检测数据触合算法分析

雷达组网反隐身目标探测技术是现代军事领域比较关注的一个问题,其中的多传感器数据融合技术又是一热点问题,因而有必要从概念和应用上对其进行了解并为检测数据融合算法的研究提供一个可参照的框架。为此,本文首先说明了多传感器下的检测问题和经典检测问题的相互关系,进而结合信息论的观点就近年来出现的一些典型检测融合算法进行了分析和比较,同时提出了其它可能的一些算法类型。最后,通过计算说明数据融合技术对探测系统的影响和对反隐身系统的重要意义。     

cis-Dihydroxylation of Olefins by a Non-Heme Iron Catalyst: A Functional Model for Rieske Dioxygenases

The first iron complex capable of olefin cis -dihydroxylation in combination with H₂O₂ provides a functional model for Rieske dioxygenases. Mechanistic studies on the model reaction suggest the participation of an Fe^III(η²-OOH) intermediate, with the oxygen atoms coming exclusively from H₂O₂ (see reaction scheme; L denotes a tris(6-methyl-2-pyridylmethyl)amine ligand, Solv=solvent). The similarities between the model and the enzymes strengthen the proposal that an Fe^III–peroxo intermediate is involved in the enzymatic reactions.     

多孔硅/多孔氧化铝与PVK复合光致发光特性

用旋涂法实现了多孔硅、多孔氧化铝与聚乙烯咔唑(PVK)的复合,研究了多孔硅／PVK、多孔氧化铝／PVK复合体系的光致发光性能。PL谱的测试发现,多孔硅／PVK复合体系的PL谱同时具有多孔硅和PVK的发射峰。此外,在485nm的位置出现了一个新峰,讨论了这个峰的来源。而多孔氧化铝与PVK复合后,没有产生新的峰。但多孔氧化铝与PVK复合后,由于多孔氧化铝纳米孔的纳米限制效应使PVK的发光峰出现大幅度蓝移。从多孔硅与多孔氧化铝发光机制的不同出发,讨论了多孔硅、多孔氧化铝与PVK复合后产生不同结果的原因。     

Preparation and trans–cis isomerization of azobenzene-containing TiO2/ormosils hybrid films derived at a low temperature sol–gel process for photonic applications

Azobenzene-containing TiO₂/γ-glycidoxypropyltrimethoxysilane and methyltrimethoxysilane hybrid films are prepared by combining a low temperature sol–gel process and a spin-coating technique. The trans–cis isomerization of azobenzene small molecules inside organic–inorganic hybrid films is induced by a photoirradiation under UV light. It is noted that below a baking temperature of 150 °C is necessary for the hybrid films in optical storage or optical switching applications. The change of the refractive index and thickness of the hybrid films with real-time heating temperature are observed by using a prism coupling technique. The structural properties of the hybrid films are also characterized and investigated by thermal gravimetric analysis, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The results indicate that the as-prepared hybrid films might allow directly integrating the optical storage or optical switching devices with the waveguide devices on the same chip.     

Shape‐Selective Interception by Hydrocarbons of the O2‐Derived Oxidant of a Biomimetic Nonheme Iron Complex

Picky ferryl : The complex [Fe(Tp)(BF)] (Tp=hydrotris(3,5‐diphenylpyrazolyl)borate; BF=benzoylformate) reacts with O₂ to generate an oxidant (see picture; O red, pink; Fe yellow; N blue; C gray; H white) that oxidizes added hydrocarbons shape‐selectively. Discrimination derives from a cleft formed by two phenyl groups of the Tp ligand, favoring oblate spheroidal substrates.

     

Wavelet based noise suppression technique and its application to ultrasonic flaw detection

The noise suppression techniques with wavelet transform (WT) are widely used in non-destructive testing and evaluation (NDT&E), especially in ultrasonics. Complete reconstruction theory with hard or soft thresholds, reconstruction technique based on the singularities of noise and signal, matched filter with an impulse response, and optimal frequency-to-bandwidth ratio of wavelet technique have all been used to analyze ultrasonic signals for noise suppression. But a more simple and effective technique has been pursued for decades. This paper develops a new technique using WT for the right purpose. In this work, WT is treated as a band-pass filter whose central frequency and frequency bandwidth (CF&FB) are determined by the spectra distribution of an ultrasonic signal captured from real testing situation. For the purpose of matching their CF&FB well, a technique for evaluating the optimal scale of a daughter wavelet is carried out too. By acting this daughter wavelet as a band-pass filter, we can obtain excellent de-noising results, even when the signal to noise ratio (SNR) is below -18 dB. The performance of the technique has been done by ultrasonic signals with computer generated white noises. Finally, the experimental verification is performed on a pipeline specimen with man-made small flaws with good results obtained. The results show that the technique is more suitable for processing heavy noised ultrasonic signals, and it can also be used in automatic flaw detection.