X-ray diffraction (XRD) and Fourier Transform Infrared spectroscopy. The results indicate that the Fe ion irradiation causes crosslinking in Bayfol DPF 5023, reflected as a decrease in the ordering character. Also, the tendency of Bayfol CR 1–4 to crosslinking due to Fe ion irradiation is lower than that of Bayfol DPF 5023. On the other hand, the Si ion irradiation causes mainly chain scission at the carbonate site of both types of Bayfol associated with the formation of hydroxyl group.     

On the stability of linear systems with fractional-order elements

Linear integer-order circuits are a narrow subset of rational-order circuits which are in turn a subset of fractional-order. Here, we study the stability of circuits having one fractional element, two fractional elements of the same order or two fractional elements of different order. A general procedure for studying the stability of a system with many fractional elements is also given. It is worth noting that a fractional element is one whose impedance in the complex frequency s-domain is proportional to s^α and α is a positive or negative fractional-order. Different transformations and methods will be illustrated via examples.     

Synthesis of some pyridine, thiopyrimidine, and isoxazoline derivatives based on the pyrrole moiety

Abstract  

Condensation of 2-acetylpyrrole with 5-methylfuran-2-carboxyaldehyde and 4-chlorobenzaldehyde in 20% NaOH give the corresponding 2-chalconylpyrroles. Some new 2-alkoxy-3-cyano-4,6-diarylpyridines were synthesized by condensation of chalcones with malononitrile, followed by cyclization in sodium alkoxide. The reactivity of chalcones towards nitrogen nucleophiles such as thiourea and hydroxylamine hydrochloride to provide thiopyrimidines and isoxazolines was investigated.     

Magneto hydrodynamic stability of self-gravitational fluid cylinder

The self-gravitating instability of a fluid cylinder pervaded by magnetic field and endowed with surface tension has been discussed. The dispersion relation is derived and some reported works are recovered as limiting cases from it. The capillary force is destabilizing only in the small axisymmetric domain and stabilizing otherwise. The magnetic field has a strong stabilizing effect in all modes of perturbation for all wavelengths. The self-gravitating force is destabilizing in the axisymmetric perturbation. However the magnetic field effect modified a lot the destabilizing character of the model and could overcome the capillary and self-gravitating instability of the model for all short and long wavelengths.     

Xenobiotic biotransformation of 4-methoxy-N-methyl-2-quinolone, isolated from Zanthoxylum monophyllum

Phytochemical evaluation of Zanthoxylum monophyllum has led to the isolation of the alkaloid 4-methoxy-N-methyl-2-quinolone (1) with a significant activity against methicillin-resistant Staphylococcus aureus (MRSA), with an IC50 value of 1.5 microg/mL. Xenobiotic biotransformation of 1 has been conducted with the general goal of increasing the bioactivity of the compound and contributing new leads for further pharmacological research. Twenty-nine microorganisms were used for screening and two (Aspergillus flavus and Cunninghamella echinulata var. echinulata) were able to transform compound 1 to 4-methoxy-2-quinolone (2). Structural identification of the compounds was based on NMR, IR, and MS data.     

Analysis of current controllers for voltage-source inverter

Current-controlled pulsewidth modulated (PWM) inverters are widely used in high-performance AC drives because they give high dynamic responses in such systems. This paper presents a comparative study of several current controllers. Particular attention is paid to the hysteresis controller and the ramp-comparator controller, due to their simplicity and widespread use. An improved ramp comparator is proposed in which the current error signals are compared to three 120° phase-shifted triangular waveforms. This eliminates the zero voltage vector applied to the inverter and reduces the inherent amplitude and phase errors. Computer simulations are used to compare the performances. Fast Fourier transform technique is used to show the power spectrum of the current waveforms. Experimental results validate the simulated performances     

Non-linear modal equations for thin elastic shells

In this paper we derive non-linear modal equations for thin elastic shells of arbitrary geometry. Geometric non-linearities are accounted for by utilizing the strain-displacement relations of the Sanders-Koiter non-linear shell theory. Arbitrary initial imperfections are accounted for and the shell thickness is free to vary within the limits of thin shell theory. The derivation gives the coefficients of the modal equations as integral expressions over the surface of the shell. The resulting equations are well-suited for practical applications. Weighting factors are introduced to allow for reduction of our results to the Love shell theory and to the Donnell approximation. The equations are specialized for a finite simply supported circular cylinder and numerical results are compared to those previously published in the literature.     

A study of the effect of depletion charge on the stable crystals structures of heavy alkalis

In the framework of second-order perturbation theory and model potential formalism we investigate the effect of variation of depletion charge on the prediction of stable crystal structures of K, Rb, and Cs. In the formal calculation the HCP structure is found to have the lowest energy for all three metals, even though the phonon contributions were added in case of K. Nevertheless, we were able to predict correctly the observed BCC structure by changing the sign of the depletion hole charge.     

Solid–solid interactions between ferric and cobalt oxides as influenced by Al2O3-doping

The solid–solid interactions between pure and alumina-doped cobalt and ferric oxides have been investigated using DTA, IR and XRD techniques. Equimolar proportions of basic cobalt carbonate and ferric oxide and different amounts of aluminum nitrate were added as dopant substrate. The amounts of dopant were 0.75, 1.5, 3.0 and 4.5 mol% Al₂O₃.

The results obtained revealed that solid–solid interaction between Fe₂O₃ and Co₃O₄ takes place at temperatures starting from 700°C to produce cobalt ferrite. The degree of propagation of this reaction increases progressively as a function of precalcination temperature and Al₂O₃-doping of the reacting solids. However, the heating of pure mixed solids at 1000°C for 6 h. was not sufficient to effect the complete conversion of the reacting solids into CoFe₂O₄, while the addition of a small amount of Al₂O₃ (1.5 mol%) to ferric/cobalt mixed solids followed by precalcination at 1000°C for 6 h conducted the complete conversion of the reacting solids into cobalt ferrite. The heat treatment of pure and the 0.75 mol%-doped solids at 900 and 1000°C effected the disappearance of most of IR transmission bands of the free oxides with subsequent appearance of new bands characteristic for the CoFe₂O₄ structure. An increase in the amount of Al₂O₃ added from 1.5–4.5 mol% to the mixed solids precalcined at 1000°C led to the disappearance of all bands of free oxides and appearance of all bands of cobalt ferrite. The promotion effect of Al₂O₃ in cobalt ferrite formation was attributed to an effective increase in the mobility of the various reacting cations. The activation energy of formation (ΔE) of CoFe₂O₄ phase was determined for pure and doped solids. The computed values of ΔE were, respectively, 99.6, 87.8, 71.9, 64.7 and 48.7 kJ mol⁻¹ for the pure solid and those treated with 0.75, 1.5, 3 and 4.5 mol% Al₂O₃.