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111.
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Covalent Immobilization of Polyoxotungstate on Alumina and Its Catalytic Generation of Sulfoxides
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Lanlan Hong Pyaesone Win Xuan Zhang Dr. Wei Chen Dr. Haralampos N. Miras Prof. Yu‐Fei Song 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(32):11232-11238
The structural and chemical stabilities of immobilized polyoxometalate (POM)‐containing catalysts are crucial factors for their industrial application. An alumina supported POM catalyst is prepared by using a facile condensation reaction between the trilacunary POM Na12[α‐P2W15O56] ? 24 H2O (P2W15) and the hydroxy groups on the surface of γ‐Al2O3 spheres under acidic conditions. The heterogeneous catalyst P2W15?Al2O3 is characterized by a wide variety of techniques and shows excellent stability and highly efficient reactivity and selectivity for the oxygenation of thioethers to sulfoxides, which are a very useful intermediate in organic synthesis and the industrial preparation of drugs. Furthermore, P2W15?Al2O3 can be recycled and reused at least ten times without any observable loss of its catalytic efficiency, mainly due to the covalent immobilization and high dispersion of P2W15 on the γ‐Al2O3 surface. 相似文献
114.
针对一个特定工业以太网系统提出了一种有效的网络流量建模思路.首先选取系统中一条流量最大的关键链路作为研究对象,采用wireshark软件捕获流经该链路的不同协议数据包,并根据数据包大小和到达时间计算得出每种协议的流量.然后分别对其中主体协议(CIP协议和TCP协议)的流量进行时频特性和小波特性分析,发现CIP协议具有平稳的周期性,而TCP协议则体现出明显的趋势特性;针对这两种协议的不同特性,提出采用SVR模型对网络流量进行建模,利用Matlab中的libsvm工具箱进行仿真分析,结果表明了算法的有效性. 相似文献
115.
最小二乘是现有贪婪迭代类压缩感知重构算法中通用的信号估计方法,其未考虑到可能将量测噪声引入信号估计的情况.针对以上不足,提出一种基于Monte Carlo采样的压缩感知弱匹配去噪重构算法.该算法在未知信号稀疏度先验的条件下,通过引入递推Bayesian估计减小量测噪声的干扰;同时,以弱匹配的方式筛选出有效的原子,并剔除冗余原子进而重构原信号.新算法继承了现有贪婪迭代类算法的有效性,同时避免了因噪声干扰或稀疏度未知导致的重构失败.理论分析和实验表明,新算法在同等条件,尤其是非高斯噪声情况下,重构性能优于现有典型贪婪迭代类算法,且其运算时间低于BPDN算法和同类的KF-SAMP算法. 相似文献
116.
Fluorescence correlation spectroscopy (FCS) is often used to determine the mass or radius of a particle by using the dependence of the diffusion coefficient on the mass and shape. In this article we discuss how the particle size of aggregates can be measured by using the concentration dependence of the amplitude of the autocorrelation function (ACF) instead of the temporal decay. We titrate a solution of aggregates or micelles with a fluorescent label that possesses a high affinity for these structures and measure the changes in the amplitude of the ACF. We develop the theory describing the change of the ACF amplitude with increasing concentrations of labels and use it to fit experimental data. It is shown how this method can determine the aggregation number and critical micelle concentration of a standard detergent nonaethylene glycol monododecyl ether (C12E9) and a lipopolysaccharide (LPS: Escherichia coli 0111:B4). 相似文献
117.
采用复合形算法建立数学模型,以PDP三维模拟仿真软件为基础,以PDP放电效率为目标函数,以扫描电极宽度、氙气比例、气体压强和驱动电压为搜索变量,进行最优化设计来提高单元的放电效率.模拟结果表明:搜索变量坐标为(80,15,498,230)时,即扫描电极宽度、氙气比例、气体压强及维持电压分别为80 μm、15%、6.6×104Pa和230 V时,对应的放电效率取得最大值11.0%,比搜索变量坐标为(160,5,310,210)初始复合形时的放电效率提高一倍多,且真空紫外辐射能量也比初始复合形时增加79%.模拟结果表明采用复合形算法可以得出影响PDP放电性能的各因素的最优化组合,使PDP单元的放电效率和放电强度都大幅提高. 相似文献
118.
119.
Intuitionistic uncertain linguistic powered einstein aggregation operators and their application to multi-attribute group decision making
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The intuitionistic uncertain fuzzy linguistic variable can easily expressthe fuzzy information, and the power average (PA) operator is a usefultool which provides more versatility in the information aggregation procedure.At the same time, Einstein operations are a kind of various t-normsand t-conorms families which can be used to perform the corresponding intersectionsand unions of intuitionistic fuzzy sets (IFSs). In this paper, wewill combine the PA operator and Einstein operations to intuitionistic uncertainlinguistic environment, and propose some new PA operators. Firstly,the definition and some basic operations of intuitionistic uncertain linguisticnumber (IULN), power aggregation (PA) operator and Einstein operationsare introduced. Then, we propose intuitionistic uncertain linguistic fuzzypowered Einstein averaging (IULFPEA) operator, intuitionistic uncertain linguisticfuzzy powered Einstein weighted (IULFPEWA) operator, intuitionisticuncertain linguistic fuzzy Einstein geometric (IULFPEG) operator and intuitionisticuncertain linguistic fuzzy Einstein weighted geometric (IULFPEWG)operator, and discuss some properties of them in detail. Furthermore, we developthe decision making methods for multi-attribute group decision making(MAGDM) problems with intuitionistic uncertain linguistic information andgive the detail decision steps. At last, an illustrate example is given to showthe process of decision making and the effectiveness of the proposed method. 相似文献
120.
Two basic types of dephasing mechanisms, carrier-carrier and carrier-phonon scattering including hole-hole and hole-phonon
scattering are proposed in the theory of ultrafast polarization dephasing of continuum transitions in bulk semiconductors.
The contribution of optical phonon scattering to the dephasing rate is the average of the scattering rates for electrons and
holes. A weighting factor that reflects the change in the momentum of the particle in a collision is introduced into the usual
integral of the carrier-carrier scattering rate to describe the contribution of carrier-carrier scattering to the dephasing
rate for the case of static screening interaction. The theoretical calculations are in quantitative agreement with the reported
experimental results. 相似文献