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71.
72.
Thermodynamic properties of quaternary aqueous solutions of mixed chlorides of 1-1*1-1*2-1 charge type with the cations (Na+, NH4
+; Mg2+, Ca2+, Ba2+) were determined using the hygrometric method. The quaternary systems NH4Cl + NaCl + MgCl2 + H2O, NH4Cl + NaCl + CaCl2+ H2O, and NH4Cl + NaCl + BaCl2 + H2O have been studied at 25 °C. The water activities were measured at total molalities from 0.44 mol⋅kg−1 to saturation for different ionic-strength fractions y of NH4Cl, y=(0.20,0.50,0.80), and different ionic strength ratios z for other solutes, z=(0.20,0.50 and 0.80) for each value of y. The obtained data allows the calculation of osmotic coefficients. 相似文献
73.
Souad Chaouche Rachid Ouarsal Brahim El Bali Mohammed Lachkar Michael Bolte Michal Dusek 《Journal of chemical crystallography》2010,40(6):526-530
Abstract
Crystal structure of Li2HPO3,H2O was determined by single-crystal X-Ray diffraction analysis at 173(2) K. It crystallizes in the monoclinic system (P21/c) with the parameters: a = 5.0322(9) ?, b = 8.9795(17) ?, c = 17.088(4) ?, β = 92.672(16)° and Z = 8. The structure was refined to R = 0.0237 and ωR = 0.0650 for 1449 reflexions. The framework of Li2HPO3, H2O can be described as layers perpendicular to the crystallographic c axis. The structure contains two types of Li-tetrahedrons. In one kind each O atom belongs to one HPO3 group, while in the second kind one apex is an O from water. A network of hydrogen bonds interactions insures the connection between the layers. 相似文献74.
Souad Chaouche Rachid Ouarsal Mohammed Lachkar Francesco Capitelli Brahim El Bali 《Journal of chemical crystallography》2010,40(6):486-490
Abstract
A new hybrid phosphate, (C6H5NH3)[ZnCl(HPO3)], has been synthesized and its structure characterized from single-crystal X-ray diffraction. The title compound crystallizes in the orthorhombic space group Pbca (n. 61) with the unit-cell parameters: a = 9.8635(2) ?, b = 9.4516(10) ?, c = 22.2430(4) ?, Z = 8 and V = 2,073.62(6) ?3. The final R factors were R/ωR = 0.0361/0.0924. Its framework might be described as a layered structure with two (010)-parallel cationic and anionic layers. The IR spectrum of this phase shows characteristic bands of phosphite and anilinium groups. 相似文献75.
76.
The mixture {yNH4Cl + (1 − y)MgCl2} (aq) has been studied using the hygrometric method at the temperature 298.15 K. The water activities are measured at total molalities from 0.30 mol kg−1 up to saturation for different ionic strength fractions y of NH4Cl with y = 0.20, 0.50 and 0.80. The obtained data allow the deduction of osmotic coefficients. Experimental results are compared with the calculations using the models of Zdanovskii–Stokes–Robinson, Kusik and Meissner, Robinson and Stokes, Lietzke and Stoughton, Reilly–Wood and Robinson and Pitzer. Thermodynamic properties have been modeled using the Pitzer ion-interaction model with inclusion of an ionic strength dependence of the third virial coefficient for the binary systems. From these measurements and the obtained binary parameters β(0), β(1), C(0) and C(1), the mixing ionic parameters θNH4Mg and ψNH4MgCl are determined by the standard Pitzer model. The results show that a good accuracy is obtained with the standard Pitzer model using extended binary parameters. The parameters θNH4Mg and ψNH4MgCl were used for evaluation of activity coefficients in the mixture. The excess Gibbs energy is also determined. 相似文献
77.
Wireless Personal Communications - This paper presents a radial cluster heads selection mechanism for homogenous wireless sensor networks. It aims to ensure a good load balancing and enhance the... 相似文献
78.
The stability and singularity problem of agile small satellite (ASS) with actuator failure is discussed in this paper. Firstly, the three-axis stabilized controller of an ASS is designed, where micro control moment gyros (MCMG's) in pyramid configuration (PC) is used as the actuator. By using the same controller and steering law, the control results before and after one gyro fails are compared by simulation. The variation of singular momentum envelope before and after one gyro fails is also compared. The simulation results show that the failure intensively decreases the capacity of output torque, which leads to the emergence of more singular points and the rapid saturation of MCMG's. Finally, the parameters of system controller are changed to compare the control effect. 相似文献
79.
Numerical modeling of multiphase flow generally requires a special procedure at the solid wall in order to be consistent with Young's law for static contact angles. The standard approach in the lattice Boltzmann method, which consists of imposing fictive densities at the solid lattice sites, is shown to be deficient for this task. Indeed, fictive mass transfer along the boundary could happen and potentially spoil the numerical results. In particular, when the contact angle is less than 90 degrees, the deficiencies of the standard model are major. Various videos that demonstrate this behavior are provided (Supporting Information). A new approach is proposed and consists of directly imposing the contact angle at the boundaries in much the same way as Dirichlet boundary conditions are generally imposed. The proposed method is able to retrieve analytical solutions for static contact angles in the case of straight and curved boundaries even when variable density and viscosity ratios between the phases are considered. Although the proposed wetting boundary condition is shown to significantly improve the numerical results for one particular class of lattice Boltzmann model, it is believed that other lattice Boltzmann multiphase schemes could also benefit from the underlying ideas of the proposed method. The proposed algorithm is two‐dimensional, and the D2Q9 lattice is used. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
80.