A short synthesis of ishwarone

2,3,4-Trimethyl-2-cyclohexenone can be converted to the corresponding isoprene Diels-Alder adduct by a sequence initiated by conjugate addition of lithium bis(3-methyl-3-butenyl)cuprate; the sesquiterpenoid ishwarone has been synthesized in two steps from the resulting octalone.     

An ion beam spectrochemical analyser with application to the analysis of silicate minerals

Ion-beam sputtering is used to provide a new method of spectrochemical analysis of solids. The theory of quantitative analysis by this method is discussed and is shown to be applicable to the analysis of a variety of rock-forming silicates.     

Modeling and evaluation criterion for thermocompression flip-chip bonding

A single joint finite element model (FEM) using a newly developed configuration independent evaluation criterion has been created, and experimentally verified, to provide more accurate predictions of bond formation based on the joint design and assembly process parameters. This model is based on the joint interface mechanics resulting from joint bump compression. Previous studies used a deformation criterion that depended on a specific joint configuration to evaluate the effectiveness of the expected bond. This limited the applicability of the model results to the joint design for which the deformation criterion had been experimentally determined. The technique reported in this research, uses finite element models to compute detailed distributions of stresses/strains at the interface of a joint when it is plastically deformed under compression. The evaluation criterion is defined to be the change in the differential area at the bonding interface, and is shown mathematically as follows: /spl Delta/A=/spl epsi//sub xx/+/spl epsi//sub yy//spl ges/(/spl epsi//sub xx/+/spl epsi//sub yy/)/sub crit/. Models using this criterion allow for the comparison of the effects of various joint design and manufacturing process parameters on the bond joint mechanics, and the resulting probable bond joint quality. A determination of the minimum deformation required for joint formation can be obtained for any design within specified limits.     

The stability of columns comprising alternating triphenylene and hexaphenyltriphenylene molecules: variations in the structure of the hexaphenyltriphenylene component

Previous investigations of complementary polytopic interaction (CPI) columnar mesophases, in which the columns are built up of alternating hexaalkoxytriphenylene (HAT) and hexaphenyltriphenylene (PTP) molecules, concentrated mainly on the effect of variations in the structure of the HAT component. This investigation is concerned with the effect of variations in the structure of the PTP component and, in particular, variations in the position of an alkoxy side chain in the phenyl ring. Stable columnar mesophases are obtained when a hexyloxy substituent is placed in the meta- or para-position but not in the ortho-position. In the case of the meta- and para-substituted systems, the two-component CPI columnar phases are stable over a considerably larger temperature range than the one-component HAT systems. The evidence suggests that unfavourable PTP/PTP stacking is as much a driving force for the formation of these mixed stacks as is favourable PTP/HAT stacking, but both need to be explained in terms of the sum of atomically dispersed van der Waals and coulombic interactions. On cooling from the isotropic into the Col_h phase, the columnar phase based on a 1:1 mixture of hexakis(hexyloxy)tripenylene and the meta-hexyloxy-substituted PTP gives an unusual texture consisting of 'viking-axe'-shaped structures.